Chapter 3: Problem 80
Give an everyday example that illustrates the limiting reactant concept.
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Chapter 3: Problem 80
Give an everyday example that illustrates the limiting reactant concept.
These are the key concepts you need to understand to accurately answer the question.
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Nitric oxide (NO) reacts with oxygen gas to form nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\), a dark-brown gas: $$2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)$$ In one experiment 0.886 mole of NO is mixed with 0.503 mole of \(\mathrm{O}_{2}\). Calculate which of the two reactants is the limiting reactant. Calculate also the number of moles of \(\mathrm{NO}_{2}\) produced.
Industrially, nitric acid is produced by the Ostwald process represented by the following equations: $$ \begin{aligned} 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) & \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \\ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}_{2}(g) \\\2 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) & \longrightarrow \mathrm{HNO}_{3}(a q)+\mathrm{HNO}_{2}(a q) \end{aligned}$$What mass of \(\mathrm{NH}_{3}\) (in grams) must be used to produce 1.00 ton of \(\mathrm{HNO}_{3}\) by the above procedure, assuming an 80 percent yield in each step? ( 1 ton = \(2000 \mathrm{lb} ; 1 \mathrm{lb}=453.6 \mathrm{~g} .)\)
Balance the following equations using the method outlined in Section 3.7 : (a) \(\mathrm{C}+\mathrm{O}_{2} \longrightarrow \mathrm{CO}\) (b) \(\mathrm{CO}+\mathrm{O}_{2} \longrightarrow \mathrm{CO}_{2}\) (c) \(\mathrm{H}_{2}+\mathrm{Br}_{2} \longrightarrow \mathrm{HBr}\) (d) \(\mathrm{K}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{KOH}+\mathrm{H}_{2}\) (e) \(\mathrm{Mg}+\mathrm{O}_{2} \longrightarrow \mathrm{MgO}\) (f) \(\mathrm{O}_{3} \longrightarrow \mathrm{O}_{2}\) (g) \(\mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\) (h) \(\mathrm{N}_{2}+\mathrm{H}_{2} \longrightarrow \mathrm{NH}_{3}\) (i) \(\mathrm{Zn}+\mathrm{AgCl} \longrightarrow \mathrm{ZnCl}_{2}+\mathrm{Ag}\) (j) \(\mathrm{S}_{8}+\mathrm{O}_{2} \longrightarrow \mathrm{SO}_{2}\) (k) \(\mathrm{NaOH}+\mathrm{H}_{2} \mathrm{SO}_{4} \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}+\mathrm{H}_{2} \mathrm{O}\) (l) \(\mathrm{Cl}_{2}+\mathrm{NaI} \longrightarrow \mathrm{NaCl}+\mathrm{I}_{2}\) \((\mathrm{m}) \mathrm{KOH}+\mathrm{H}_{3} \mathrm{PO}_{4} \longrightarrow \mathrm{K}_{3} \mathrm{PO}_{4}+\mathrm{H}_{2} \mathrm{O}\) (n) \(\mathrm{CH}_{4}+\mathrm{Br}_{2} \longrightarrow \mathrm{CBr}_{4}+\mathrm{HBr}\)
Allicin is the compound responsible for the characteristic smell of garlic. An analysis of the compound gives the following percent composition by mass: C: 44.4 percent, \(\mathrm{H}: 6.21\) percent, \(\mathrm{S}: 39.5\) percent, \(\mathrm{O}:\) 9.86 percent. Calculate its empirical formula. What is its molecular formula given that its molar mass is about \(162 \mathrm{~g}\) ?
Ammonia and sulfuric acid react to form ammonium sulfate. (a) Write an equation for the reaction. (b) Determine the starting mass (in grams) of each reactant if \(20.3 \mathrm{~g}\) of ammonium sulfate is produced and \(5.89 \mathrm{~g}\) of sulfuric acid remains unreacted.
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