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How many grams of solute would you use to prepare each of the following solutions? (a) \(250.0 \mathrm{~mL}\) of \(0.600 \mathrm{M}\) ethyl alcohol \(\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}\right)\) (b) \(167 \mathrm{~mL}\) of \(0.200 \mathrm{M}\) boric acid \(\left(\mathrm{H}_{3} \mathrm{BO}_{3}\right)\)

Short Answer

Expert verified
6.912 g of ethyl alcohol and 2.065 g of boric acid are needed.

Step by step solution

01

Understand Molarity Formula

Molarity (M) is defined as moles of solute (mol) per liter of solution (L). The formula is: \[ M = \frac{n}{V} \]where \(n\) is the number of moles of solute and \(V\) is the volume of the solution in liters. To find the mass of solute, we use the formula: \[ \text{mass} = n \times \text{molar mass} \]
02

Calculate Volume in Liters for Solution (a)

Convert the volume from milliliters to liters. For ethyl alcohol: \[250.0 \, \text{mL} = 0.2500 \, \text{L}\]
03

Determine Moles of Ethyl Alcohol (a)

Use the molarity to find moles of solute: \[ 0.600 = \frac{n}{0.2500} \]Solving for \(n\): \[ n = 0.600 \times 0.2500 = 0.150 \text{ moles} \]
04

Calculate Mass of Ethyl Alcohol (a)

The molar mass of ethyl alcohol (\(C_2H_6O\)) is calculated as: \[ 2(12.01) + 6(1.01) + 16.00 \approx 46.08 \text{ g/mol} \]Then, \[ \text{mass} = 0.150 \times 46.08 = 6.912 \text{ g} \]
05

Calculate Volume in Liters for Solution (b)

Convert the volume from milliliters to liters. For boric acid: \[167 \, \text{mL} = 0.167 \, \text{L}\]
06

Determine Moles of Boric Acid (b)

Use the molarity to find moles of solute: \[ 0.200 = \frac{n}{0.167} \]Solving for \(n\): \[ n = 0.200 \times 0.167 = 0.0334 \text{ moles} \]
07

Calculate Mass of Boric Acid (b)

The molar mass of boric acid (\(H_3BO_3\)) is calculated as: \[ 3(1.01) + 10.81 + 3(16.00) \approx 61.83 \text{ g/mol} \]Then, \[ \text{mass} = 0.0334 \times 61.83 = 2.065 \text{ g} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Moles of solute
One of the foundational concepts in chemistry is the idea of moles, particularly moles of solute in solutions. A mole is a standard unit of measurement that represents a quantity of chemical entities, like atoms, molecules, or ions. When it comes to solutions, moles play a critical role in determining how much solute you need to achieve a particular concentration.

For instance, in step 3 of the original exercise, we calculate the number of moles of ethyl alcohol required to make a solution with a given molarity. The formula here is straightforward:
  • Molarity (M) is defined as moles of solute per liter of solution.
  • Thus, the formula becomes: \[ M = \frac{n}{V} \]
With this formula, solving for the number of moles \(n\) becomes easy by rearranging it: \[ n = M \times V \].

Using molarity and volume to find the number of moles is crucial when preparing solutions with precise concentrations for reactions and experiments.
Molar mass
Molar mass is another essential concept when dealing with solution preparation in chemistry. It acts as a bridge between moles and grams, allowing you to convert between a substance's amount in moles and its measurable mass in the laboratory.
To find molar mass, usually given in grams per mole (g/mol), one needs to sum the atomic masses of all atoms in a molecule. For example, in the exercise, the molar mass calculation for ethyl alcohol and boric acid is demonstrated:

  • Ethyl alcohol \( C_2H_6O \):
    • carbon: 2 atoms \( \times 12.01 \) g/mol
    • hydrogen: 6 atoms \( \times 1.01 \) g/mol
    • oxygen: 16.00 g/mol
  • Boric acid \( H_3BO_3 \):
    • hydrogen: 3 atoms \( \times 1.01 \) g/mol
    • boron: 10.81 g/mol
    • oxygen: 3 atoms \( \times 16.00 \) g/mol
Understanding and calculating molar mass accurately ensures that the translation from moles of a substance to grams is precise, maintaining the integrity of solution calculations.
Concentration
The concentration of a solution is a measure of how much solute is present in a given amount of solution. It specifies the strength or dilution of a mixture and is commonly expressed in terms of molarity (M), which is calculated as moles of solute per liter of solution.
In practical terms, concentration is vital because it directly impacts the behavior and reactivity of the solution. For example, the problems in the original exercise both involve finding the exact mass of the solute required to achieve a desired concentration. To prepare a 0.600 M solution of ethyl alcohol or a 0.200 M solution of boric acid, the ratio of solute to solvent allows chemists to predict and control the outcomes of chemical reactions.

