Chapter 4: Problem 41
Is it possible to have a reaction in which oxidation occurs and reduction does not? Explain.
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Chapter 4: Problem 41
Is it possible to have a reaction in which oxidation occurs and reduction does not? Explain.
These are the key concepts you need to understand to accurately answer the question.
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The concentration of a hydrogen peroxide solution can be conveniently determined by titration against a standardized potassium permanganate solution in an acidic medium according to the equation \(2 \mathrm{MnO}_{4}^{-}+5 \mathrm{H}_{2} \mathrm{O}_{2}+6 \mathrm{H}^{+} \longrightarrow\) \(5 \mathrm{O}_{2}+2 \mathrm{Mn}^{2+}+8 \mathrm{H}_{2} \mathrm{O}\) If \(36.44 \mathrm{~mL}\) of a \(0.01652 \mathrm{M} \mathrm{KMnO}_{4}\) solution are required to oxidize \(25.00 \mathrm{~mL}\) of a \(\mathrm{H}_{2} \mathrm{O}_{2}\) solution, calculate the molarity of the \(\mathrm{H}_{2} \mathrm{O}_{2}\) solution.
Sulfites (compounds containing the \(\mathrm{SO}_{3}^{2-}\) ions) are used as preservatives in dried fruits and vegetables and in wine making. In an experiment to test the presence of sulfite in fruit, a student first soaked several dried apricots in water overnight and then filtered the solution to remove all solid particles. She then treated the solution with hydrogen peroxide \(\left(\mathrm{H}_{2} \mathrm{O}_{2}\right)\) to oxidize the sulfite ions to sulfate ions. Finally, the sulfate ions were precipitated by treating the solution with a few drops of a barium chloride \(\left(\mathrm{BaCl}_{2}\right)\) solution. Write a balanced equation for each of the preceding steps.
Write the equation for calculating molarity. Why is molarity a convenient concentration unit in chemistry?
How is the activity series organized? How is it used in the study of redox reactions?
Which of the following aqueous solutions would you expect to be the best conductor of electricity at \(25^{\circ} \mathrm{C} ?\) Explain your answer. (a) \(0.20 \mathrm{M} \mathrm{NaCl}\) (b) \(0.60 \mathrm{M} \mathrm{CH}_{3} \mathrm{COOH}\) (c) \(0.25 M \mathrm{HCl}\) (d) \(0.20 M \operatorname{Mg}\left(\mathrm{NO}_{3}\right)_{2}\)
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