Chapter 13: Problem 60
What are the characteristics of a catalyst?
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Chapter 13: Problem 60
What are the characteristics of a catalyst?
These are the key concepts you need to understand to accurately answer the question.
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Consider the reaction $$ \mathrm{A}+\mathrm{B} \longrightarrow \text { products } $$ From the following data obtained at a certain temperature, determine the order of the reaction and calculate the rate constant. $$ \begin{array}{ccc} \hline[\mathrm{A}](M) & {[\mathrm{B}](M)} & \text { Rate }(M / \mathrm{s}) \\ \hline 1.50 & 1.50 & 3.20 \times 10^{-1} \\ 1.50 & 2.50 & 3.20 \times 10^{-1} \\ 3.00 & 1.50 & 6.40 \times 10^{-1} \\ \hline \end{array} $$
Given the same reactant concentrations, the reaction $$ \mathrm{CO}(g)+\mathrm{Cl}_{2}(g) \longrightarrow \mathrm{COCl}_{2}(g) $$ at \(250^{\circ} \mathrm{C}\) is \(1.50 \times 10^{3}\) times as fast as the same reaction at \(150^{\circ} \mathrm{C}\). Calculate the activation energy for this reaction. Assume that the frequency factor is constant.
List four factors that influence the rate of a reaction.
The following data were collected for the reaction between hydrogen and nitric oxide at \(700^{\circ} \mathrm{C}\) : $$ 2 \mathrm{H}_{2}(g)+2 \mathrm{NO}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{N}_{2}(g) $$ $$ \begin{array}{clll} \hline \text { Experiment } & {\left[\mathrm{H}_{2}\right]} & {[\mathrm{NO}]} & \text { Initial Rate }(M / \mathrm{s}) \\ \hline 1 & 0.010 & 0.025 & 2.4 \times 10^{-6} \\ 2 & 0.0050 & 0.025 & 1.2 \times 10^{-6} \\ 3 & 0.010 & 0.0125 & 0.60 \times 10^{-6} \\ \hline \end{array} $$ (a) Determine the order of the reaction. (b) Calculate the rate constant. (c) Suggest a plausible mechanism that is consistent with the rate law. (Hint: Assume that the oxygen atom is the intermediate.)
Cyclobutane decomposes to ethylene according to the equation $$ \mathrm{C}_{4} \mathrm{H}_{8}(g) \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{4}(g) $$ Determine the order of the reaction and the rate constant based on the following pressures, which were recorded when the reaction was carried out at \(430^{\circ} \mathrm{C}\) in a constant-volume vessel. $$ \begin{array}{rc} \hline \text { Time (s) } & P_{\mathrm{C}_{4} \mathrm{H}_{8}}(\mathrm{mmHg}) \\\ \hline 0 & 400 \\ 2,000 & 316 \\ 4,000 & 248 \\ 6,000 & 196 \\ 8,000 & 155 \\ 10,000 & 122 \\ \hline \end{array} $$
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