Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
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Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
These are the key concepts you need to understand to accurately answer the question.
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Carbon monoxide is toxic because it bonds much more strongly to the iron in hemoglobin (Hgb) than does \(\mathrm{O}_{2}\). Consider the following reactions and approximate standard free energy changes: $$\begin{array}{clr}\mathrm{Hgb}+\mathrm{O}_{2} \longrightarrow \mathrm{HgbO}_{2} & \Delta G^{\circ}=-70 \mathrm{~kJ} \\ \mathrm{Hgb}+\mathrm{CO} \longrightarrow \mathrm{HgbCO} & \Delta G^{\circ}=-80 \mathrm{~kJ} \end{array}$$ Using these data, estimate the equilibrium constant value at \(25^{\circ} \mathrm{C}\) for the following reaction: $$\mathrm{HgbO}_{2}+\mathrm{CO} \rightleftharpoons \mathrm{HgbCO}+\mathrm{O}_{2}$$
When most biologic enzymes are heated, they lose their catalytic activity. The change Original enzyme \(\longrightarrow\) new form that occurs on heating is endothermic and spontaneous. Is the structure of the original enzyme or its new form more ordered (has the smaller positional probability)? Explain.
a. Using the free energy profile for a simple one-step reaction, show that at equilibrium \(K=k_{\mathrm{f}} / k_{\mathrm{r}}\), where \(k_{\mathrm{f}}\) and \(k_{\mathrm{r}}\) are the rate constants for the forward and reverse reactions. Hint: Use the relationship \(\Delta G^{\circ}=-R T \ln (K)\) and represent \(k_{\mathrm{f}}\) and \(k_{\mathrm{r}}\) using the Arrhenius equation \(\left(k=A e^{-E_{2} / R T}\right)\). b. Why is the following statement false? "A catalyst can increase the rate of a forward reaction but not the rate of the reverse reaction."
For mercury, the enthalpy of vaporization is \(58.51 \mathrm{~kJ} / \mathrm{mol}\) and the entropy of vaporization is \(92.92 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). What is the normal boiling point of mercury?
For each of the following pairs of substances, which substance has the greater value of \(S^{\circ} ?\) a. \(C_{\text {graphite }}(s)\) or \(C_{\text {diamond }}(s)\) b. \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l)\) or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{g})\) c. \(\mathrm{CO}_{2}(s)\) or \(\mathrm{CO}_{2}(g)\)
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