Chapter 4: Problem 21
Differentiate between the following terms. a. species reduced versus the reducing agent b. species oxidized versus the oxidizing agent c. oxidation state versus actual charge
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Chapter 4: Problem 21
Differentiate between the following terms. a. species reduced versus the reducing agent b. species oxidized versus the oxidizing agent c. oxidation state versus actual charge
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Many plants are poisonous because their stems and leaves contain oxalic acid \(\left(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\right)\) or sodium oxalate \(\left(\mathrm{Na}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\right)\); when ingested, these substances cause swelling of the respiratory tract and suffocation. A standard analysis for determining the amount of oxalate ion \(\left(\mathrm{C}_{2} \mathrm{O}_{4}{ }^{2-}\right)\) in a sample is to precipitate this species as calcium oxalate, which is insoluble in water. Write the net ionic equation for the reaction between sodium oxalate and calcium chloride \(\left(\mathrm{CaCl}_{2}\right)\) in aqueous solution.
What volume of each of the following bases will react completely with \(25.00 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{HCl}\) ? a. \(0.100 \mathrm{M} \mathrm{NaOH}\) b. \(0.0500 \mathrm{M} \mathrm{Ba}(\mathrm{OH})_{2}\) c. \(0.250 \mathrm{M} \mathrm{KOH}\)
Calcium chloride is a strong electrolyte and is used to "salt" streets in the winter to melt ice and snow. Write a reaction to show how this substance breaks apart when it dissolves in water.
Consider a \(1.50-\mathrm{g}\) mixture of magnesium nitrate and magnesium chloride. After dissolving this mixture in water, \(0.500 \mathrm{M}\) silver nitrate is added dropwise until precipitate formation is complete. The mass of the white precipitate formed is \(0.641 \mathrm{~g}\). a. Calculate the mass percent of magnesium chloride in the mixture. b. Determine the minimum volume of silver nitrate that must have been added to ensure complete formation of the precipitate.
Douglasite is a mineral with the formula \(2 \mathrm{KCl} \cdot \mathrm{FeCl}_{2} \cdot 2 \mathrm{H}_{2} \mathrm{O}\). Calculate the mass percent of douglasite in a \(455.0-\mathrm{mg}\) sample if it took \(37.20 \mathrm{~mL}\) of a \(0.1000 \mathrm{M} \mathrm{AgNO}_{3}\) solution to precipitate all the \(\mathrm{Cl}^{-}\) as \(\mathrm{AgCl}\). Assume the douglasite is the only source of chloride ion.
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