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Write the formula for each of the following compounds: a. ammonium hydrogen phosphate b. mercury(I) sulfide c. silicon dioxide d. sodium sulfite e. aluminum hydrogen sulfate f. nitrogen trichloride g. hydrobromic acid \(\mathbf{h}\). bromous acid i. perbromic acid j. potassium hydrogen sulfide k. calcium iodide 1\. cesium perchlorate

Short Answer

Expert verified
a. \(NH_4_2HPO_4\) b. \(Hg_2S\) c. \(SiO_2\) d. \(Na_2SO_3\) e. \(Al_2(HSO_4)_6\) f. \(NCl_3\) g. \(HBr\) h. \(HBrO_2\) i. \(HBrO_4\) j. \(KHS\) k. \(CaI_2\) 1. \(CsClO_4\)

Step by step solution

01

a. Ammonium hydrogen phosphate

First, identify the ions involved: ammonium (NH鈧勨伜), hydrogen (H鈦), and phosphate (PO鈧劼斥伝). Next, balance the charges by finding the lowest common multiple of the positive and negative charge magnitudes: LCM(3,1) = 3. Ammonium and hydrogen charges sum up to 3鈦, which balances the phosphate charge of 3鈦. Therefore, the formula is (NH鈧)鈧(HPO鈧) or NH鈧勨倐HPO鈧.
02

b. Mercury(I) sulfide

Identify the ions involved: mercury(I) or mercurous ion (Hg鈧偮测伜) and sulfide (S虏鈦). The ionic charges are already balanced since both have a charge magnitude of 2. The formula for mercury(I) sulfide is Hg鈧係.
03

c. Silicon dioxide

Silicon (Si) has a valency of 4 and oxygen (O) has a valency of 2. Therefore, to balance the valencies, we combine them in a 1:2 ratio, resulting in the formula SiO鈧.
04

d. Sodium sulfite

Sodium (Na鈦) and sulfite (SO鈧兟测伝) ions are involved in this compound. To balance, we need two sodium ions for each sulfite ion. Hence, the formula is Na鈧係O鈧.
05

e. Aluminum hydrogen sulfate

Aluminum (Al鲁鈦), hydrogen (H鈦), and sulfate (SO鈧劼测伝) ions are involved in this compound. The LCM of the charges is 6. We need two aluminum ions and six hydrogen and sulfate ions to balance the charges. The formula is Al鈧(HSO鈧)鈧.
06

f. Nitrogen trichloride

Nitrogen (N) has a valency of 3 and chlorine (Cl) has a valency of 1. Therefore, for a covalent molecule, their ratio should be 1:3. The formula for nitrogen trichloride is NCl鈧.
07

g. Hydrobromic acid

This is a binary acid composed of hydrogen (H鈦) and bromide (Br鈦) ions. The charges balance each other, so the formula for hydrobromic acid is HBr.
08

h. Bromous acid

Bromous acid has an oxyanion - bromite (BrO鈧傗伝). It combines with hydrogen (H鈦) ion in a 1:1 ratio, as the charges are balanced. The formula is HBrO鈧.
09

i. Perbromic acid

Perbromic acid has an oxyanion - perbromate (BrO鈧勨伝). It combines with hydrogen (H鈦) ion in a 1:1 ratio, as the charges are balanced. The formula is HBrO鈧.
10

j. Potassium hydrogen sulfide

Potassium (K鈦) and hydrogen sulfide (HS鈦) ions are involved. Their charges are balanced in a 1:1 ratio. The formula for potassium hydrogen sulfide is KHS.
11

k. Calcium iodide

Calcium (Ca虏鈦) and iodide (I鈦) ions are involved in this compound. To balance the charges, we combine two iodide ions with one calcium ion. The formula is CaI鈧.
12

1. Cesium perchlorate

Cesium (Cs鈦) and perchlorate (ClO鈧勨伝) ions are involved in this compound. Their charges balance each other in a 1:1 ratio, so the formula for cesium perchlorate is CsClO鈧.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Compounds
Ionic compounds are formed by the electrostatic attraction between ions, which are atoms or groups of atoms with a net positive or negative charge. In the creation of ionic compounds, metals typically lose electrons to become positively charged cations, while non-metals gain electrons to become negatively charged anions. The resulting compound is neutral overall, meaning the total positive charge equals the total negative charge. For example, to write the formula for calcium iodide, you would pair the calcium cation (Ca虏鈦) with two iodide anions (I鈦) to balance the charges, resulting in CaI鈧.

Ionic compound formulas are crucial for understanding chemical reactions and properties such as melting points, boiling points, and solubility. To ensure students accurately determine the formulas for ionic compounds, they must first understand the concept of valency and how to balance charges to achieve electrical neutrality.
Covalent Compounds
In stark contrast to ionic compounds, covalent compounds are formed when two or more non-metal atoms share electrons in order to achieve a full outer shell, similar to that of a noble gas. This sharing of electrons leads to the formation of a covalent bond. The resulting molecules exhibit precise ratios of atoms, reflected in their chemical formulas. For instance, nitrogen trichloride is composed of one nitrogen atom and three chlorine atoms. Since nitrogen has a valency of 3 and chlorine has a valency of 1, they combine in a 1:3 ratio to form NCl鈧.

