In acidic aqueous solution, the purple complex ion
\(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Br}^{2+}\) undergoes a
slow reaction in which the bromide ion is replaced by a water molecule,
yielding the pinkishorange complex ion
\(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2}
\mathrm{O}\right)^{3+}\) : The reaction is first order in
\(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Br}^{2+}\), the rate
constant at \(25^{\circ} \mathrm{C}\) is \(6.3 \times 10^{-6} \mathrm{~s}^{-1}\),
and the initial concentration of \(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}
\mathrm{Br}^{2+}\)
is \(0.100 \mathrm{M}\).