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α-glucose and β-glucose are two isomers of glucose that differ only in the configuration of the hydroxyl group (OH) attached to the first carbon atom (C1) in the cyclic glucose molecule. Both isomers are monosaccharides that can be used as building blocks for polymers.

In α-glucose, the hydroxyl group (OH) on the first carbon atom (C1) is positioned below the plane of the ring. In contrast, in β-glucose, the hydroxyl group (OH) on the first carbon atom (C1) is positioned above the plane of the ring. This difference in orientation is a result of epimerization at the anomeric carbon (C1) during the formation of the cyclic structures.

The structural differences in the arrangement of the hydroxyl group (OH) on the first carbon atom (C1) allow α-glucose molecules to link together to form the polymer amylose, while β-glucose molecules link together to form the polymer cellulose. In the case of amylose, the α-glucose molecules link together via α(1→4) glycosidic bonds, creating a linear chain structure. This glycosidic bond is formed between the hydroxyl group of C1 of one glucose molecule and the hydroxyl group of C4 of the next glucose molecule in the chain. In the case of cellulose, the β-glucose molecules create alternating orientation along the chain. They link together via β(1→4) glycosidic bonds, which are formed between the hydroxyl group of C1 of one glucose molecule and the hydroxyl group of C4 of the next glucose molecule. The alternating arrangement in cellulose allows for hydrogen bonding between parallel chains, providing strength and stability to the structure. The variations in the glycosidic bonds and arrangements in the polymers result in different properties and functions between amylose, which is a primary structural component in starches, and cellulose, which is a primary structural component in plant cell walls.