Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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Chapter 18: Problem 121
When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.
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a. In the electrolysis of an aqueous solution of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\), what reactions occur at the anode and the cathode (assuming standard conditions)? b. When water containing a small amount \((-0.01 M)\) of sodium sulfate is electrolyzed, measurement of the volume of gases generated consistently gives a result that the volume ratio of hydrogen to oxygen is not quite \(2: 1 .\) To what do you attribute this discrepancy? Predict whether the measured ratio is greater than or less than \(2: 1 .\) (Hint: Consider overvoltage.)
Balance the following oxidation-reduction reactions that occur in basic solution. a. \(\mathrm{Al}(s)+\mathrm{MnO}_{4}^{-}(a q) \rightarrow \mathrm{MnO}_{2}(s)+\mathrm{Al}(\mathrm{OH})_{4}^{-}(a q)\) b. \(\mathrm{Cl}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}^{-}(a q)+\mathrm{OCl}^{-}(a q)\) c. \(\mathrm{NO}_{2}^{-}(a q)+\mathrm{Al}(s) \rightarrow \mathrm{NH}_{3}(g)+\mathrm{AlO}_{2}^{-}(a q)\)
When magnesium metal is added to a beaker of \(\mathrm{HCl}(a q)\), a gas is produced. Knowing that magnesium is oxidized and that hydrogen is reduced, write the balanced equation for the reaction. How many electrons are transferred in the balanced equation? What quantity of useful work can be obtained when \(\mathrm{Mg}\) is added directly to the beaker of HCl? How can you harness this reaction to do useful work?
An electrochemical cell consists of a nickel metal electrode immersed in a solution with \(\left[\mathrm{Ni}^{2+}\right]=1.0 M\) separated by a porous disk from an aluminum metal electrode immersed in a solution with \(\left[\mathrm{Al}^{3+}\right]=1.0 M .\) Sodium hydroxide is added to the aluminum compartment, causing \(\mathrm{Al}(\mathrm{OH})_{3}(s)\) to precipitate. After precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) has ceased, the concentration of \(\mathrm{OH}^{-}\) is \(1.0 \times 10^{-4} M\) and the measured cell potential is \(1.82 \mathrm{~V}\). Calculate the \(K_{\mathrm{sp}}\) value for \(\mathrm{Al}(\mathrm{OH})_{3}\). $$\mathrm{Al}(\mathrm{OH})_{3}(s) \rightleftharpoons \mathrm{Al}^{3+}(a q)+3 \mathrm{OH}^{-}(a q) \quad K_{\mathrm{sp}}=?$$
Consider only the species (at standard conditions) $$\mathrm{Na}^{+}, \mathrm{Cl}^{-}, \mathrm{Ag}^{+}, \mathrm{Ag}, \mathrm{Zn}^{2+}, \mathrm{Zn}, \mathrm{Pb}$$ in answering the following questions. Give reasons for your answers. (Use data from Table 18.1.) a. Which is the strongest oxidizing agent? b. Which is the strongest reducing agent? c. Which species can be oxidized by \(\mathrm{SO}_{4}^{2-}(a q)\) in acid? d. Which species can be reduced by \(\mathrm{Al}(s)\) ?
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