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Sulfur trioxide, \(\mathrm{SO}_{3}\), is produced in enormous quantities each year for use in the synthesis of sulfuric acid. $$ \begin{aligned} \mathrm{S}(s)+\mathrm{O}_{2}(g) & \longrightarrow \mathrm{SO}_{2}(g) \\ 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow & 2 \mathrm{SO}_{3}(g) \end{aligned} $$ What volume of \(\mathrm{O}_{2}(g)\) at \(350 .{ }^{\circ} \mathrm{C}\) and a pressure of \(5.25 \mathrm{~atm}\) is needed to completely convert \(5.00 \mathrm{~g}\) sulfur to sulfur trioxide?

Short Answer

Expert verified
The required volume of O₂(g) at 350°C and a pressure of 5.25 atm to completely convert 5.00 g sulfur to sulfur trioxide is approximately 3.09 L.

Step by step solution

01

Determine the number of moles of sulfur.

Given that we have 5.00 g of sulfur, we can use the molar mass of sulfur to convert the mass to the number of moles. The molar mass of sulfur (S) is approximately 32.06 g/mol. Number of moles of sulfur = (mass of sulfur) / (molar mass of sulfur) = \(5.00 \mathrm{\ g}\) / \(32.06 \mathrm{\ g/mol}\) = 0.1559 mol
02

Find the stoichiometric ratio of Oâ‚‚ to S.

From the balanced chemical equations, we can find the stoichiometric ratio of O₂ to S for the complete conversion to SO₃: S(s) + O₂(g) → SO₂(g) 2 SO₂(g) + O₂(g) → 2 SO₃(g) From the first equation, 1 mol of S requires 1 mol of O₂ to form SO₂. From the second equation, 2 mol of SO₂ requires 1 mol of O₂ to form 2 mol of SO₃. Since 1 mol of S forms 1 mol of SO₂, the overall stoichiometry between O₂ and S in the conversion to SO₃ is: 1 mol S + 2 mol O₂ → 2 mol SO₃ Thus, 1 mol of S requires 2 mol of O₂ to fully convert into SO₃.
03

Calculate the moles of Oâ‚‚ required.

Using the stoichiometric ratios, we can find the moles of O₂ required to convert 0.1559 mol of S to SO₃: Moles of O₂ = (Moles of S) × (Stoichiometric ratio of O₂ : S) = 0.1559 mol × (2 mol O₂ / 1 mol S) = 0.3118 mol So, 0.3118 mol of O₂ is required for the complete conversion of 5.00 g sulfur to sulfur trioxide.
04

Use the ideal gas law to find the volume of Oâ‚‚.

Now, we'll use the ideal gas law (PV = nRT) to find the volume of O₂ at the given pressure and temperature: P = 5.25 atm n = 0.3118 mol R = 0.0821 L * atm / (K * mol) (gas constant) T = 350°C + 273.15 = 623.15 K Rearranging the ideal gas law to solve for the volume V: V = (n * R * T) / P V = \((0.3118 \mathrm{\ mol}) (0.0821 \mathrm{\ L\cdot atm / (mol\cdot K)})(623.15 \mathrm{\ K}) \ / \ (5.25 \mathrm{\ atm})\) V ≈ 3.09 L So, the required volume of O₂(g) at 350°C and a pressure of 5.25 atm to completely convert 5.00 g sulfur to sulfur trioxide is approximately 3.09 L.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The ideal gas law is a fundamental equation that relates the pressure, volume, amount, and temperature of a gas. It is written as \(PV = nRT\), where:
  • \(P\) is the pressure of the gas
  • \(V\) is the volume of the gas
  • \(n\) is the number of moles of the gas
  • \(R\) is the ideal gas constant, which is approximately 0.0821 L·atm/mol·K
  • \(T\) is the temperature in Kelvin
To find the volume of a gas, you can rearrange the equation to \(V = \frac{nRT}{P}\). This relation allows you to calculate one parameter if the others are known. For instance, in this problem, knowing the pressure, temperature, and moles of \(O_2\), the volume was calculated to determine how much space the gas occupies under specified conditions.
Understanding the ideal gas law is essential when studying gases, as it helps predict how a gas will behave under different conditions of temperature and pressure.
Chemical Equation Balancing
Balancing a chemical equation is a key skill in chemistry that ensures the quantities of reactants and products are in proportion according to the law of conservation of mass. In the production of sulfur trioxide from sulfur, we observe two sequential reactions:- \(\text{S}(s) + \text{O}_2(g) \rightarrow \text{SO}_2(g)\)- \(2\text{SO}_2(g) + \text{O}_2(g) \rightarrow 2\text{SO}_3(g)\)In these reactions, each sulfur atom and oxygen molecule is accounted for in the products. Balancing chemical equations involves adjusting the coefficients in front of chemical formulas to obtain the same number of each type of atom on both sides of the equation. This practice is crucial, as it allows chemists to determine the exact stoichiometries for reactants and products and ensures that calculations related to the amounts of substances involved are accurate.
Molar Mass Calculation
Molar mass is an important concept when converting between the mass of a substance and the amount in moles. It is the mass of one mole of a chemical element or compound. For sulfur, the molar mass is approximately 32.06 g/mol.
  • To calculate the number of moles: \(\text{Number of moles} = \frac{\text{Mass of element}}{\text{Molar mass}}\).
  • Here, the calculation becomes \( \frac{5.00 \text{ g}}{32.06 \text{ g/mol}} = 0.1559 \text{ mol}\).
This conversion is critical for chemical problem-solving, as it links the macroscopic property (mass) to a microscopic property (moles), allowing precise calculations of reaction requirements and product yields.
Gas Volume Calculation
Gas volume calculation involves determining how much space a gaseous substance occupies under given conditions of temperature and pressure, often using the ideal gas law. After finding the required number of moles of \(O_2\) (0.3118 mol) needed to react with sulfur, we used the conditions provided:
  • Pressure (\(P\)) = 5.25 atm
  • Temperature (\(T\)) = 623.15 K (converted from 350°C)
  • Gas constant (\(R\)) = 0.0821 L·atm/mol·K
The volume \(V\) is obtained from the rearranged ideal gas law: \(V = \frac{nRT}{P}\).
This approach provides the theoretical framework to predict how gases will respond to changes in conditions, ensuring accuracy in fields ranging from chemistry to meteorology. In this problem, it showed that 3.09 liters of oxygen gas are needed for the full conversion process.

