Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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How long will it take to plate out each of the following with a current of \(100.0 \mathrm{~A}\) ? a. \(1.0 \mathrm{~kg} \mathrm{Al}\) from aqueous \(\mathrm{Al}^{3+}\) b. \(1.0 \mathrm{~g} \mathrm{Ni}\) from aqueous \(\mathrm{Ni}^{2+}\) c. \(5.0 \mathrm{~mol} \mathrm{Ag}\) from aqueous \(\mathrm{Ag}^{+}\)
It takes \(15 \mathrm{kWh}\) (kilowatt-hours) of electrical energy to produce 1.0 kg aluminum metal from aluminum oxide by the HallHeroult process. Compare this to the amount of energy necessary to melt \(1.0 \mathrm{~kg}\) aluminum metal. Why is it economically feasible to recycle aluminum cans?
Explain why cell potentials are not multiplied by the coefficients in the balanced redox equation. (Use the relationship between \(\Delta G\) and cell potential to do this.)
Nerve impulses are electrical "signals" that pass through neurons in the body. The electrical potential is created by the differences in the concentration of \(\mathrm{Na}^{+}\) and \(\mathrm{K}^{+}\) ions across the nerve cell membrane. We can think about this potential as being caused by a concentration gradient, similar to what we see in a concentration cell (keep in mind that this is a very simple explanation of how nerves work; there is much more involved in the true biologic process). A typical nerve cell has a resting potential of about \(-70 \mathrm{mV}\). Let's assume that this resting potential is due only to the \(\mathrm{K}^{+}\) ion concentration difference. In nerve cells, the \(\mathrm{K}^{+}\) concentration inside the cell is larger than the \(\mathrm{K}^{+}\) concentration outside the cell. Calculate the \(\mathrm{K}^{+}\) ion concentration ratio necessary to produce a resting potential of \(-70 . \mathrm{mV}\). $$\frac{\left[\mathrm{K}^{+}\right]_{\text {inside }}}{\left[\mathrm{K}^{+}\right]_{\text {outside }}}=?$$
What reaction will take place at the cathode and the anode when each of the following is electrolyzed? (Assume standard conditions.) a. \(1.0 \mathrm{M}\) KF solution b. \(1.0 \mathrm{M} \mathrm{CuCl}_{2}\) solution c. \(1.0 \mathrm{M} \mathrm{MgI}_{2}\) solution
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