Chapter 14: Problem 10
Write the equation relating \(K_{\mathrm{c}}\) to \(K_{P}\), and define all the terms.
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Chapter 14: Problem 10
Write the equation relating \(K_{\mathrm{c}}\) to \(K_{P}\), and define all the terms.
These are the key concepts you need to understand to accurately answer the question.
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At a certain temperature the following reactions have the constants shown: $$\begin{array}{ll}\mathrm{S}(s)+\mathrm{O}_{2}(g) \rightleftharpoons \mathrm{SO}_{2}(g) & K_{\mathrm{c}}^{\prime}=4.2 \times 10^{52} \\ 2 \mathrm{~S}(s)+3 \mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) & K_{\mathrm{c}}^{\prime \prime}=9.8 \times 10^{128}\end{array}$$ Calculate the equilibrium constant \(K_{\mathrm{c}}\) for the following reaction at that temperature: $$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g)$$
Consider the equilibrium $$2 \mathrm{NOBr}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Br}_{2}(g)$$ If nitrosyl bromide, \(\mathrm{NOBr},\) is 34 percent dissociated at \(25^{\circ} \mathrm{C}\) and the total pressure is 0.25 atm, calculate \(K_{P}\) and \(K_{\mathrm{c}}\) for the dissociation at this temperature.
At \(25^{\circ} \mathrm{C}\), a mixture of \(\mathrm{NO}_{2}\) and \(\mathrm{N}_{2} \mathrm{O}_{4}\) gases are in equilibrium in a cylinder fitted with a movable piston. The concentrations are \(\left[\mathrm{NO}_{2}\right]=0.0475 \mathrm{M}\) and \(\left[\mathrm{N}_{2} \mathrm{O}_{4}\right]=0.487 \mathrm{M} .\) The volume of the gas mixture is halved by pushing down on the piston at constant temperature. Calculate the concentrations of the gases when equilibrium is reestablished. Will the color become darker or lighter after the change? [Hint: \(K_{\mathrm{c}}\) for the dissociation of \(\mathrm{N}_{2} \mathrm{O}_{4}\) to \(\mathrm{NO}_{2}\) is \(4.63 \times 10^{-3} . \mathrm{N}_{2} \mathrm{O}_{4}(g)\) is colorless and \(\mathrm{NO}_{2}(g)\) has a brown color. \(]\)
When a gas was heated under atmospheric conditions, its color deepened. Heating above \(150^{\circ} \mathrm{C}\) caused the color to fade, and at \(550^{\circ} \mathrm{C}\) the color was barely detectable. However, at \(550^{\circ} \mathrm{C},\) the color was partially restored by increasing the pressure of the system. Which of the following best fits the above description? Justify your choice. (a) A mixture of hydrogen and bromine, (b) pure bromine, (c) a mixture of nitrogen dioxide and dinitrogen tetroxide. (Hint: Bromine has a reddish color and nitrogen dioxide is a brown gas. The other gases are colorless.)
Consider the equilibrium system \(3 \mathrm{~A} \rightleftharpoons \mathrm{B}\). Sketch the changes in the concentrations of \(\mathrm{A}\) and \(\mathrm{B}\) over time for the following situations: (a) Initially only A is present. (b) Initially only B is present. (c) Initially both A and B are present (with A in higher concentration). In each case, assume that the concentration of \(\mathrm{B}\) is higher than that of \(\mathrm{A}\) at equilibrium.
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