Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
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Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
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One reason suggested to account for the instability of long chains of silicon atoms is that the decomposition involves the transition state shown below: The activation energy for such a process is \(210 \mathrm{~kJ} / \mathrm{mol}\), which is less than either the \(\mathrm{Si}-\mathrm{Si}\) or \(\mathrm{Si}-\mathrm{H}\) energy. Why would a similar mechanism not be expected to be very important in the decomposition of long carbon chains?
Use bond energies to estimate the maximum wavelength of light that will cause the reaction $$\mathrm{O}_{3} \stackrel{\mathrm{hr}}{\longrightarrow} \mathrm{O}_{2}+\mathrm{O}$$
Compare the Lewis structures with the molecular orbital view of the bonding in \(\mathrm{NO}, \mathrm{NO}^{+}\), and \(\mathrm{NO}^{-}\). Account for any discrepancies between the two models.
The inert-pair effect is sometimes used to explain the tendency of heavier members of Group \(3 \mathrm{~A}\) to exhibit \(+1\) and \(+3\) oxidation states. What does the inert-pair effect reference? (Hint: Consider the valence electron configuration for Group \(3 \mathrm{~A}\) elements.)
What will be the atomic number of the next alkali metal to be discovered? How would you expect the physical properties of the next alkali metal to compare with the properties of the other alkali metals summarized in Table \(20.4 ?\)
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