Chapter 22: Problem 19
Give an example of a carbide and a cyanide.
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Chapter 22: Problem 19
Give an example of a carbide and a cyanide.
These are the key concepts you need to understand to accurately answer the question.
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When \(1.645 \mathrm{~g}\) of white phosphorus are dissolved in \(75.5 \mathrm{~g}\) of \(\mathrm{CS}_{2},\) the solution boils at \(46.709^{\circ} \mathrm{C}\) whereas pure \(\mathrm{CS}_{2}\) boils at \(46.300^{\circ} \mathrm{C}\). The molal boiling-point elevation constant for \(\mathrm{CS}_{2}\) is \(2.34^{\circ} \mathrm{C} / \mathrm{m}\). Calculate the molar mass of white phosphorus and give the molecular formula.
Give an example of hydrogen as (a) an oxidizing agent and (b) a reducing agent.
Explain why two \(\mathrm{N}\) atoms can form a double bond or a triple bond, whereas two \(\mathrm{P}\) atoms normally can form only a single bond.
At \(620 \mathrm{~K}\) the vapor density of ammonium chloride relative to hydrogen \(\left(\mathrm{H}_{2}\right)\) under the same conditions of temperature and pressure is \(14.5,\) although, according to its formula mass, it should have a vapor density of \(26.8 .\) How would you account for this discrepancy?
Sulfuric acid is a dehydrating agent. Write balanced equations for the reactions between sulfuric acid and the following substances: (a) \(\mathrm{HCOOH}\) (b) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) (c) \(\mathrm{HNO}_{3}\), (d) \(\mathrm{HClO}_{3}\). (Hint: Sulfuric acid is not decomposed by the dehydrating action.)
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