91Ó°ÊÓ

Plot or analyze the given initial rate data and note any relationships between the initial concentration and the initial rate. If the rate directly depends on the initial concentration, it is a first-order reaction. If the rate depends on the square of the initial concentration, it is a second-order reaction. If there is no dependency, it is a zero-order reaction. For example, consider the following initial rate data table: | Initial Concentration, [AB] (M) | Initial Rate, R (M/s) | | ---------------------------------- | --------------------------- | | 1.00 \(\times\) \(10^{-2}\) | 1.00 \(\times\) \(10^{-4}\) | | 2.00 \(\times\) \(10^{-2}\) | 2.00 \(\times\) \(10^{-4}\) | | 3.00 \(\times\) \(10^{-2}\) | 3.00 \(\times\) \(10^{-4}\) | The initial rate directly depends on the initial concentration of AB, meaning this is a first-order reaction.

Use the rate equation to determine the rate constant, k: Rate = k [AB]\(^n\) As determined in Step 1, the reaction is first-order. Thus, n = 1. Rate = k [AB] Choose any row of data to find the rate constant. For example, using the first row: 1.00 \(\times\) \(10^{-4}\) = k (1.00 \(\times\) \(10^{-2}\)) k = 0.01

Use the half-life formula for a first-order reaction: Half-life = \(\dfrac{0.693}{k}\) Substitute the determined rate constant: Half-life = \(\dfrac{0.693}{0.01}\) Half-life = 69.3 s The half-life for the decomposition reaction with an initial concentration of 1.00 M AB is 69.3 seconds.