Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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Balance the following oxidation-reduction reactions that occur in basic solution. a. \(\mathrm{Cr}(s)+\mathrm{CrO}_{4}^{2-}(a q) \rightarrow \mathrm{Cr}(\mathrm{OH})_{3}(s)\) b. \(\mathrm{MnO}_{4}^{-}(a q)+\mathrm{S}^{2-}(a q) \rightarrow \mathrm{MnS}(s)+\mathrm{S}(s)\) c. \(\mathrm{CN}^{-}(a q)+\mathrm{MnO}_{4}^{-}(a q) \rightarrow \mathrm{CNO}^{-}(a q)+\mathrm{MnO}_{2}(s)\)
A solution containing \(\mathrm{Pt}^{4+}\) is electrolyzed with a current of \(4.00 \mathrm{~A}\). How long will it take to plate out \(99 \%\) of the platinum in \(0.50 \mathrm{~L}\) of a \(0.010 \mathrm{M}\) solution of \(\mathrm{Pt}^{4+}\) ?
Gold metal will not dissolve in either concentrated nitric acid on concentrated hydrochloric acid. It will dissolve, however, in aqua regia, a mixture of the two concentrated acids. The products of the reaction are the \(\mathrm{AuCl}_{4}^{-}\) ion and gaseous NO. Write a balanced equation for the dissolution of gold in aqua regia.
Aluminum is produced commercially by the electrolysis of \(\mathrm{Al}_{2} \mathrm{O}_{3}\) in the presence of a molten salt. If a plant has a continuous capacity of \(1.00\) million A, what mass of aluminum can be produced in \(2.00 \mathrm{~h} ?\)
Balance the following oxidation-reduction reactions that occur in acidic solution using the half-reaction method. a. \(\mathrm{I}^{-}(a q)+\mathrm{ClO}^{-}(a q) \rightarrow \mathrm{I}_{3}^{-}(a q)+\mathrm{Cl}^{-}(a q)\) b. \(\mathrm{As}_{2} \mathrm{O}_{3}(s)+\mathrm{NO}_{3}^{-}(a q) \rightarrow \mathrm{H}_{3} \mathrm{AsO}_{4}(a q)+\mathrm{NO}(g)\) c. \(\mathrm{Br}^{-}(a q)+\mathrm{MnO}_{4}^{-}(a q) \rightarrow \mathrm{Br}_{2}(l)+\mathrm{Mn}^{2+}(a q)\) d. \(\mathrm{CH}_{3} \mathrm{OH}(a q)+\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(a q) \rightarrow \mathrm{CH}_{2} \mathrm{O}(a q)+\mathrm{Cr}^{3+}(a q)\)
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