Here is how concentration aids in the calculation:
  • Identify the desired concentration (given in M).
  • Convert the volume of the solution from mL to L to match the molarity's volume requirement.
  • Use the molarity formula: \[ M = \frac{n}{V} \],then solve for moles \(n\).
  • Finally, convert the moles back to grams using the molar mass.
Accurate knowledge of concentration helps assure that chemical processes are both safe and effective.

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Most popular questions from this chapter

A bottle of \(12.0 \mathrm{M}\) hydrochloric acid has only \(35.7 \mathrm{~mL}\) left in it. What will the HCl concentration be if the solution is diluted to \(250.0 \mathrm{~mL} ?\)

A certain metal sulfide, \(\mathrm{MS}_{n}\) (where \(n\) is a small integer), is widely used as a high-temperature lubricant. The substance is prepared by reaction of the metal pentachloride \(\left(\mathrm{MCl}_{5}\right)\) with sodium sulfide \(\left(\mathrm{Na}_{2} \mathrm{~S}\right)\). Heating the metal sulfide to \(700^{\circ} \mathrm{C}\) in air gives the metal trioxide \(\left(\mathrm{MO}_{3}\right)\) and sulfur dioxide \(\left(\mathrm{SO}_{2}\right)\), which reacts with \(\mathrm{Fe}^{3+}\) ion under aqueous acidic conditions to give sulfate ion \(\left(\mathrm{SO}_{4}^{2-}\right)\). Addition of aqueous \(\mathrm{BaCl}_{2}\) then forms a precipitate of \(\mathrm{BaSO}_{4}\). The unbalanced equations are: (1) \(\mathrm{MCl}_{5}(s)+\mathrm{Na}_{2} \mathrm{~S}(s) \longrightarrow \mathrm{MS}_{n}(s)+\mathrm{S}(l)+\mathrm{NaCl}(s)\) (2) \(\mathrm{MS}_{n}(s)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{MO}_{3}(s)+\mathrm{SO}_{2}(g)\) (3) \(\mathrm{SO}_{2}(g)+\mathrm{Fe}^{3+}(a q) \longrightarrow \mathrm{Fe}^{2+}(a q)+\mathrm{SO}_{4}{ }^{2-}(a q)\) (in acid) (4) \(\mathrm{SO}_{4}{ }^{2-}(a q)+\mathrm{Ba}^{2+}(a q) \longrightarrow \mathrm{BaSO}_{4}(s)\) Assume that you begin with \(4.61 \mathrm{~g}\) of \(\mathrm{MCl}_{5}\) and that reaction (1) proceeds in \(91.3 \%\) yield. After oxidation of the \(\mathrm{MS}_{n}\) product, oxidation of \(\mathrm{SO}_{2}\), and precipitation of sulfate ion, \(7.19 \mathrm{~g}\) of \(\mathrm{BaSO}_{4}(s)\) is obtained. (a) How many moles of sulfur are present in the \(\mathrm{MS}_{n}\) sample? (b) Assuming several possible values for \(n(n=1,2,3 \ldots)\) what is the atomic weight of \(\mathbf{M}\) in each case? (c) What is the likely identity of the metal \(\mathbf{M}\), and what is the formula of the metal sulfide \(\mathrm{MS}_{n} ?\) (d) Balance all equations.

Iron content in ores can be determined by a redox procedure in which the sample is first reduced with \(\mathrm{Sn}^{2+}\), as in Problem \(4.122\) and then titrated with \(\mathrm{KMnO}_{4}\) to oxidize the \(\mathrm{Fe}^{2+}\) to \(\mathrm{Fe}^{3+}\). The balanced equation is \(\begin{aligned} \mathrm{MnO}_{4}^{-}(a q)+5 \mathrm{Fe}^{2+}(a q)+8 \mathrm{H}^{+}(a q) & \longrightarrow \\ \mathrm{Mn}^{2+}(a q)+5 \mathrm{Fe}^{3+}(a q)+4 \mathrm{H}_{2} \mathrm{O}(l) \end{aligned}\) What is the mass percent Fe in a \(2.368 \mathrm{~g}\) sample if \(48.39 \mathrm{~mL}\) of a \(0.1116 \mathrm{M} \mathrm{KMnO}_{4}\) solution is needed to titrate the \(\mathrm{Fe}^{3+} ?\)

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What is the volume of the solution that would result by diluting \(70.00 \mathrm{~mL}\) of \(0.0913 \mathrm{M} \mathrm{NaOH}\) to a concentration of \(0.0150 \mathrm{M} ?\)

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