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Most popular questions from this chapter

Ethene is converted to ethane by the reaction $$ \mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{H}_{2}(g) \stackrel{\text { Catalyst }}{\longrightarrow} \mathrm{C}_{2} \mathrm{H}_{6}(g) $$ \(\mathrm{C}_{2} \mathrm{H}_{4}\) flows into a catalytic reactor at \(25.0 \mathrm{~atm}\) and \(300 .{ }^{\circ} \mathrm{C}\) with a flow rate of \(1000 . \mathrm{L} / \mathrm{min}\). Hydrogen at \(25.0 \mathrm{~atm}\) and \(300 .{ }^{\circ} \mathrm{C}\) flows into the reactor at a flow rate of \(1500 . \mathrm{L} / \mathrm{min}\). If \(15.0 \mathrm{~kg}\) \(\mathrm{C}_{2} \mathrm{H}_{6}\) is collected per minute, what is the percent yield of the reaction?

Consider a sample of a hydrocarbon (a compound consisting of only carbon and hydrogen) at \(0.959\) atm and \(298 \mathrm{~K}\). Upon combusting the entire sample in oxygen, you collect a mixture of gaseous carbon dioxide and water vapor at \(1.51\) atm and \(375 \mathrm{~K}\). This mixture has a density of \(1.391 \mathrm{~g} / \mathrm{L}\) and occupies a volume four times as large as that of the pure hydrocarbon. Determine the molecular formula of the hydrocarbon.

Solid thorium(IV) fluoride has a boiling point of \(1680^{\circ} \mathrm{C}\). What is the density of a sample of gaseous thorium(IV) fluoride at its boiling point under a pressure of \(2.5\) atm in a 1.7-L container? Which gas will effuse faster at \(1680^{\circ} \mathrm{C}\), thorium(IV) fluoride or uranium(III) fluoride? How much faster?

In Example \(5.11\) of the text, the molar volume of \(\mathrm{N}_{2}(g)\) at STP is given as \(22.42 \mathrm{~L} / \mathrm{mol} \mathrm{N}_{2}\). How is this number calculated? How does the molar volume of \(\mathrm{He}(g)\) at STP compare to the molar volume of \(\mathrm{N}_{2}(\mathrm{~g})\) at STP (assuming ideal gas behavior)? Is the molar volume of \(\mathrm{N}_{2}(g)\) at \(1.000 \mathrm{~atm}\) and \(25.0^{\circ} \mathrm{C}\) equal to, less than, or greater than \(22.42 \mathrm{~L} / \mathrm{mol}\) ? Explain. Is the molar volume of \(\mathrm{N}_{2}(g)\) collected over water at a total pressure of \(1.000\) atm and \(0.0^{\circ} \mathrm{C}\) equal to, less than, or greater than \(22.42\) \(\mathrm{L} / \mathrm{mol}\) ? Explain.

At \(0^{\circ} \mathrm{C}\) a \(1.0\) - \(\mathrm{L}\) flask contains \(5.0 \times 10^{-2}\) mole of \(\mathrm{N}_{2}, 1.5 \times 10^{2}\) \(\mathrm{mg} \mathrm{O}_{2}\), and \(5.0 \times 10^{21}\) molecules of \(\mathrm{NH}_{3} .\) What is the partial pressure of each gas, and what is the total pressure in the flask?

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