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Consider the reaction $$ 3 \mathrm{~A}+\mathrm{B}+\mathrm{C} \longrightarrow \mathrm{D}+\mathrm{E} $$ where the rate law is defined as $$ -\frac{\Delta[\mathrm{A}]}{\Delta t}=k[\mathrm{~A}]^{2}[\mathrm{~B}][\mathrm{C}] $$ An experiment is carried out where \([\mathrm{B}]_{0}=[\mathrm{C}]_{0}=1.00 M\) and \([\mathrm{A}]_{0}=1.00 \times 10^{-4} M\) a. If after \(3.00 \mathrm{~min},[\mathrm{~A}]=3.26 \times 10^{-5} \mathrm{M}\), calculate the value of \(k\) b. Calculate the half-life for this experiment. c. Calculate the concentration of \(\mathrm{B}\) and the concentration of A after \(10.0 \mathrm{~min}\).

Short Answer

Expert verified
The rate constant \(k\) is found to be \(2.49 \times 10^4 \mathrm{~M^{-3}~min^{-1}}\). The half-life for this reaction is 13.33 minutes. The concentration of \(\mathrm{A}\) after \(10.0 \mathrm{~min}\) is \(2.94 \times 10^{-5} \mathrm{M}\) and the concentration of \(\mathrm{B}\) after \(10.0 \mathrm{~min}\) is \(0.998 \mathrm{M}\).

Step by step solution

01

Calculate the change in concentration of A

We need to calculate the change in concentration of A between the initial time and after 3 minutes. The change in concentration of A is given by: $$\Delta[\mathrm{A}] = [\mathrm{A}]_{0} - [\mathrm{A}]_{3}$$ ##Step 2: Calculate the rate of the reaction##
02

Calculate the rate of the reaction

Using the given rate law, we can calculate the rate of the reaction by plugging in the change in concentration of A and the change in time: $$-\frac{\Delta[\mathrm{A}]}{\Delta t} = k[\mathrm{A}]^{2}[\mathrm{B}][\mathrm{C}]$$ ##Step 3: Find the value of k##
03

Find the value of k

We can isolate k by dividing both sides of the equation by the other terms: $$k = -\frac{\Delta[\mathrm{A}]}{\Delta t \cdot [\mathrm{A}]^{2}[\mathrm{B}][\mathrm{C}]}$$ Plug in the values for the change in concentration of A and the initial concentrations of A, B, and C to solve for k. ##Step 4: Calculate the half-life##
04

Calculate the half-life

The half-life can be found using the following formula: $$t_{1/2} = \frac{1}{k[\mathrm{B}]_{0}[\mathrm{C}]_{0}}$$ Substitute the value of k and the initial concentrations of B and C to find the half-life. ##Step 5: Determine the concentration of A after 10 minutes##
05

Determine the concentration of A after 10 minutes

Using the rate law, rearrange the equation to find the concentration of A after 10 minutes. Then, plug in the value of k, the initial concentrations of A, B, and C, and the time of 10 minutes. $$[\mathrm{A}]_{10} = -kt[\mathrm{A}]_{0}^{2}[\mathrm{B}]_{0}[\mathrm{C}]_{0} + [\mathrm{A}]_{0}$$ ##Step 6: Determine the concentration of B after 10 minutes##
06

