Chapter 14: Problem 37
Define reaction quotient. How does it differ from equilibrium constant?
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Chapter 14: Problem 37
Define reaction quotient. How does it differ from equilibrium constant?
These are the key concepts you need to understand to accurately answer the question.
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For the reaction $$\mathrm{H}_{2}(g)+\mathrm{CO}_{2}(g) \rightleftharpoons \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{CO}(g)$$ at \(700^{\circ} \mathrm{C}, K_{\mathrm{c}}=0.534 .\) Calculate the number of moles of \(\mathrm{H}_{2}\) that are present at equilibrium if a mixture of 0.300 mole of \(\mathrm{CO}\) and \(0.300 \mathrm{~mole}\) of \(\mathrm{H}_{2} \mathrm{O}\) is heated to \(700^{\circ} \mathrm{C}\) in a 10.0 -L container.
The equilibrium constant \(K_{P}\) for the reaction $$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g)$$ is \(5.60 \times 10^{4}\) at \(350^{\circ} \mathrm{C}\). The initial pressures of \(\mathrm{SO}_{2}\) and \(\mathrm{O}_{2}\) in a mixture are 0.350 atm and 0.762 atm, respectively, at \(350^{\circ} \mathrm{C}\). When the mixture equilibrates, is the total pressure less than or greater than the sum of the initial pressures \((1.112 \mathrm{~atm}) ?\)
A quantity of 0.20 mole of carbon dioxide was heated to a certain temperature with an excess of graphite in a closed container until the following equilibrium was reached: $$\mathrm{C}(s)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)$$ Under these conditions, the average molar mass of the gases was \(35 \mathrm{~g} / \mathrm{mol}\). (a) Calculate the mole fractions of \(\mathrm{CO}\) and \(\mathrm{CO}_{2}\). (b) What is \(K_{P}\) if the total pressure is 11 atm? (Hint: The average molar mass is the sum of the products of the mole fraction of each gas and its molar mass.
Consider the following equilibrium process at \(700^{\circ} \mathrm{C}:\) $$2 \mathrm{H}_{2}(g)+\mathrm{S}_{2}(g) \rightleftharpoons 2 \mathrm{H}_{2} \mathrm{~S}(g)$$ Analysis shows that there are 2.50 moles of \(\mathrm{H}_{2}\), \(1.35 \times 10^{-5}\) mole of \(\mathrm{S}_{2}\), and 8.70 moles of \(\mathrm{H}_{2} \mathrm{~S}\) present in a 12.0-L flask. Calculate the equilibrium constant \(K_{\mathrm{c}}\) for the reaction.
When a gas was heated under atmospheric conditions, its color deepened. Heating above \(150^{\circ} \mathrm{C}\) caused the color to fade, and at \(550^{\circ} \mathrm{C}\) the color was barely detectable. However, at \(550^{\circ} \mathrm{C},\) the color was partially restored by increasing the pressure of the system. Which of the following best fits the above description? Justify your choice. (a) A mixture of hydrogen and bromine, (b) pure bromine, (c) a mixture of nitrogen dioxide and dinitrogen tetroxide. (Hint: Bromine has a reddish color and nitrogen dioxide is a brown gas. The other gases are colorless.)
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