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What number of atoms of nitrogen are present in \(5.00 \mathrm{~g}\) of each of the following? a. glycine, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}_{2} \mathrm{~N}\) b. magnesium nitride c. calcium nitrate d. dinitrogen tetroxide

Short Answer

Expert verified
In 5.00 grams of each compound, there are approximately: a. Glycine: \(4.01 \times 10^{22}\) nitrogen atoms b. Magnesium nitride: \(5.96 \times 10^{22}\) nitrogen atoms c. Calcium nitrate: \(3.68 \times 10^{22}\) nitrogen atoms d. Dinitrogen tetroxide: \(6.54 \times 10^{22}\) nitrogen atoms

Step by step solution

01

a. Glycine, Câ‚‚Hâ‚…Oâ‚‚N

Step 1: Calculate molar mass of glycine The molar mass of glycine is the sum of the molar masses of all its elements: \(M_{glycine} = 2 \times M_{C} + 5 \times M_{H} + 2 \times M_{O} + M_{N}\) Using the standard atomic masses, \(M_{glycine} = 2 \times 12.01 + 5 \times 1.01 + 2 \times 16.00 + 14.01 \approx 75.07 \, g/mol\) Step 2: Calculate moles of glycine Use the given mass and molar mass of glycine to find the number of moles: \(n_{glycine} =\frac{5.00 \, g}{75.07 \, g/mol} \approx 0.0666 \, mol\) Step 3: Calculate number of nitrogen atoms Number of molecules of glycine = moles × Avogadro's number \(\text{Molecules} = 0.0666 \, mol \times 6.022 \times 10^{23} \, mol^{-1} \approx 4.01 \times 10^{22}\, \text{molecules}\) Since there is 1 nitrogen atom in a glycine molecule, Number of nitrogen atoms = number of molecules × nitrogen atoms per molecule \(N_{N} = 4.01 \times 10^{22} \times 1\) So, there are approximately \(4.01 \times 10^{22}\) nitrogen atoms in 5.00 grams of glycine.
02

b. Magnesium nitride, Mg₃N₂

Step 1: Calculate molar mass of magnesium nitride \(M_{Mg_{3}N_{2}} = 3 \times M_{Mg} + 2 \times M_{N}\) \(M_{Mg_{3}N_{2}} = 3 \times 24.31 + 2 \times 14.01 \approx 100.95 \, g/mol\) Step 2: Calculate moles of magnesium nitride \(n_{Mg_{3}N_{2}} = \frac{5.00 \, g}{100.95 \, g/mol} \approx 0.0495 \, mol\) Step 3: Calculate number of nitrogen atoms Number of formula units of magnesium nitride = moles × Avogadro's number \(\text{Formula units} = 0.0495 \, mol \times 6.022 \times 10^{23} \, mol^{-1} \approx 2.98 \times 10^{22} \, \text{formula units}\) Since there are 2 nitrogen atoms in a formula unit of magnesium nitride, Number of nitrogen atoms = formula units × nitrogen atoms per formula unit \(N_{N} = 2.98 \times 10^{22} \times 2\) So, there are approximately \(5.96 \times 10^{22}\) nitrogen atoms in 5.00 grams of magnesium nitride.
03

c. Calcium nitrate, Ca(NO₃)₂

Step 1: Calculate molar mass of calcium nitrate \(M_{Ca(NO_{3})_{2}} = M_{Ca} + 2 \times ( M_{N} + 3 \times M_{O} )\) \(M_{Ca(NO_{3})_{2}} = 40.08 + 2 \times ( 14.01 + 3 \times 16.00 ) \approx 164.09 \, g/mol\) Step 2: Calculate moles of calcium nitrate \(n_{Ca(NO_{3})_{2}} = \frac{5.00 \, g}{164.09 \, g/mol} \approx 0.0305 \, mol\) Step 3: Calculate number of nitrogen atoms Number of formula units of calcium nitrate = moles × Avogadro's number \(\text{Formula units} = 0.0305 \, mol \times 6.022 \times 10^{23} \, mol^{-1} \approx 1.84 \times 10^{22} \, \text{formula units}\) Since there are 2 nitrogen atoms in a formula unit of calcium nitrate, Number of nitrogen atoms = formula units × nitrogen atoms per formula unit \(N_{N} = 1.84 \times 10^{22} \times 2\) So, there are approximately \(3.68 \times 10^{22}\) nitrogen atoms in 5.00 grams of calcium nitrate.
04

d. Dinitrogen tetroxide, Nâ‚‚Oâ‚„

Step 1: Calculate molar mass of dinitrogen tetroxide \(M_{N_{2}O_{4}} = 2 \times M_{N} + 4 \times M_{O}\) \(M_{N_{2}O_{4}} = 2 \times 14.01 + 4 \times 16.00 \approx 92.02 \, g/mol\) Step 2: Calculate moles of dinitrogen tetroxide \(n_{N_{2}O_{4}} = \frac{5.00 \, g}{92.02 \, g/mol} \approx 0.0543 \, mol\) Step 3: Calculate number of nitrogen atoms Number of molecules of dinitrogen tetroxide = moles × Avogadro's number \(\text{Molecules} = 0.0543 \, mol \times 6.022 \times 10^{23} \, mol^{-1} \approx 3.27 \times 10^{22} \, \text{molecules}\) Since there are 2 nitrogen atoms in a molecule of dinitrogen tetroxide, Number of nitrogen atoms = molecules × nitrogen atoms per molecule \(N_{N} = 3.27 \times 10^{22} \times 2\) So, there are approximately \(6.54 \times 10^{22}\) nitrogen atoms in 5.00 grams of dinitrogen tetroxide.

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Arrange the following substances in order of increasing mass percent of carbon. a. caffeine, \(\mathrm{C}_{\mathrm{s}} \mathrm{H}_{10} \mathrm{~N}_{4} \mathrm{O}_{2}\) b. sucrose, \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\) c. ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\)

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In the production of printed circuit boards for the electronics industry, a \(0.60-\mathrm{mm}\) layer of copper is laminated onto an insulating plastic board. Next, a circuit pattern made of a chemically resistant polymer is printed on the board. The unwanted copper is removed by chemical etching, and the protective polymer is finally removed by solvents. One etching reaction is \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}(a q)+4 \mathrm{NH}_{3}(a q)+\mathrm{Cu}(s) \longrightarrow 2 \mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}(a q)\) A plant needs to manufacture 10,000 printed circuit boards, each \(8.0 \times 16.0 \mathrm{~cm}\) in area. An average of \(80 . \%\) of the copper is remoyed from each board (density of copper \(=8.96 \mathrm{~g} / \mathrm{cm}^{3}\) ). What masses of \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\) and \(\mathrm{NH}_{3}\) are needed to do this? Assume \(100 \%\) yield.

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