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Approximately \(83 \%\) of all ammonia produced is used as fertilizer for crops. Ammonia is synthesized from hydrogen and nitrogen gas according to the equation $$ 3 \mathrm{H}_{2}(g)+\mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{NH}_{3}(g) $$ What volume of hydrogen and nitrogen gas is needed to synthesize \(500.0 \mathrm{~L}\) of ammonia at STP?

Short Answer

Expert verified
750.0 L of hydrogen and 250.0 L of nitrogen are needed at STP.

Step by step solution

01

Determine the Stoichiometric Relationships

From the given balanced chemical equation: \(3 \mathrm{H}_{2}(g) + \mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{NH}_{3}(g)\), we identify the stoichiometric ratios: \(3\mathrm{~mol}~\mathrm{H}_{2}(g): 1\mathrm{~mol}~\mathrm{N}_{2}(g): 2 \mathrm{~mol}~\mathrm{NH}_{3}(g)\). This indicates that 3 volumes of hydrogen react with 1 volume of nitrogen to produce 2 volumes of ammonia gas.
02

Calculate Volumes Using Stoichiometry

Since gases at STP behave ideally, the volumes are directly proportional to the moles used in the equation. Therefore, to synthesize \(500.0\mathrm{~L}\) of ammonia, we setup a ratio for hydrogen: \(\frac{3}{2} = \frac{V_{\mathrm{H}_2}}{500.0}\), solving for \(V_{\mathrm{H}_2}\) gives \(750.0\mathrm{~L}\) of hydrogen. For nitrogen, the ratio is \(\frac{1}{2} = \frac{V_{\mathrm{N}_2}}{500.0}\), thus \(V_{\mathrm{N}_2} = 250.0\mathrm{~L}\).
03

Conclusion of the Required Volumes

Given the stoichiometric calculations, the process to synthesize \(500.0 \mathrm{~L}\) of ammonia requires \(750.0\mathrm{~L}\) of hydrogen gas and \(250.0\mathrm{~L}\) of nitrogen gas when all volumes are measured at STP.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ammonia synthesis
Ammonia is a vital chemical used primarily in fertilizers to boost crop growth. It is synthesized through a process called the Haber-Bosch method, which combines hydrogen and nitrogen gases. The reaction is represented by the equation: \( 3 \mathrm{H}_{2}(g) + \mathrm{N}_{2}(g) \rightarrow 2 \mathrm{NH}_{3}(g) \). This means three molecules of hydrogen react with one molecule of nitrogen to yield two molecules of ammonia.

Producing ammonia requires specific conditions like high pressure and temperature, and the reaction is facilitated by a catalyst. These conditions make the synthesis efficient and economically viable for large-scale production. Understanding this reaction helps in calculating the required amounts of reactants for industrial ammonia production.
Chemical equations
Chemical equations are symbolic representations of chemical reactions, showing the reactants and the resulting products. In the context of ammonia synthesis, the equation \( 3 \mathrm{H}_{2}(g) + \mathrm{N}_{2}(g) \rightarrow 2 \mathrm{NH}_{3}(g) \) not only tells us which chemicals are involved but also their proportions.

A balanced chemical equation is crucial as it ensures that the mass and the number of atoms are conserved. This means we have the same number of each type of atom on both sides of the equation. From the equation for ammonia synthesis, we see a stoichiometric ratio where 3 volumes of hydrogen react with 1 volume of nitrogen to produce 2 volumes of ammonia. This ratio is key to understanding how much of each reactant is needed.
Volume calculations at STP
Volume calculations at Standard Temperature and Pressure (STP) assume ideal gas behavior, making it simpler to relate volumes to moles in a balanced equation. At STP, gases occupy a volume of 22.4 liters per mole.

For ammonia synthesis, suppose we need to produce 500.0 liters of ammonia. Using the ratio from the chemical equation, the volumes of hydrogen and nitrogen required can be calculated. For hydrogen gas, the ratio is \( \frac{3}{2} = \frac{V_{\mathrm{H}_2}}{500.0} \), solving gives us 750.0 liters. Similarly, for nitrogen: \( \frac{1}{2} = \frac{V_{\mathrm{N}_2}}{500.0} \) gives 250.0 liters.

Understanding these calculations is critical for planning and optimizing chemical production processes.

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Most popular questions from this chapter

(a) If a barometer were filled with liquid water instead of mercury (Figure 10.4), what would be the height \((\mathrm{m})\) of the column of water if the atmospheric pressure were \(1 \mathrm{~atm} ?\) In other words, express the pressure of 1 atm in units of meters of water instead of millimeters of mercury. (The density of mercury is \(13.6 \mathrm{~g} / \mathrm{mL}\) and the density of water is \(1.00 \mathrm{~g} / \mathrm{mL}\).) (b) Why is Hg more commonly used in a barometer than water?

Which gas in each of the following pairs diffuses more rapidly, and what are the relative rates of diffusion? (a) \(\mathrm{Kr}\) and \(\mathrm{O}_{2}\) (b) \(\mathrm{N}_{2}\) and acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\)

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