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What mass of \(\mathrm{Na}_{2} \mathrm{CrO}_{4}\) is required to precipitate all of the silver ions from \(75.0 \mathrm{~mL}\) of a \(0.100 M\) solution of \(\mathrm{AgNO}_{3}\) ?

Short Answer

Expert verified
To precipitate all the silver ions from a \(75.0\,\mathrm{mL}\) solution of \(0.100\, \mathrm{M}\, \mathrm{AgNO}_{3}\), approximately \(0.607\, \mathrm{g}\) of \(\mathrm{Na}_{2} \mathrm{CrO}_{4}\) is required.

Step by step solution

01

Write the balanced chemical equation

The reaction that occurs when sodium chromate (Na鈧侰rO鈧) reacts with silver nitrate (AgNO鈧) to precipitate silver ions (Ag鈦) can be described by the following balanced chemical equation: \[2 AgNO_3(aq) + Na_2CrO_4(aq) \rightarrow Ag_2CrO_4(s) + 2 NaNO_3(aq)\]
02

Find the moles of AgNO鈧 in the given solution

We are given the volume (\(75.0\,\text{mL}\)) and concentration (\(0.100\,\text{M}\)) of the AgNO鈧 solution. We can use these values to calculate the moles of AgNO鈧 in the solution. Moles = Molarity 脳 Volume The volume needs to be converted to liters, so \(\text{Volume} = 75.0\,\text{mL} \times \frac{1 \,\text{L}}{1000\, \text{mL}} = 0.075\, \text{L}\). Then, Moles of AgNO鈧 = \(0.100\, \text{M} \times 0.075\, \text{L} = 0.0075\, \text{mol}\)
03

Find the moles of Na鈧侰rO鈧 required to precipitate all the Ag鈦 ions

From the balanced chemical equation, we can see that 2 moles of AgNO鈧 react with 1 mole of Na鈧侰rO鈧 to form 2 moles of NaNO鈧 and 1 mole of Ag鈧侰rO鈧. So, the mole ratio of AgNO鈧 to Na鈧侰rO鈧 is 2:1. To find the moles of Na鈧侰rO鈧 required to precipitate all the silver ions, we can use this mole ratio: Moles of Na鈧侰rO鈧 = \(\text{Moles of AgNO鈧儅 \, \times \, \frac{1\, \text{mol Na鈧侰rO鈧剗}{2\, \text{mol AgNO鈧儅} = 0.0075\, \text{mol} \, \times \, \frac{1}{2} = 0.00375\, \text{mol}\)
04

Calculate the mass of Na鈧侰rO鈧 needed

Now that we know the moles of Na鈧侰rO鈧 required, we can calculate the mass of Na鈧侰rO鈧 using its molar mass. The molar mass of Na鈧侰rO鈧 is approximately \(2(22.99) + 51.996 + 4(16.00) = 161.984\, \text{g/mol}\). Then, Mass of Na鈧侰rO鈧 = \(\text{Moles of Na鈧侰rO鈧剗 \, \times \, \text{Molar mass of Na鈧侰rO鈧剗 = 0.00375\, \text{mol} \, \times \, 161.984\, \text{g/mol} = 0.607\, \text{g}\) So, the mass of Na鈧侰rO鈧 required to precipitate all the silver ions from a \(75.0\,\mathrm{mL}\) solution of \(0.100\, \mathrm{M}\, \mathrm{AgNO}_{3}\) is approximately \(0.607\, \mathrm{g}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Moles Calculation
In chemistry, moles serve as a bridge between the atomic world and the macroscopic amounts we handle in the lab. To perform moles calculation, it is important to understand that the "mole" relates to Avogadro's number, which is approximately \(6.022 \times 10^{23}\). This number signifies the quantity of atoms, ions, or molecules in one mole of a substance.
To find moles in a solution, you use the relation:
  • Moles = Molarity \(\times\) Volume
The molarity gives the concentration of a solution, expressed as moles per liter, and the volume must be in liters to ensure consistency. For example, if you have 0.100 M (molar) solution and 75.0 mL of this solution, you first convert the volume to liters by dividing by 1000, giving 0.075 L. Then, multiplying the molarity by this volume provides the number of moles of the solution, which in our case of AgNO鈧, is \(0.100\,\text{M} \times 0.075\,\text{L} = 0.0075\,\text{mol}\).
Understanding moles calculation is crucial as it lets you quantify chemicals in practical laboratory scenarios, facilitating further calculations like mass or concentration conversions.
Balanced Chemical Equation
The balanced chemical equation is essential in any chemical reaction analysis as it provides the stoichiometric relationship between the reactants and products. This balance respects the Law of Conservation of Mass, meaning all atoms present in the reactants must be accounted for in the products.
When sodium chromate \((\text{Na}_2\text{CrO}_4)\) reacts with silver nitrate \((\text{AgNO}_3)\), the products formed are silver chromate \((\text{Ag}_2\text{CrO}_4)\) and sodium nitrate \((\text{NaNO}_3)\). Our balanced equation:
  • \[2 \text{AgNO}_3 (aq) + \text{Na}_2\text{CrO}_4 (aq) \rightarrow \text{Ag}_2\text{CrO}_4 (s) + 2 \text{NaNO}_3 (aq)\]
highlights the stoichiometry required: two moles of silver nitrate react with one mole of sodium chromate. Balancing equations requires adjusting the coefficients before each compound until the same number of each type of atom appears on both sides of the equation. This equation ensures accurate calculations for further investigations and predicts the amounts of reactants needed or products formed in a reaction, enhancing the efficiency of experimental setups.
Precipitation Reaction
A precipitation reaction is a type of chemical reaction occurring when two soluble ions in separate solutions combine to form an insoluble compound, which settles from the solution as a solid, known as a precipitate.
In our case, when sodium chromate \((\text{Na}_2\text{CrO}_4)\) and silver nitrate \((\text{AgNO}_3)\) are mixed, the silver ions \((\text{Ag}^+)\) react with chromate ions \((\text{CrO}_4^{2-})\) to form silver chromate \((\text{Ag}_2\text{CrO}_4)\), a bright red precipitate.
  • This process is key in removing or separating components from a solution.
  • The reaction: \[2 \text{AgNO}_3 (aq) + \text{Na}_2\text{CrO}_4 (aq) \rightarrow \text{Ag}_2\text{CrO}_4 (s) + 2 \text{NaNO}_3 (aq)\]
shows the formation of a precipitate of \(\text{Ag}_2\text{CrO}_4\). Precipitation reactions are crucial in various applications such as water purification, chemical analysis, and manufacturing processes where specific substances need to be extracted from mixtures.

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Most popular questions from this chapter

When hydrochloric acid reacts with magnesium metal, hydrogen gas and aqueous magnesium chloride are produced. What volume of \(5.0 M \mathrm{HCl}\) is required to react completely with \(3.00 \mathrm{~g}\) of magnesium?

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