Chapter 4: Problem 55
What mass of \(\mathrm{Na}_{2} \mathrm{CrO}_{4}\) is required to precipitate all of the silver ions from \(75.0 \mathrm{~mL}\) of a \(0.100 M\) solution of \(\mathrm{AgNO}_{3}\) ?
Short Answer
Expert verified
To precipitate all the silver ions from a \(75.0\,\mathrm{mL}\) solution of \(0.100\, \mathrm{M}\, \mathrm{AgNO}_{3}\), approximately \(0.607\, \mathrm{g}\) of \(\mathrm{Na}_{2} \mathrm{CrO}_{4}\) is required.
Step by step solution
01
Write the balanced chemical equation
The reaction that occurs when sodium chromate (Na鈧侰rO鈧) reacts with silver nitrate (AgNO鈧) to precipitate silver ions (Ag鈦) can be described by the following balanced chemical equation:
\[2 AgNO_3(aq) + Na_2CrO_4(aq) \rightarrow Ag_2CrO_4(s) + 2 NaNO_3(aq)\]
02
Find the moles of AgNO鈧 in the given solution
We are given the volume (\(75.0\,\text{mL}\)) and concentration (\(0.100\,\text{M}\)) of the AgNO鈧 solution. We can use these values to calculate the moles of AgNO鈧 in the solution.
Moles = Molarity 脳 Volume
The volume needs to be converted to liters, so \(\text{Volume} = 75.0\,\text{mL} \times \frac{1 \,\text{L}}{1000\, \text{mL}} = 0.075\, \text{L}\). Then,
Moles of AgNO鈧 = \(0.100\, \text{M} \times 0.075\, \text{L} = 0.0075\, \text{mol}\)
03
Find the moles of Na鈧侰rO鈧 required to precipitate all the Ag鈦 ions
From the balanced chemical equation, we can see that 2 moles of AgNO鈧 react with 1 mole of Na鈧侰rO鈧 to form 2 moles of NaNO鈧 and 1 mole of Ag鈧侰rO鈧. So, the mole ratio of AgNO鈧 to Na鈧侰rO鈧 is 2:1. To find the moles of Na鈧侰rO鈧 required to precipitate all the silver ions, we can use this mole ratio:
Moles of Na鈧侰rO鈧 = \(\text{Moles of AgNO鈧儅 \, \times \, \frac{1\, \text{mol Na鈧侰rO鈧剗}{2\, \text{mol AgNO鈧儅} = 0.0075\, \text{mol} \, \times \, \frac{1}{2} = 0.00375\, \text{mol}\)
04
Calculate the mass of Na鈧侰rO鈧 needed
Now that we know the moles of Na鈧侰rO鈧 required, we can calculate the mass of Na鈧侰rO鈧 using its molar mass. The molar mass of Na鈧侰rO鈧 is approximately \(2(22.99) + 51.996 + 4(16.00) = 161.984\, \text{g/mol}\). Then,
Mass of Na鈧侰rO鈧 = \(\text{Moles of Na鈧侰rO鈧剗 \, \times \, \text{Molar mass of Na鈧侰rO鈧剗 = 0.00375\, \text{mol} \, \times \, 161.984\, \text{g/mol} = 0.607\, \text{g}\)
So, the mass of Na鈧侰rO鈧 required to precipitate all the silver ions from a \(75.0\,\mathrm{mL}\) solution of \(0.100\, \mathrm{M}\, \mathrm{AgNO}_{3}\) is approximately \(0.607\, \mathrm{g}\).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Moles Calculation
In chemistry, moles serve as a bridge between the atomic world and the macroscopic amounts we handle in the lab. To perform moles calculation, it is important to understand that the "mole" relates to Avogadro's number, which is approximately \(6.022 \times 10^{23}\). This number signifies the quantity of atoms, ions, or molecules in one mole of a substance.
To find moles in a solution, you use the relation:
Understanding moles calculation is crucial as it lets you quantify chemicals in practical laboratory scenarios, facilitating further calculations like mass or concentration conversions.
To find moles in a solution, you use the relation:
- Moles = Molarity \(\times\) Volume
Understanding moles calculation is crucial as it lets you quantify chemicals in practical laboratory scenarios, facilitating further calculations like mass or concentration conversions.
Balanced Chemical Equation
The balanced chemical equation is essential in any chemical reaction analysis as it provides the stoichiometric relationship between the reactants and products. This balance respects the Law of Conservation of Mass, meaning all atoms present in the reactants must be accounted for in the products.
When sodium chromate \((\text{Na}_2\text{CrO}_4)\) reacts with silver nitrate \((\text{AgNO}_3)\), the products formed are silver chromate \((\text{Ag}_2\text{CrO}_4)\) and sodium nitrate \((\text{NaNO}_3)\). Our balanced equation:
When sodium chromate \((\text{Na}_2\text{CrO}_4)\) reacts with silver nitrate \((\text{AgNO}_3)\), the products formed are silver chromate \((\text{Ag}_2\text{CrO}_4)\) and sodium nitrate \((\text{NaNO}_3)\). Our balanced equation:
- \[2 \text{AgNO}_3 (aq) + \text{Na}_2\text{CrO}_4 (aq) \rightarrow \text{Ag}_2\text{CrO}_4 (s) + 2 \text{NaNO}_3 (aq)\]
Precipitation Reaction
A precipitation reaction is a type of chemical reaction occurring when two soluble ions in separate solutions combine to form an insoluble compound, which settles from the solution as a solid, known as a precipitate.
In our case, when sodium chromate \((\text{Na}_2\text{CrO}_4)\) and silver nitrate \((\text{AgNO}_3)\) are mixed, the silver ions \((\text{Ag}^+)\) react with chromate ions \((\text{CrO}_4^{2-})\) to form silver chromate \((\text{Ag}_2\text{CrO}_4)\), a bright red precipitate.
In our case, when sodium chromate \((\text{Na}_2\text{CrO}_4)\) and silver nitrate \((\text{AgNO}_3)\) are mixed, the silver ions \((\text{Ag}^+)\) react with chromate ions \((\text{CrO}_4^{2-})\) to form silver chromate \((\text{Ag}_2\text{CrO}_4)\), a bright red precipitate.
- This process is key in removing or separating components from a solution.
- The reaction: \[2 \text{AgNO}_3 (aq) + \text{Na}_2\text{CrO}_4 (aq) \rightarrow \text{Ag}_2\text{CrO}_4 (s) + 2 \text{NaNO}_3 (aq)\]