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Consider the reaction $$\mathrm{MnO}_{2}+4 \mathrm{HCl} \longrightarrow \mathrm{MnCl}_{2}+\mathrm{Cl}_{2}+2 \mathrm{H}_{2} \mathrm{O} $$If 0.86 mole of \(\mathrm{MnO}_{2}\) and \(48.2 \mathrm{~g}\) of \(\mathrm{HCl}\) react, which reactant will be used up first? How many grams of \(\mathrm{Cl}_{2}\) will be produced?

Short Answer

Expert verified
HCl is the limiting reactant. The reaction produces 23.43 g of Cl2

Step by step solution

01

Convert grams of HCl to moles

The molar mass of HCl is \(36.5 \mathrm{~g/mol}\). Use the molar mass to convert grams of HCl to moles: \[\frac{48.2 \mathrm{~g}}{36.5 \mathrm{~g/mol}} = 1.32 \mathrm{~moles}\]
02

Determine which reactant is the limiting reactant

From the balanced equation, it can be inferred that 4 moles of HCl react with 1 mole of MnO2. Divide the number of moles of each reactant by the coefficient in the balanced equation to determine which reactant is the limiting reactant: MnO2: \[\frac{0.86 \mathrm{~moles}}{1} = 0.86\] HCl: \[\frac{1.32 \mathrm{~moles}}{4} = 0.33\] The limiting reactant is the one that gives the smallest number, so HCl is the limiting reactant.
03

Calculate the amount of Cl2 produced

The balanced equation shows that 1 mole of Cl2 is produced for each 4 moles of HCl. With 1.32 moles of HCl available, the moles of Cl2 produced are: \[\frac{1.32 \mathrm{~moles}}{4} = 0.33 \mathrm{~moles}\] The molar mass of Cl2 is \(71 \mathrm{~g/mol}\), so the grams of Cl2 produced are calculated by multiplying the moles of Cl2 by the molar mass of Cl2: \[0.33 \mathrm{~moles} \times 71 \mathrm{~g/mol} = 23.43 \mathrm{~g}\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Understanding molar mass is essential for converting units in chemical reactions. Molar mass is the mass of one mole of a substance, usually expressed in grams per mole (g/mol).
It's a key factor that connects the mass of a substance to the number of particles or moles. For example, in the original exercise with hydrochloric acid (HCl), we use the molar mass to switch from grams to moles.
Molar mass can be determined by adding up the atomic masses of all the atoms in a chemical formula. The atomic masses can be found on the periodic table.
  • For HCl, H (hydrogen) has an atomic mass of about 1 g/mol and Cl (chlorine) is about 35.5 g/mol.
  • When you add them together, you get approximately 36.5 g/mol, which is the molar mass of HCl.
Mastering this concept allows you to move seamlessly between mass and moles in various chemical equations.
Balanced Chemical Equation
A balanced chemical equation shows the relationship between the reactants and the products in a chemical reaction. It's crucial because it ensures the conservation of mass, meaning the number of atoms for each element is the same before and after a reaction.
In the given exercise, the balanced equation is:\[\mathrm{MnO}_{2}+4 \mathrm{HCl} \longrightarrow \mathrm{MnCl}_{2}+\mathrm{Cl}_{2}+2 \mathrm{H}_{2} \mathrm{O}\]
This equation tells us several things:
  • One mole of \(\mathrm{MnO}_{2}\) reacts with four moles of \(\mathrm{HCl}\).
  • It produces one mole of \(\mathrm{MnCl}_{2}\), one mole of \(\mathrm{Cl}_{2}\), and two moles of \(\mathrm{H}_{2} \mathrm{O}\).
Balancing chemical equations is a fundamental skill as it allows you to predict the quantities of products formed from given reactants, just like in the problem you tackled.
Stoichiometry
Stoichiometry involves the calculation of reactants and products in chemical reactions. It's about measuring the proportions of elements that react and quantify the products formed.
Using stoichiometry, you can determine the limiting reactant, which is the reactant that will run out first and thus limit the amount of product that can be formed.
In the exercise, by using stoichiometry:
  • You find that \( \mathrm{HCl} \) is the limiting reactant since it has a smaller adjusted mole ratio in the reaction (\( 0.33 \) compared to \( 0.86 \)).
  • This means \( \mathrm{HCl} \) will run out before \( \mathrm{MnO}_{2} \), stopping the reaction.
Stoichiometry provides the tools needed to follow the flow of atoms through a reaction, making it a critical aspect of chemistry.
Moles Conversion
Converting between moles and grams is a skill frequently employed in chemistry to switch between different measurement units. The conversion relies on the relation provided by molar mass.
In the exercise, you needed to convert grams of \( \mathrm{HCl} \) to moles using its molar mass:\[ \text{Moles of HCl} = \frac{\text{Given grams of HCl}}{\text{Molar mass of HCl}} = \frac{48.2}{36.5} = 1.32 \text{ moles} \]
Similarly, when you find the moles of \( \mathrm{Cl}_{2} \) produced and convert it back to grams:\[ \text{Grams of } \mathrm{Cl}_{2} = \text{Moles of } \mathrm{Cl}_{2} \times \text{Molar mass of } \mathrm{Cl}_{2} \]\[ = 0.33 \text{ moles} \times 71 \text{ g/mol} = 23.43 \text{ g} \]
This conversion bridge allows for moving seamlessly between mass and molecules, aiding in precise reaction measurements.

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Most popular questions from this chapter

Ethylene reacts with hydrogen chloride to form ethyl chloride: $$\mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Cl}(g) $$Calculate the mass of ethyl chloride formed if \(4.66 \mathrm{~g}\) of ethylene reacts with an 89.4 percent yield.

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