Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
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Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
These are the key concepts you need to understand to accurately answer the question.
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Consider the following reaction at \(298 \mathrm{~K}\) : $$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g)$$ An equilibrium mixture contains \(\mathrm{O}_{2}(\mathrm{~g})\) and \(\mathrm{SO}_{3}(g)\) at partial pressures of \(0.50\) atm and \(2.0\) atm, respectively. Using data from Appendix 4 , determine the equilibrium partial pressure of \(\mathrm{SO}_{2}\) in the mixture. Will this reaction be most favored at a high or a low temperature, assuming standard conditions?
Consider the reaction $$2 \mathrm{POCl}_{3}(g) \longrightarrow 2 \mathrm{PCl}_{3}(g)+\mathrm{O}_{2}(g)$$ a. Calculate \(\Delta G^{\circ}\) for this reaction. The \(\Delta G_{\mathrm{f}}^{\circ}\) values for \(\mathrm{POCl}_{3}(g)\) and \(\mathrm{PCl}_{3}(g)\) are \(-502 \mathrm{~kJ} / \mathrm{mol}\) and \(-270 . \mathrm{kJ} / \mathrm{mol}\), respectively. b. Is this reaction spontaneous under standard conditions at \(298 \mathrm{~K} ?\) c. The value of \(\Delta S^{\circ}\) for this reaction is \(179 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). At what temperatures is this reaction spontaneous at standard conditions? Assume that \(\Delta H^{\circ}\) and \(\Delta S^{\circ}\) do not depend on temperature.
Using data from Appendix 4, calculate \(\Delta H^{\circ}, \Delta G^{\circ}\), and \(K\) (at 298 K) for the production of ozone from oxygen: $$3 \mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{O}_{3}(g)$$ At \(30 \mathrm{~km}\) above the surface of the earth, the temperature is about 230\. \(\mathrm{K}\) and the partial pressure of oxygen is about \(1.0 \times 10^{-3}\) atm. Estimate the partial pressure of ozone in equilibrium with oxygen at \(30 \mathrm{~km}\) above the earth's surface. Is it reasonable to assume that the equilibrium between oxygen and ozone is maintained under these conditions? Explain.
Consider two perfectly insulated vessels. Vessel 1 initially contains an ice cube at \(0^{\circ} \mathrm{C}\) and water at \(0^{\circ} \mathrm{C}\). Vessel 2 initially contains an ice cube at \(0^{\circ} \mathrm{C}\) and a saltwater solution at \(0^{\circ} \mathrm{C}\). Consider the process \(\mathrm{H}_{2} \mathrm{O}(s) \rightarrow \mathrm{H}_{2} \mathrm{O}(l)\) a. Determine the sign of \(\Delta S, \Delta S_{\text {surr }}\), and \(\Delta S_{\text {univ }}\) for the process in vessel 1 . b. Determine the sign of \(\Delta S, \Delta S_{\text {surt }}\), and \(\Delta S_{\text {univ }}\) for the process in vessel 2 . (Hint: Think about the effect that a salt has on the freezing point of a solvent.)
For ammonia \(\left(\mathrm{NH}_{3}\right.\) ), the enthalpy of fusion is \(5.65 \mathrm{~kJ} / \mathrm{mol}\) and the entropy of fusion is \(28.9 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). a. Will \(\mathrm{NH}_{3}(s)\) spontaneously melt at \(200 . \mathrm{K}\) ? b. What is the approximate melting point of ammonia?
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