Understanding covalent bonding is key for students to grasp the formation and properties of a wide range of molecules, from simple diatomic elements like O鈧 to complex organic compounds.
Chemical Nomenclature
Chemical nomenclature is the systematic method of naming chemical compounds using a set of standard rules. It allows scientists and students alike to communicate unambiguously about chemical substances. For example, the name 'potassium hydrogen sulfide' directly informs us of the elements involved and the presence of hydrogen, suggesting an acid salt. When we use these names to write chemical formulas, we can reference the rules of nomenclature along with valency to arrive at KHS, the correct formula for potassium hydrogen sulfide.

Students should familiarize themselves with nomenclature rules which include naming for simple and complex ions, molecular compounds, acids, and organic compounds. These rules are essential for interpreting written chemical language into representative formulas and vice versa.
Valency
Valency is an atom's capacity to bond with other atoms. It indicates how many electrons an atom can lose, gain, or share to achieve a stable electron configuration. Metals often have a positive valency, indicating the number of electrons they can lose, while nonmetals have a negative valency, showing how many electrons they can gain or share. For instance, in silicon dioxide (SiO鈧), silicon has a valency of 4 while oxygen has a valency of 2. By sharing electrons, one silicon atom bonds with two oxygen atoms to form a stable compound.

For students to comprehensively understand compound formation, valency is a fundamental concept that underpins the formation of both ionic and covalent bonds. Recognizing the valency of different elements helps in predicting the chemical formulas of compounds they form. Exercise questions often help reinforce this concept through practice.
Oxyanion
An oxyanion is a polyatomic ion that comprises a central atom surrounded by oxygen atoms and carries a net negative charge. These anions are named systematically based on the number of oxygen atoms and the oxidation state of the central atom. The exercise included oxyanions such as phosphate (PO鈧劼斥伝), sulfite (SO鈧兟测伝), and perchlorate (ClO鈧勨伝). In bromous acid (HBrO鈧), the bromite ion (BrO鈧傗伝) is combined with a hydrogen ion to form a weak acid. Students learning to write chemical formulas must understand how to identify and combine oxyanions with other ions, respecting their charge and naming conventions.

To improve student comprehension, introduce examples of common oxyanions like nitrate and sulfate, and show how changing the central atom鈥檚 oxidation state leads to different names and formulas. This understanding is crucial for mastering acid-base chemistry and the behavior of these ions in aqueous solutions.

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Most popular questions from this chapter

From the information in this chapter on the mass of the proton, the mass of the electron, and the sizes of the nucleus and the atom, calculate the densities of a hydrogen nucleus and a hydrogen atom.

Indium oxide contains \(4.784 \mathrm{~g}\) of indium for every \(1.000 \mathrm{~g}\) of oxygen. In 1869 , when Mendeleev first presented his version of the periodic table, he proposed the formula \(\mathrm{In}_{2} \mathrm{O}_{3}\) for indium oxide. Before that time it was thought that the formula was InO. What values for the atomic mass of indium are obtained using these two formulas? Assume that oxygen has an atomic mass of \(16.00\).

Consider the elements of Group \(4 \mathrm{~A}\) (the "carbon family"): \(\mathrm{C}, \mathrm{Si}\), Ge, \(\mathrm{Sn}\), and \(\mathrm{Pb}\). What is the trend in metallic character as one goes down this group? What is the trend in metallic character going from left to right across a period in the periodic table?

You have gone back in time and are working with Dalton on a table of relative masses. Following are his data. \(0.602 \mathrm{~g}\) gas A reacts with \(0.295 \mathrm{~g}\) gas \(\mathrm{B}\) \(0.172 \mathrm{~g}\) gas \(\mathrm{B}\) reacts with \(0.401 \mathrm{~g}\) gas \(\mathrm{C}\) \(0.320 \mathrm{~g}\) gas \(\mathrm{A}\) reacts with \(0.374 \mathrm{~g}\) gas \(\mathrm{C}\) a. Assuming simplest formulas \((\mathrm{AB}, \mathrm{BC}\), and \(\mathrm{AC}\) ), construct a table of relative masses for Dalton. b. Knowing some history of chemistry, you tell Dalton that if he determines the volumes of the gases reacted at constant temperature and pressure, he need not assume simplest formulas. You collect the following data: 6 volumes gas \(A+1\) volume gas \(B \rightarrow 4\) volumes product 1 volume gas \(\mathrm{B}+4\) volumes gas \(\mathrm{C} \rightarrow 4\) volumes product 3 volumes gas \(\mathrm{A}+2\) volumes gas \(\mathrm{C} \rightarrow 6\) volumes product Write the simplest balanced equations, and find the actual relative masses of the elements. Explain your reasoning.

a. Classify the following elements as metals or nonmetals: $$ \begin{array}{lll} \mathrm{Mg} & \mathrm{Si} & \mathrm{Rn} \\ \mathrm{Ti} & \mathrm{Ge} & \mathrm{Eu} \\ \mathrm{Au} & \mathrm{B} & \mathrm{Am} \\ \mathrm{Bi} & \mathrm{At} & \mathrm{Br} \end{array} $$ b. The distinction between metals and nonmetals is really not a clear one. Some elements, called metalloids, are intermediate in their properties. Which of these elements would you reclassify as metalloids? What other elements in the periodic table would you expect to be metalloids?

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