/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 103 \(\mathrm{YBa}_{2} \mathrm{Cu}_{... [FREE SOLUTION] | 91Ó°ÊÓ

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\(\mathrm{YBa}_{2} \mathrm{Cu}_{3} \mathrm{O}_{7}\) is a superconductor below its \(T_{\mathrm{c}}\) of \(90 \mathrm{~K}\) and a metallic conductor above \(90 \mathrm{~K}\). Make a rough plot of electrical resistance versus temperature for \(\mathrm{YBa}_{2} \mathrm{Cu}_{3} \mathrm{O}_{7} .\)

Short Answer

Expert verified
The plot shows zero resistance below 90 K and increasing resistance above 90 K.

Step by step solution

01

Understand the Material Transition

When \(\mathrm{YBa}_{2} \mathrm{Cu}_{3} \mathrm{O}_{7}\)is below the critical temperature \(T_{\mathrm{c}} = 90 \mathrm{~K}\),it behaves as a superconductor, meaning the electrical resistance drops to zero. Above this temperature, it acts like a typical metallic conductor with non-zero resistance.
02

Identify Key Points on the Plot

Key points on the plot include:- At temperatures below \(90 \mathrm{~K}\),the resistance is \(0 \Omega\).- At the critical temperature \(T_{\mathrm{c}} = 90 \mathrm{~K}\),the resistance begins to increase.- Above \(90 \mathrm{~K}\),the material has a non-zero resistance typical of a metal, increasing with temperature.
03

Draw the Plot

Begin with the y-axis labeled as Electrical Resistance and the x-axis as Temperature.- From the origin (on the temperature axis) to just below \(90 \mathrm{~K}\), draw a horizontal line at resistance \(0\).- At \(90 \mathrm{~K}\), show a sharp upward increase in resistance.- Continue from \(90 \mathrm{~K}\) onward with a line that gently rises to represent increasing resistance with temperature.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

YBa2Cu3O7
YBa2Cu3O7 is a compound that stands out in the world of superconductors. Also known as Yttrium Barium Copper Oxide (YBCO), it showcases remarkable properties that have garnered attention since its discovery. The formula indicates that it consists of two atoms of Barium, three of Copper, and seven of Oxygen, along with one Yttrium atom. This particular chemical composition allows YBCO to become superconducting under specific conditions.
Below its critical temperature, YBCO can conduct electricity with zero resistance, making it a crucial material for various applications like advanced MRI machines and efficient power lines.
  • Remarkable transition from insulator to superconductor.
  • Uses in modern technology due to its unique properties.
Understanding YBa2Cu3O7 is fundamental for grasping the potential and challenge of superconductors.
Critical Temperature
The critical temperature, often denoted as \(T_c\), is a pivotal point for superconductors. This is the exact temperature below which materials like YBa2Cu3O7 suddenly lose all electrical resistance, reaching a state of superconductivity. For YBa2Cu3O7, this magic mark is at 90 Kelvin. When cooled below this threshold, the material allows electrical currents to flow without any loss of energy due to resistance.
It's important because:
  • Determines the operational efficiency of superconductors.
  • Technical and logistical challenges arise in maintaining this temperature.
The concept of \(T_c\) is crucial for applications that rely on the perfect conductivity of these materials.
Electrical Resistance
Electrical resistance is a measure of how much a material opposes the flow of electric current. For typical materials, resistance increases with temperature as the atoms vibrate more and obstruct the flow of electrons. However, this rule astonishingly does not apply to superconductors such as YBa2Cu3O7 below their critical temperature.
In these cases:
  • Resistance is exactly zero below \(T_c\).
  • Facilitates long-distance energy transmission without loss.
This lack of electrical resistance at very low temperatures underpins the economic and technological benefits of using superconductors.
Metallic Conductor
Above the critical temperature, YBa2Cu3O7 behaves like a typical metallic conductor. In this phase, it exhibits a resistance that changes with temperature. As with most metals, resistance increases as temperature rises due to increased electron-atom collisions. This property ensures that while it is not superconducting, it still follows the fundamental principles of metallic conduction.
Characteristics of metallic conductors include:
  • Non-zero resistance above the critical temperature.
  • Temperature-dependent increase in resistance.
This dual behavior is essential for identifying practical uses for YBa2Cu3O7, influencing how we design systems for temperature control.
Phase Transition
The transition from a superconducting state to a metallic conductor or vice versa in materials like YBa2Cu3O7 is a fascinating phase transition. Unlike changes such as ice melting to water, this transition involves a fundamental shift in how electricity flows through the material. As a phase transition:
  • Occurs at the critical temperature \(T_c\).
  • Marked by a stark contrast in electrical properties (zero resistance below \(T_c\)).
Understanding this phase transition is vital not only for physics but also for engineering and materials science, where such shifts can be harnessed to develop new technologies and devices.

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Most popular questions from this chapter

How does the electron-sea model account for the malleability and ductility of metals?

Silicon nitride \(\left(\mathrm{Si}_{3} \mathrm{~N}_{4}\right)\), a high- temperature ceramic useful for making engine components, is a covalent network solid in which each \(\mathrm{Si}\) atom is bonded to four \(\mathrm{N}\) atoms and each \(\mathrm{N}\) atom is bonded to three Si atoms. Explain why silicon nitride is more brittle than a metal like copper.

An \(8.894 \mathrm{~g}\) block of aluminum was pressed into a thin square of foil with \(36.5 \mathrm{~cm}\) edge lengths. (a) If the density of \(\mathrm{Al}\) is \(2.699 \mathrm{~g} / \mathrm{cm}^{3}\), how thick is the foil in centimeters? (b) How many unit cells thick is the foil? Aluminum crystallizes in a face- centered cubic structure and has an atomic radius of \(143 \mathrm{pm}\)

Explain what an \(n\) -type semiconductor is, and give an example. Draw an MO energy-level diagram, and show the population of the valence band and the conduction band for an \(n\) -type semiconductor.

The \(\mathrm{YBa}_{2} \mathrm{Cu}_{3} \mathrm{O}_{7}\) superconductor can be synthesized by the solgel method from a stoichiometric mixture of metal ethoxides followed by heating in oxygen. How many grams of \(\mathrm{Y}\left(\mathrm{OCH}_{2} \mathrm{CH}_{3}\right)_{3}\) and how many grams of \(\mathrm{Ba}\left(\mathrm{OCH}_{2} \mathrm{CH}_{3}\right)_{2}\) are required to react with \(75.4 \mathrm{~g}\) of \(\mathrm{Cu}\left(\mathrm{OCH}_{2} \mathrm{CH}_{3}\right)_{2}\) and an excess of water? Assuming a \(100 \%\) yield, how many grams of \(\mathrm{YBa}_{2} \mathrm{Cu}_{3} \mathrm{O}_{7}\) are obtained?

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