Chapter 21: Problem 16
Almost all metals in nature are found as ionic compounds in ores instead of being in the pure state. Why? What must be done to a sample of ore to obtain a metal substance that has desirable properties?
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Chapter 21: Problem 16
Almost all metals in nature are found as ionic compounds in ores instead of being in the pure state. Why? What must be done to a sample of ore to obtain a metal substance that has desirable properties?
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BAL is a chelating agent used in treating heavy metal poisoning. It acts as a bidentate ligand. What type of linkage isomers are possible when BAL coordinates to a metal ion?
Draw all geometrical isomers of \(\mathrm{Pt}(\mathrm{CN})_{2} \mathrm{Br}_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\). Which of these isomers has an optical isomer? Draw the various optical isomers.
Draw geometrical isomers of each of the following complex ions. a. \(\left[\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\right]^{-}\) c. \(\left[\operatorname{Ir}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\) b. \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{I}_{2}\right]^{2+}\) d. \(\left[\mathrm{Cr}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{2} \mathrm{I}_{2}\right]^{+}\)
Would it be better to use octahedral \(\mathrm{Ni}^{2+}\) complexes or octahedral \(\mathrm{Cr}^{2+}\) complexes to determine whether a given ligand is a strong-field or weak-field ligand by measuring the number of unpaired electrons? How else could the relative ligand field strengths be determined?
How many unpaired electrons are present in the tetrahedral ion \(\mathrm{FeCl}_{4}^{-} ?\)
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