Chapter 16: Problem 85
Outline the general procedure of qualitative analysis.
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Chapter 16: Problem 85
Outline the general procedure of qualitative analysis.
These are the key concepts you need to understand to accurately answer the question.
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Sketch titration curves for the following acid-base titrations: (a) \(\mathrm{HCl}\) versus \(\mathrm{NaOH},\) (b) \(\mathrm{HCl}\) versus \(\mathrm{CH}_{3} \mathrm{NH}_{2},\) (c) \(\mathrm{CH}_{3} \mathrm{COOH}\) versus \(\mathrm{NaOH}\). In each case, the base is added to the acid in an Erlenmeyer flask. Your graphs should show \(\mathrm{pH}\) on the \(y\) axis and volume of base added on the \(x\) axis.
A 0.1276 -g sample of an unknown monoprotic acid was dissolved in \(25.0 \mathrm{~mL}\) of water and titrated with \(0.0633 \mathrm{M} \mathrm{NaOH}\) solution. The volume of base required to bring the solution to the equivalence point was \(18.4 \mathrm{~mL}\). (a) Calculate the molar mass of the acid. (b) After \(10.0 \mathrm{~mL}\) of base had been added during the titration, the \(\mathrm{pH}\) was determined to be 5.87 . What is the \(K_{\mathrm{a}}\) of the unknown acid?
If \(\mathrm{NaOH}\) is added to \(0.010 \mathrm{M} \mathrm{Al}^{3+}\), which will be the predominant species at equilibrium: \(\mathrm{Al}(\mathrm{OH})_{3}\) or \(\mathrm{Al}(\mathrm{OH})_{4}^{-} ?\) The \(\mathrm{pH}\) of the solution is \(14.00 .\left[K_{\mathrm{f}}\right.\) for \(\left.\mathrm{Al}(\mathrm{OH})_{4}^{-}=2.0 \times 10^{33} .\right]\)
Find the approximate \(\mathrm{pH}\) range suitable for separating \(\mathrm{Mg}^{2+}\) and \(\mathrm{Zn}^{2+}\) by the precipitation of \(\mathrm{Zn}(\mathrm{OH})_{2}\) from a solution that is initially \(0.010 M\) in \(\mathrm{Mg}^{2+}\) and \(\mathrm{Zn}^{2+}\)
Use Le Châtelier's principle to explain how the common ion effect affects the \(\mathrm{pH}\) of a solution.
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