Chapter 22: Problem 24
Draw the structures for two examples of unsaturated hydrocarbons. What structural feature makes a hydrocarbon unsaturated?
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Chapter 22: Problem 24
Draw the structures for two examples of unsaturated hydrocarbons. What structural feature makes a hydrocarbon unsaturated?
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In glycine, the carboxylic acid group has \(K_{\mathrm{a}}=4.3 \times 10^{-3}\) and the amino group has \(K_{\mathrm{b}}=6.0 \times 10^{-5}\). Use these equilibrium constant values to calculate the equilibrium constants for the following. a. \({ }^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{3} \mathrm{O}^{+}\) b. \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H}+\mathrm{OH}^{-}\) c. \({ }^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}\)
Polystyrene can be made more rigid by copolymerizing styrene with divinylbenzene: How does the divinylbenzene make the copolymer more rigid?
What is wrong with the following names? Give the correct name for each compound. a. 2 -ethylpropane b. 5 -iodo \(-5,6\) -dimethylhexane c. cis-4-methyl-3-pentene d. 2 -bromo- 3 -butanol
Give two examples of saturated hydrocarbons. How many other atoms are bonded to each carbon in a saturated hydrocarbon?
The base sequences in mRNA that code for certain amino acids are Glu: \(\quad\) GAA, GAG Val: GUU, GUC, GUA, GUG Met: \(\quad\) AUG Trp: \(\quad\) UGG Phe: UUU, UUC Asp: \(\quad\) GAU, GAC These sequences are complementary to the sequences in DNA. a. Give the corresponding sequences in DNA for the amino acids listed above. b. Give a DNA sequence that would code for the peptide trp-glu-phe-met. c. How many different DNA sequences can code for the tetrapeptide in part \(\mathrm{b}\) ? d. What is the peptide that is produced from the DNA sequence \(\mathrm{T}-\mathrm{A}-\mathrm{C}-\mathrm{C}-\mathrm{T}-\mathrm{G}-\mathrm{A}-\mathrm{A}-\mathrm{G} ?\) e. What other DNA sequences would yield the same tripeptide as in part \(\mathrm{d}\) ?
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