Chapter 10: Problem 69
Cobalt fluoride crystallizes in a closest packed array of fluoride ions with the cobalt ions filling one-half of the octahedral holes. What is the formula of this compound?
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Chapter 10: Problem 69
Cobalt fluoride crystallizes in a closest packed array of fluoride ions with the cobalt ions filling one-half of the octahedral holes. What is the formula of this compound?
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MnO has either the \(\mathrm{NaCl}\) type structure or the \(\mathrm{CsCl}\) type structure (see Exercise 67). The edge length of the \(\mathrm{MnO}\) unit cell is \(4.47 \times 10^{-8} \mathrm{~cm}\) and the density of \(\mathrm{MnO}\) is \(5.28 \mathrm{~g} / \mathrm{cm}^{3}\) a. Does \(\mathrm{Mn} \mathrm{O}\) crystallize in the \(\mathrm{NaCl}\) or the \(\mathrm{CsCl}\) type structure? b. Assuming that the ionic radius of oxygen is \(140 . \mathrm{pm}\), estimate the ionic radius of manganese.
What is the formula for the compound that crystallizes with a cubic closest packed array of sulfur ions, and that contains zinc ions in \(\frac{1}{8}\) of the tetrahedral holes and aluminum ions in \(\frac{1}{2}\) of the octahedral holes?
Explain how the evaporation of water acts as a coolant for the earth.
What type of solid will each of the following substances form? a. diamond e. \(\mathrm{KCl}\) i. \(\mathrm{Ar}\) b. \(\mathrm{PH}_{3}\) f. quartz j. \(\mathrm{Cu}\) c. \(\mathrm{H}_{2}\) g. \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) k. \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) d. \(\mathrm{Mg}\) h. \(\mathrm{SF}_{2}\)
A topaz crystal has an interplanar spacing \((d)\) of \(1.36 \AA^{\circ}(1 \AA=\) \(\left.1 \times 10^{-10} \mathrm{~m}\right) .\) Calculate the wavelength of the \(\mathrm{X}\) ray that should be used if \(\theta=15.0^{\circ}\) (assume \(n=1\) ).
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