Chapter 6: Problem 22
Explain the advantages and disadvantages of hydrogen as an alternative fuel.
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Chapter 6: Problem 22
Explain the advantages and disadvantages of hydrogen as an alternative fuel.
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Given the following data $$ \begin{aligned} 2 \mathrm{ClF}(g)+\mathrm{O}_{2}(g) & \longrightarrow \mathrm{Cl}_{2} \mathrm{O}(g)+\mathrm{F}_{2} \mathrm{O}(g) & \Delta H &=167.4 \mathrm{~kJ} \\ 2 \mathrm{ClF}_{3}(g)+2 \mathrm{O}_{2}(g) & \longrightarrow \mathrm{Cl}_{2} \mathrm{O}(g)+3 \mathrm{~F}_{2} \mathrm{O}(g) & \Delta H &=341.4 \mathrm{~kJ} \\\ 2 \mathrm{~F}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{~F}_{2} \mathrm{O}(g) & \Delta H &=-43.4 \mathrm{~kJ} \end{aligned} $$ calculate \(\Delta H\) for the reaction $$ \mathrm{ClF}(g)+\mathrm{F}_{2}(g) \longrightarrow \mathrm{ClF}_{3}(g) $$
Consider \(5.5 \mathrm{~L}\) of a gas at a pressure of \(3.0 \mathrm{~atm}\) in a cylinder with a movable piston. The external pressure is changed so that the volume changes to \(10.5 \mathrm{~L}\). a. Calculate the work done, and indicate the correct sign. b. Use the preceding data but consider the process to occur in two steps. At the end of the first step, the volume is \(7.0 \mathrm{~L}\). The second step results in a final volume of \(10.5\) L. Calculate the work done, and indicate the correct sign. c. Calculate the work done if after the first step the volume is \(8.0 \mathrm{~L}\) and the second step leads to a volume of \(10.5 \mathrm{~L}\). Does the work differ from that in part b? Explain.
Given the following data $$ \begin{array}{ll} \mathrm{NH}_{3}(g) \longrightarrow \frac{1}{2} \mathrm{~N}_{2}(g)+\frac{3}{2} \mathrm{H}_{2}(g) & \Delta H=46 \mathrm{~kJ} \\ 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g) & \Delta H=-484 \mathrm{~kJ} \end{array} $$ calculate \(\Delta H\) for the reaction $$ 2 \mathrm{~N}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \longrightarrow 3 \mathrm{O}_{2}(g)+4 \mathrm{NH}_{3}(g) $$ On the basis of the enthalpy change, is this a useful reaction for the synthesis of ammonia?
The combustion of \(0.1584 \mathrm{~g}\) benzoic acid increases the temperature of a bomb calorimeter by \(2.54^{\circ} \mathrm{C}\). Calculate the heat capacity of this calorimeter. (The energy released by combustion of benzoic acid is \(26.42 \mathrm{~kJ} / \mathrm{g} .\) ) A \(0.2130-\mathrm{g}\) sample of vanillin \(\left(\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}_{3}\right)\) is then burned in the same calorimeter, and the temperature increases by \(3.25^{\circ} \mathrm{C}\). What is the energy of combustion per gram of vanillin? Per mole of vanillin?
Calculate the kinetic energy of a baseball (mass \(=5.25 \mathrm{oz}\) ) with a velocity of \(1.0 \times 10^{2} \mathrm{mi} / \mathrm{h}\).
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