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The radius of gold is \(144 \mathrm{pm}\), and the density is \(19.32 \mathrm{~g} / \mathrm{cm}^{3}\). Does elemental gold have a face-centered cubic structure or a body-centered cubic structure?

Short Answer

Expert verified
Elemental gold likely has a face-centered cubic (FCC) structure, as the FCC atomic packing factor (APF) is 鈮 0.74, which is higher than the body-centered cubic (BCC) APF of 鈮 0.68. This indicates a more efficient atomic packing in the FCC structure.

Step by step solution

01

Calculate the volume of an atom

We are given the radius of gold atoms, so we can calculate their volume using the formula for the volume of a sphere: \(V_{atom} = \frac{4}{3}\pi r^3\) Plugging in the given radius of 144 pm: \(V_{atom} = \frac{4}{3}\pi (144 \times 10^{-12} m)^3 鈮 1.25 \times 10^{-28} m^3\)
02

Calculate the volume of the unit cell for FCC and BCC structures

The volume of the unit cell can be expressed in terms of the length of its side (a). Due to the unique geometry, for FCC and BCC structures the side length can be expressed in terms of the radius: 1. For FCC: \(a_{FCC} = 2\sqrt{2}r\) 2. For BCC: \(a_{BCC} = 4r/\sqrt{3}\) Now, let's find the volume of the unit cell for both structures: \(V_{cell_{FCC}} = a_{FCC}^3 = (2\sqrt{2}r)^3\) \(V_{cell_{BCC}} = a_{BCC}^3 = (4r/\sqrt{3})^3\)
03

Calculate the APF for FCC and BCC structures

Using the formulas from our analysis: APF for FCC = \(\frac{4\textit{V}_{atom}}{V_{cell_{FCC}}}\) APF for BCC = \(\frac{2\textit{V}_{atom}}{V_{cell_{BCC}}}\) Plugging in the values of \(V_{atom}\), \(V_{cell_{FCC}}\), and \(V_{cell_{BCC}}\): APF for FCC 鈮 0.74 APF for BCC 鈮 0.68
04

Determine the structure of elemental gold

From the given density (饾湆) = 19.32 g/cm鲁 and radius (r) = 144 pm, we found that the APF for FCC and BCC structures are 鈮 0.74 and 鈮 0.68, respectively. Since the APF for the face-centered cubic (FCC) structure is higher than the body-centered cubic (BCC) structure, it means that the atoms are more efficiently packed in the FCC structure. Considering this information and the given data, it is likely that elemental gold has a face-centered cubic (FCC) structure.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Face-Centered Cubic Structure
Gold, a precious metal, is known for its unique and highly efficient crystal arrangement known as the face-centered cubic (FCC) structure. In this arrangement, atoms are located at each corner and at the center of each of the faces of the cube that makes up the unit cell. This creates a highly symmetrical structure.

An easy way to visualize this is by thinking of each unit cell as a dice, with atoms at each corner point (imagine the pips on the dice) and additional atoms at the center of each face (like a pip in the face-center if such existed on a dice). Each unit cell in an FCC structure contains 4 whole atoms (each corner atom is shared with eight adjacent unit cells, and each face-centered atom is shared with two units), contributing to its high density and stable properties, which are characteristic of gold.

Due to this configuration, FCC metals like gold are known for their good ductility, allowing them to be drawn into wires without breaking.
Body-Centered Cubic Structure
Unlike the face-centered cubic structure, the body-centered cubic (BCC) structure is another arrangement where atoms are located at each corner of the cube and a single atom at the center of the cube. This geometry contrasts with the FCC structure because it does not have atoms in the center of the faces.

Imagine a simple cube-shaped box with balls (atoms) stuck at each corner and one right in the middle of the box. The BCC structure is less dense than the FCC structure, meaning that there are fewer atoms in a given volume. This crystal arrangement typically has lower atomic packing factor (APF), which means that it has more empty space between atoms when compared to FCC structures.
Atomic Packing Factor
The atomic packing factor (APF) is a measure of how densely packed the atoms are within a crystal structure. It is defined as the ratio of the volume of atoms in a unit cell to the total volume of the unit cell.

The higher the APF, the more space is filled with atoms, with less empty space. As seen in the case of gold, the FCC structure has a higher APF (around 0.74) compared to the BCC structure (about 0.68). These differences in APF are significant because they affect the physical properties of the material, such as density, melting point, and how the material deforms under stress. For materials with a higher APF, like gold in its FCC crystal structure, they are typically more dense and have a higher melting point.
Crystal Lattice
The term 'crystal lattice' refers to the three-dimensional arrangement of atoms, ions, or molecules in a crystalline material. It represents the orderly, repeating pattern that extends in all three spatial dimensions.

Crystal lattices are characterized by the geometrical pattern formed by points that correspond to the atom or molecule positions. This regular pattern is what gives crystals their typical flat faces and sharp edges. In crystals like gold with a face-centered cubic lattice, the symmetry and regularity of the lattice are what account for the characteristic physical properties, such as high conductivity and malleability. The crystal lattice concept is fundamental to understanding various properties of materials, including how they interact with light, electricity, and how they are affected by pressure and temperature changes.

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Most popular questions from this chapter

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