Chapter 17: Problem 34
What is the role of ATP in biological reactions?
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Chapter 17: Problem 34
What is the role of ATP in biological reactions?
These are the key concepts you need to understand to accurately answer the question.
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As an approximation, we can assume that proteins exist either in the native (or physiologically functioning) state and the denatured state: $$ \text { native } \rightleftharpoons \text { denatured } $$ The standard molar enthalpy and entropy of the denaturation of a certain protein are \(512 \mathrm{~kJ} / \mathrm{mol}\) and \(1.60 \mathrm{~kJ} / \mathrm{K} \cdot \mathrm{mol},\) respectively. Comment on the signs and magnitudes of these quantities, and calculate the temperature at which the process favors the denatured state.
For each pair of substances listed here, choose the one having the larger standard entropy value at \(25^{\circ} \mathrm{C}\). The same molar amount is used in the comparison. Explain the basis for your choice. (a) \(\mathrm{Li}(s)\) or \(\mathrm{Li}(l)\) (b) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l)\) or \(\mathrm{CH}_{3} \mathrm{OCH}_{3}(l)\) (Hint: Which molecule can hydrogen-bond?); (c) \(\operatorname{Ar}(g)\) or \(\operatorname{Xe}(g) ;\) (d) \(\operatorname{CO}(g)\) or \(\mathrm{CO}_{2}(g)\) (e) \(\mathrm{O}_{2}(g)\) or \(\mathrm{O}_{3}(g) ;(\mathrm{f}) \mathrm{NO}_{2}(g)\) or \(\mathrm{N}_{2} \mathrm{O}_{4}(g)\)
The molar heat of vaporization of ethanol is 39.3 kJ/mol and the boiling point of ethanol is \(78.3^{\circ} \mathrm{C}\). Calculate \(\Delta S\) for the vaporization of 0.50 mol ethanol.
The internal engine of a 1200 -kg car is designed to run on octane \(\left(\mathrm{C}_{8} \mathrm{H}_{18}\right),\) whose enthalpy of combustion is \(5510 \mathrm{~kJ} / \mathrm{mol}\). If the car is moving up a slope, calculate the maximum height (in meters) to which the car can be driven on 1.0 gallon of the fuel. Assume that the engine cylinder temperature is \(2200^{\circ} \mathrm{C}\) and the exit temperature is \(760^{\circ} \mathrm{C},\) and neglect all forms of friction. The mass of 1 gallon of fuel is \(3.1 \mathrm{~kg} .\) [Hint: See the Chemistry in Action essay "The Efficiency of Heat Engines" in Section \(17.5 .\) The work done in moving the car over a vertical distance is \(m g h,\) where \(m\) is the mass of the car in \(\mathrm{kg}\), \(g\) the acceleration due to gravity \(\left(9.81 \mathrm{~m} / \mathrm{s}^{2}\right),\) and \(h\) the height in meters.]
Under what conditions does a substance have a standard entropy of zero? Can a substance ever have a negative standard entropy?
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