Chapter 6: Problem 22
Explain the advantages and disadvantages of hydrogen as an alternative fuel.
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Chapter 6: Problem 22
Explain the advantages and disadvantages of hydrogen as an alternative fuel.
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A coffee-cup calorimeter initially contains \(125 \mathrm{~g}\) water at \(24.2^{\circ} \mathrm{C}\). Potassium bromide \((10.5 \mathrm{~g})\), also at \(24.2^{\circ} \mathrm{C}\), is added to the water, and after the KBr dissolves, the final temperature is \(21.1^{\circ} \mathrm{C}\). Calculate the enthalpy change for dissolving the salt in \(\mathrm{J} / \mathrm{g}\) and \(\mathrm{kJ} / \mathrm{mol}\). Assume that the specific heat capacity of the solution is \(4.18 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) and that no heat is transferred to the surroundings or to the calorimeter.
The overall reaction in a commercial heat pack can be represented as $$ 4 \mathrm{Fe}(s)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{Fe}_{2} \mathrm{O}_{3}(s) \quad \Delta H=-1652 \mathrm{~kJ} $$ a. How much heat is released when \(4.00 \mathrm{~mol}\) iron is reacted with excess \(\mathrm{O}_{2}\) ? b. How much heat is released when \(1.00 \mathrm{~mol} \mathrm{Fe}_{2} \mathrm{O}_{3}\) is produced? c. How much heat is released when \(1.00 \mathrm{~g}\) iron is reacted with excess \(\mathrm{O}_{2} ?\) d. How much heat is released when \(10.0 \mathrm{~g} \mathrm{Fe}\) and \(2.00 \mathrm{~g} \mathrm{O}_{2}\) are reacted?
It takes \(585 \mathrm{~J}\) of energy to raise the temperature of \(125.6 \mathrm{~g}\) mercury from \(20.0^{\circ} \mathrm{C}\) to \(53.5^{\circ} \mathrm{C}\). Calculate the specific heat capacity and the molar heat capacity of mercury.
Given the following data $$ \begin{aligned} 2 \mathrm{ClF}(g)+\mathrm{O}_{2}(g) & \longrightarrow \mathrm{Cl}_{2} \mathrm{O}(g)+\mathrm{F}_{2} \mathrm{O}(g) & \Delta H &=167.4 \mathrm{~kJ} \\ 2 \mathrm{ClF}_{3}(g)+2 \mathrm{O}_{2}(g) & \longrightarrow \mathrm{Cl}_{2} \mathrm{O}(g)+3 \mathrm{~F}_{2} \mathrm{O}(g) & \Delta H &=341.4 \mathrm{~kJ} \\\ 2 \mathrm{~F}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{~F}_{2} \mathrm{O}(g) & \Delta H &=-43.4 \mathrm{~kJ} \end{aligned} $$ calculate \(\Delta H\) for the reaction $$ \mathrm{ClF}(g)+\mathrm{F}_{2}(g) \longrightarrow \mathrm{ClF}_{3}(g) $$
Assume that \(4.19 \times 10^{6} \mathrm{~kJ}\) of energy is needed to heat a home. If this energy is derived from the combustion of methane \(\left(\mathrm{CH}_{4}\right)\), what volume of methane, measured at STP, must be burned? \(\left(\Delta H_{\text {combustion }}^{\circ}\right.\) for \(\mathrm{CH}_{4}=-891 \mathrm{~kJ} / \mathrm{mol}\) )
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