Chapter 13: Problem 60
What are the characteristics of a catalyst?
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These are the key concepts you need to understand to accurately answer the question.
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Chapter 13: Problem 60
What are the characteristics of a catalyst?
These are the key concepts you need to understand to accurately answer the question.
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Write an equation relating the concentration of a reactant \(\mathrm{A}\) at \(t=0\) to that at \(t=t\) for a first-order reaction. Define all the terms and give their units. Do the same for a second-order reaction.
When a mixture of methane and bromine is exposed to visible light, the following reaction occurs slowly: $$ \mathrm{CH}_{4}(g)+\mathrm{Br}_{2}(g) \longrightarrow \mathrm{CH}_{3} \mathrm{Br}(g)+\mathrm{HBr}(g) $$ Suggest a reasonable mechanism for this reaction. (Hint: Bromine vapor is deep red; methane is colorless.)
"The rate constant for the reaction $$ \mathrm{NO}_{2}(g)+\mathrm{CO}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g) $$ is \(1.64 \times 10^{-6} / M \cdot\) s." What is incomplete about this statement?
Hydrogen and iodine monochloride react as follows: $$ \mathrm{H}_{2}(g)+2 \mathrm{ICl}(g) \longrightarrow 2 \mathrm{HCl}(g)+\mathrm{I}_{2}(g) $$ The rate law for the reaction is rate \(=k\left[\mathrm{H}_{2}\right][\mathrm{ICl}]\) Suggest a possible mechanism for the reaction.
The integrated rate law for the zero-order reaction \(\mathrm{A} \longrightarrow \mathrm{B}\) is \([\mathrm{A}]_{t}=[\mathrm{A}]_{0}-k t .\) (a) Sketch the follow- ing plots: (i) rate versus \([\mathrm{A}]_{t}\) and (ii) \([\mathrm{A}]_{t}\) versus \(t\). (b) Derive an expression for the half-life of the reaction. (c) Calculate the time in half-lives when the integrated rate law is no longer valid, that is, when \([\mathrm{A}]_{t}=0\)
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