/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 44 Which solvent, water or hexane \... [FREE SOLUTION] | 91影视

91影视

Which solvent, water or hexane \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right)\), would you choose to dissolve each of the following? a. \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}\) d. \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{CH}_{2} \mathrm{OH}\) b. \(\mathrm{CS}_{2}\) e. \(\mathrm{HCl}\) c. \(\mathrm{CH}_{3} \mathrm{OH}\) f. \(\mathrm{C}_{6} \mathrm{H}_{6}\)

Short Answer

Expert verified
a. Water d. Hexane b. Hexane e. Water c. Water f. Hexane

Step by step solution

01

Identify the polarity of solvents

Water is a polar solvent, as oxygen is more electronegative than hydrogen, leading to a partial negative charge on oxygen and a partial positive charge on hydrogen atoms. Hexane, on the other hand, is a nonpolar solvent comprised of carbon and hydrogen atoms only, with minimal differences in electronegativity, and therefore no significant positive or negative charges on the molecule.
02

Identify the polarity of each compound

a. Copper nitrate (Cu(NO鈧)鈧) is a polar compound as it contains ionic bonds between copper (Cu虏鈦) and nitrate (NO鈧) ions. d. CH鈧(CH鈧)鈧佲倖CH鈧侽H is a large nonpolar hydrocarbon with a small polar hydroxyl (-OH) group at the end, so it's mostly nonpolar. b. Carbon disulfide (CS鈧) is a nonpolar compound as both carbon and sulfur have similar electronegativities, and there is no charge separation within the molecule. e. Hydrogen chloride (HCl) is a polar compound due to the electronegativity difference between hydrogen and chlorine atoms, leading to a partial positive charge on hydrogen and a partial negative charge on chlorine. c. Methanol (CH鈧僌H) is a polar compound due to the electronegativity difference between oxygen and hydrogen atoms in the hydroxyl group. f. Benzene (C鈧咹鈧) is a nonpolar compound comprising carbon and hydrogen atoms only, with no significant electronegativity difference.
03

Determine which solvent would be a better choice

a. For Cu(NO鈧)鈧, choose water as the solvent because both are polar. d. For CH鈧(CH鈧)鈧佲倖CH鈧侽H, choose hexane as the solvent because the molecule is mostly nonpolar. b. For CS鈧, choose hexane as the solvent because both are nonpolar. e. For HCl, choose water as the solvent because both are polar. c. For CH鈧僌H, choose water as the solvent because both are polar. f. For C鈧咹鈧, choose hexane as the solvent because both are nonpolar.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Polar and Nonpolar Compounds
Understanding the difference between polar and nonpolar compounds is crucial in chemistry. This distinction often determines how substances interact with each other.

Polar compounds have molecules that possess distinct regions of positive and negative charge. This occurs due to differences in electronegativity between atoms, such as in water (H鈧侽) where the oxygen atom is more electronegative than hydrogen. This imbalance creates a dipole moment, leading to one side of the molecule being more positive and the other more negative.

On the other hand, nonpolar compounds have molecules with symmetrical charge distribution, resulting in no distinct positive or negative regions. In nonpolar molecules such as hexane (C鈧咹鈧佲倓) or benzene (C鈧咹鈧), the atoms have similar electronegativities and share electrons more equally. This lack of poles means these compounds can share electrons freely, without tugging them towards one side.

Knowing whether a compound is polar or nonpolar helps predict how it will behave in solutions, especially when deciding which solvent to use.
Solubility in Chemistry
Solubility is a key concept in chemistry that describes how well a substance dissolves in a solvent. The principle "like dissolves like" usually applies, meaning that polar substances tend to dissolve well in polar solvents and nonpolar substances dissolve well in nonpolar solvents.

This principle can be observed when trying to dissolve ionic compounds such as copper nitrate (Cu(NO鈧)鈧) in water. Because both are polar, the water molecules interact with the charged particles in copper nitrate, making it soluble.

Conversely, nonpolar solvents, such as hexane, are effective at dissolving other nonpolar substances, like carbon disulfide (CS鈧) or benzene (C鈧咹鈧). These substances have similar molecular structures that allow them to combine without strong attractions to polar molecules or ions.

Understanding solubility is vital for predicting reactions and behaviors of substances in natural and controlled environments. Whether you鈥檙e working in the lab or cooking a meal, knowing what dissolves in what can be extremely useful.
Solvent Selection
Choosing the right solvent is essential in many chemical processes, whether in research, industry, or daily applications. Solvent selection is mainly guided by the polarity of both the solvent and the solute involved.

For example, polar solvents like water are excellent at dissolving other polar solutes or ionic compounds due to their ability to stabilize different charges. When dealing with a substance like methanol (CH鈧僌H), which is polar, water is an effective solvent.

Meanwhile, nonpolar solvents like hexane work best with nonpolar solutes since there's no attraction to polar molecules to disrupt their structure. This is why nonpolar compounds like CH鈧(CH鈧)鈧佲倖CH鈧侽H or benzene dissolve well in hexane.

In scenarios where the solute can have both polar and nonpolar characteristics, the dominant portion of the molecule usually dictates the best solvent choice. For instance, long-chain alcohols with a nonpolar body and a polar head might be better dissolved in a nonpolar solvent.

Solvent selection is not always straightforward, but recognizing the relationship between solute and solvent polarity helps guide effective decision-making in practical applications.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

You drop an ice cube (made from pure water) into a saltwater solution at \(0^{\circ} \mathrm{C}\). Explain what happens and why.

Calculate the freezing point and the boiling point of each of the following aqueous solutions. (Assume complete dissociation.) a. \(0.050 \mathrm{~m} \mathrm{MgCl}_{2}\) b. \(0.050 \mathrm{~m} \mathrm{FeCl}_{3}\)

A \(2.00-\mathrm{g}\) sample of a large biomolecule was dissolved in \(15.0 \mathrm{~g}\) carbon tetrachloride. The boiling point of this solution was determined to be \(77.85^{\circ} \mathrm{C}\). Calculate the molar mass of the biomolecule. For carbon tetrachloride, the boiling-point constant is \(5.03^{\circ} \mathrm{C} \cdot \mathrm{kg} / \mathrm{mol}\), and the boiling point of pure carbon tetrachloride is \(76.50^{\circ} \mathrm{C}\).

Consider the following solutions: \(0.010 \mathrm{~m} \mathrm{Na}_{3} \mathrm{PO}_{4}\) in water \(0.020 \mathrm{~m} \mathrm{CaBr}_{2}\) in water \(0.020 \mathrm{~m} \mathrm{KCl}\) in water \(0.020 \mathrm{~m} \mathrm{HF}\) in water \((\mathrm{HF}\) is a weak acid. \()\) a. Assuming complete dissociation of the soluble salts, which solution(s) would have the same boiling point as \(0.040 \mathrm{~m} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) in water? \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) is a nonelectrolyte. b. Which solution would have the highest vapor pressure at \(28^{\circ} \mathrm{C}\) ? c. Which solution would have the largest freezing-point depression?

A solid mixture contains \(\mathrm{MgCl}_{2}\) and NaCl. When \(0.5000 \mathrm{~g}\) of this solid is dissolved in enough water to form \(1.000 \mathrm{~L}\) of solution, the osmotic pressure at \(25.0^{\circ} \mathrm{C}\) is observed to be \(0.3950\) atm. What is the mass percent of \(\mathrm{MgCl}_{2}\) in the solid? (Assume ideal behavior for the solution.)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.