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When the following solutions are mixed together, what precipitate (if any) will form? a. \(\mathrm{Hg}_{2}\left(\mathrm{NO}_{3}\right)_{2}(a q)+\mathrm{CuSO}_{4}(a q)\) b. \(\mathrm{Ni}\left(\mathrm{NO}_{3}\right)_{2}(a q)+\mathrm{CaCl}_{2}(a q)\) c. \(\mathrm{K}_{2} \mathrm{CO}_{3}(a q)+\mathrm{MgI}_{2}(a q)\) d. \(\mathrm{Na}_{2} \mathrm{CrO}_{4}(a q)+\mathrm{AlBr}_{3}(a q)\)

Short Answer

Expert verified
When the following solutions are mixed together, these precipitates will form: a. \(Hg_{2}SO_{4}\) b. No precipitate c. \(MgCO_{3}\) d. \(Al_{2}(CrO_{4})_{3}\)

Step by step solution

01

Write Double Replacement Reactions

Write the balanced double replacement reactions for each pair of solutions: a. \(Hg_{2}(NO_{3})_{2}(aq) + CuSO_{4}(aq) \rightarrow Hg_{2}SO_{4}(s?) + Cu(NO_{3})_{2}(aq) \) b. \(Ni(NO_{3})_{2}(aq) + CaCl_{2}(aq) \rightarrow NiCl_{2}(s?) + Ca(NO_{3})_{2}(aq) \) c. \(K_{2}CO_{3}(aq) + MgI_{2}(aq) \rightarrow MgCO_{3}(s?) + 2KI(aq) \) d. \(Na_{2}CrO_{4}(aq) + AlBr_{3}(aq) \rightarrow Al_{2}(CrO_{4})_{3}(s?) + 6NaBr(aq) \)
02

Apply Solubility Rules

Check the solubility rules for each of the potential precipitates: a. \( Hg_{2}SO_{4} \) - Mercury(I) sulfate is insoluble, so it will form a precipitate. b. \( NiCl_{2} \) - Nickel(II) chloride is soluble, so it will not form a precipitate. c. \( MgCO_{3} \) - Magnesium carbonate is insoluble, so it will form a precipitate. d. \( Al_{2}(CrO_{4})_{3} \) - Aluminum chromate is insoluble, so it will form a precipitate.
03

Identify Precipitates

Identify the precipitate for each reaction: a. Precipitate: \( Hg_{2}SO_{4} \) b. Precipitate: None c. Precipitate: \( MgCO_{3} \) d. Precipitate: \( Al_{2}(CrO_{4})_{3} \) Now, we know the result when each of the mentioned solutions is mixed: a. \(Hg_{2}(NO_{3})_{2}(aq) + CuSO_{4}(aq)\) forms the precipitate \(Hg_{2}SO_{4}\). b. \(Ni(NO_{3})_{2}(aq) + CaCl_{2}(aq)\) forms no precipitate. c. \(K_{2}CO_{3}(aq) + MgI_{2}(aq)\) forms the precipitate \(MgCO_{3}\). d. \(Na_{2}CrO_{4}(aq) + AlBr_{3}(aq)\) forms the precipitate \(Al_{2}(CrO_{4})_{3}\).

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Most popular questions from this chapter

The blood alcohol \(\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}\right)\) level can be determined by titrating a sample of blood plasma with an acidic potassium dichromate solution, resulting in the production of \(\mathrm{Cr}^{3+}(a q)\) and carbon dioxide. The reaction can be monitored because the dichromate ion \(\left(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\right)\) is orange in solution, and the \(\mathrm{Cr}^{3+}\) ion is green. The balanced equation is \(16 \mathrm{H}^{+}(a q)+2 \mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(a q)+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(a q) \longrightarrow\) $$ 4 \mathrm{Cr}^{3+}(a q)+2 \mathrm{CO}_{2}(g)+11 \mathrm{H}_{2} \mathrm{O}(l) $$ This reaction is an oxidation-reduction reaction. What species is reduced, and what species is oxidized? How many electrons are transferred in the balanced equation above?

How would you prepare \(1.00 \mathrm{~L}\) of a \(0.50 M\) solution of each of the following? a. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) from "concentrated" \((18 M)\) sulfuric acid b. \(\mathrm{HCl}\) from "concentrated" \((12 \mathrm{M})\) reagent c. \(\mathrm{NiCl}_{2}\) from the salt \(\mathrm{NiCl}_{2} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) d. HNO \(_{3}\) from "concentrated" (16 M) reagent e. Sodium carbonate from the pure solid

Which of the following solutions of strong electrolytes contains the largest number of ions: \(100.0 \mathrm{~mL}\) of \(0.100 \mathrm{M} \mathrm{NaOH}, 50.0 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{BaCl}_{2}\), or \(75.0 \mathrm{~mL}\) of \(0.150 \mathrm{M} \mathrm{Na}_{4} \mathrm{PO}_{4}\) ?

A student mixes four reagents together, thinking that the solutions will neutralize each other. The solutions mixed together are \(50.0 \mathrm{~mL}\) of \(0.100 M\) hydrochloric acid, \(100.0 \mathrm{~mL}\) of \(0.200 M\) of nitric acid, \(500.0 \mathrm{~mL}\) of \(0.0100 \mathrm{M}\) calcium hydroxide, and \(200.0 \mathrm{~mL}\) of \(0.100 M\) rubidium hydroxide. Did the acids and bases exactly neutralize each other? If not, calculate the concentration of excess \(\mathrm{H}^{+}\) or \(\mathrm{OH}^{-}\) ions left in solution.

A 6.50-g sample of a diprotic acid requires \(137.5 \mathrm{~mL}\) of a \(0.750\) \(M\) NaOH solution for complete neutralization. Determine the molar mass of the acid.

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