Determine the concentration of B after 10 minutes

Using the stoichiometry of the reaction (3 moles of A reacts with 1 mole of B), the concentration of B after 10 minutes can be determined by: $$[\mathrm{B}]_{10} = [\mathrm{B}]_{0} - \frac{1}{3}(\Delta[\mathrm{A}])$$ Using the concentration of A after 10 minutes, calculate the concentration of B after 10 minutes.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Reaction Kinetics
Reaction kinetics focuses on the speed or rate at which a chemical reaction happens. In our problem, this is explained by the rate law provided, which works as a mathematical description of how the concentrations of reactants impact the rate of the reaction. The rate law is crucial as it shows how the change in concentration of one or more reactants controls the rate and also helps us understand the reaction mechanism. For the given reaction, the rate is influenced by the concentration of each reactant: A, B, and C. More specifically, the rate is determined using the equation \[-\frac{\Delta[\mathrm{A}]}{\Delta t} = k[\mathrm{A}]^{2}[\mathrm{B}][\mathrm{C}]\]where the concentrations of B and C linearly affect the rate, while the concentration of A affects it quadratically. Understanding this lets us predict how the reaction proceeds in different scenarios.
Half-life Calculation
The half-life of a reaction is the time it takes for the concentration of a reactant to decrease to half its initial value. In the context of this reaction, it tells us how quickly substance A is consumed. The problem solution uses the formula geared toward second-order reactions:\[t_{1/2} = \frac{1}{k[\mathrm{B}]_{0}[\mathrm{C}]_{0}}\]This formula demonstrates that the half-life is inversely related to both the rate constant \(k\) and the initial concentrations of reactants B and C. Longer half-lives mean the reaction is slow, while shorter half-lives indicate a fast reaction. Calculating this enables us to understand not only the speed of the reaction but also how frequent adjustments or calculations might need to be when monitoring the actual reaction process.
Concentration Change
Concentration change in a reaction provides insight into how much reactants are transforming over time. In this exercise, calculating changes in concentration involves young scientists exploring how concentrations of reactants A and B change over particular periods, like 3 and 10 minutes.First, we find the change in concentration of A after a specified time by using:\[\Delta[\mathrm{A}] = [\mathrm{A}]_{0} - [\mathrm{A}]_{\text{final}}\]For determining future concentrations, the rate law equation can adapt to solve for unknowns at specific times. This involves algebraic manipulations. By understanding these concepts, one can effectively deduce not only what happens to A but what remains from B using stoichiometric ratios, essential for complex real-life chemical calculations and predictions.
Stoichiometry
Stoichiometry involves the calculation of reactants and products in chemical reactions, ensuring mass conservation. Here, the stoichiometric coefficients in the balanced chemical equation (3A + B + C → D + E) indicate that 3 moles of A react with 1 mole of B. It reflects a mole relationship crucial for calculating concentration changes for the reactants. The concentration of B after 10 minutes, once A's concentration is known, is computed using:\[[\mathrm{B}]_{10} = [\mathrm{B}]_{0} - \frac{1}{3}(\Delta[\mathrm{A}])\]This stoichiometric ratio (1 mole of B per 3 moles of A) allows chemists to understand how the consumption of one reactant affects another. Grasping stoichiometry allows advanced problem-solving and optimizations regarding resource usage and prediction of product yields in both theoretical and practical settings.

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Most popular questions from this chapter

The rate constant \((k)\) depends on which of the following (there may be more than one answer)? a. the concentration of the reactants b. the nature of the reactants c. the temperature d. the order of the reaction Explain.

A reaction of the form \(\mathrm{aA} \longrightarrow\) Products gives a plot of \(\ln [\mathrm{A}]\) versus time (in seconds), which is a straight line with a slope of \(-7.35 \times 10^{-3}\). Assuming \([\mathrm{A}]_{0}=\) \(0.0100 M\), calculate the time (in seconds) required for the reaction to reach \(22.9 \%\) completion.

Consider the general reaction $$ \mathrm{aA}+\mathrm{bB} \longrightarrow \mathrm{cC} $$ and the following average rate data over some time period \(\Delta t\) : $$ \begin{aligned} -\frac{\Delta \mathrm{A}}{\Delta t} &=0.0080 \mathrm{~mol} / \mathrm{L} \cdot \mathrm{s} \\ -\frac{\Delta \mathrm{B}}{\Delta t} &=0.0120 \mathrm{~mol} / \mathrm{L} \cdot \mathrm{s} \\ \frac{\Delta \mathrm{C}}{\Delta t} &=0.0160 \mathrm{~mol} / \mathrm{L} \cdot \mathrm{s} \end{aligned} $$ Determine a set of possible coefficients to balance this general reaction.

The reaction $$ \mathrm{A} \longrightarrow \mathrm{B}+\mathrm{C} $$ is known to be zero order in \(\mathrm{A}\) and to have a rate constant of \(5.0 \times 10^{-2} \mathrm{~mol} / \mathrm{L} \cdot \mathrm{s}\) at \(25^{\circ} \mathrm{C}\). An experiment was run at \(25^{\circ} \mathrm{C}\) where \([\mathrm{A}]_{0}=1.0 \times 10^{-3} M\) a. Write the integrated rate law for this reaction. b. Calculate the half-life for the reaction. c. Calculate the concentration of \(\mathrm{B}\) after \(5.0 \times 10^{-3} \mathrm{~s}\) has elapsed assuming \([\mathrm{B}]_{0}=0\).

Upon dissolving \(\operatorname{InCl}(s)\) in \(\mathrm{HCl}, \operatorname{In}^{+}(a q)\) undergoes a disproportionation reaction according to the following unbalanced equation: $$ \operatorname{In}^{+}(a q) \longrightarrow \operatorname{In}(s)+\operatorname{In}^{3+}(a q) $$ This disproportionation follows first-order kinetics with a half-life of \(667 \mathrm{~s}\). What is the concentration of \(\operatorname{In}^{+}(a q)\) after \(1.25 \mathrm{~h}\) if the initial solution of \(\mathrm{In}^{+}(a q)\) was prepared by dissolving \(2.38 \mathrm{~g} \operatorname{InCl}(s)\) in dilute \(\mathrm{HCl}\) to make \(5.00 \times 10^{2} \mathrm{~mL}\) of solution? What mass of \(\operatorname{In}(s)\) is formed after \(1.25 \mathrm{~h}\) ?

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