Chapter 22: Problem 17
Draw a structural formula for each of the following compounds. a. 2 -methylpropane b. 2 -methylbutane c. 2 -methylpentane d. 2 -methylhexane
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Chapter 22: Problem 17
Draw a structural formula for each of the following compounds. a. 2 -methylpropane b. 2 -methylbutane c. 2 -methylpentane d. 2 -methylhexane
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In Section 22.6, three important classes of biologically important natural polymers are discussed. What are the three classes, what are the monomers used to form the polymers, and why are they biologically important?
Choose one of the following terms to match the description given in statements (1)-(17). All of the following pertain to proteins or carbohydrates. a. aldohexose g. disaccharides \(\mathbf{m}\). ketohexoses b. saliva h. disulfide n. oxytocin c. cellulose i. globular o. pleated sheet d. \(\mathrm{CH}_{2} \mathrm{O}\) j. glycogen p. polypeptide e. cysteine \(\mathbf{k}\). glycoside linkage q. primary structure f. denaturation 1\. hydrophobic (1) polymer consisting of many amino acids (2) linkage that forms between two cysteine species (3) peptide hormone that triggers milk secretion (4) proteins with roughly spherical shape (5) sequence of amino acids in a protein (6) silk protein secondary structure (7) water-repelling amino acid side chain (8) amino acid responsible for permanent wave in hair (9) breakdown of a protein's tertiary and/or secondary structure (10) animal polymer of glucose (11) \(-\mathrm{C}-\mathrm{O}-\mathrm{C}-\) bond betwecn rings in disaccharide sugars (12) empirical formula leading to the name carbohydrate (13) where enzymes catalyzing the breakdown of glycoside linkages are found (14) six-carbon ketone sugars (15) structural component of plants, polymer of glucose (16) sugars consisting of two monomer units (17) six-carbon aldehyde sugars
Give an example reaction that would yield the following products as major organic products. See Exercises \(22.62\) and \(22.65\) for some hints. For oxidation reactions, just write oxidation over the arrow and don't worry about the actual reagent. a. primary alcohol b. secondary alcohol c. tertiary alcohol d. aldehyde e. ketone f. carboxylic acid g. ester
In glycine, the carboxylic acid group has \(K_{\mathrm{a}}=4.3 \times 10^{-3}\) and the amino group has \(K_{\mathrm{b}}=6.0 \times 10^{-5}\). Use these equilibrium constant values to calculate the equilibrium constants for the following. a. \({ }^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{3} \mathrm{O}^{+}\) b. \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H}+\mathrm{OH}^{-}\) c. \({ }^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}\)
Draw the structures of the two dipeptides that can be formed from serine and alanine.
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