Chapter 13: Problem 3
What are the advantages of measuring the initial rate of a reaction?
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Chapter 13: Problem 3
What are the advantages of measuring the initial rate of a reaction?
These are the key concepts you need to understand to accurately answer the question.
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Distinguish between homogeneous catalysis and heterogeneous catalysis. Describe three important industrial processes that utilize heterogeneous catalysis.
What are the units for the rate constants of zeroorder, first-order, and second-order reactions?
The thermal decomposition of phosphine \(\left(\mathrm{PH}_{3}\right)\) into phosphorus and molecular hydrogen is a first-order reaction: $$ 4 \mathrm{PH}_{3}(g) \longrightarrow \mathrm{P}_{4}(g)+6 \mathrm{H}_{2}(g) $$ The half-life of the reaction is \(35.0 \mathrm{~s}\) at \(680^{\circ} \mathrm{C}\). Calculate (a) the first-order rate constant for the reaction and (b) the time required for 95 percent of the phosphine to decompose.
The bromination of acetone is acid-catalyzed: \(\mathrm{CH}_{3} \mathrm{COCH}_{3}+\mathrm{Br}_{2} \frac{\mathrm{H}^{+}}{\text {cually }} \mathrm{CH}_{3} \mathrm{COCH}_{2} \mathrm{Br}+\mathrm{H}^{+}+\mathrm{Br}^{-}\) The rate of disappearance of bromine was measured for several different concentrations of acetone, bromine, and \(\mathrm{H}^{+}\) ions at a certain temperature: $$ \begin{array}{lclll} \hline & &{\text { Rate of }} \\ & & & & \text { Disappearance } \\ & {\left[\mathrm{CH}_{3} \mathrm{COCH}_{3}\right]} & {\left[\mathrm{Br}_{2}\right]} & {\left[\mathrm{H}^{+}\right]} & \text {of } \mathrm{Br}_{2}(M / \mathrm{s}) \\ \hline(1) & 0.30 & 0.050 & 0.050 & 5.7 \times 10^{-5} \\ (2) & 0.30 & 0.10 & 0.050 & 5.7 \times 10^{-5} \\ (3) & 0.30 & 0.050 & 0.20 & 1.2 \times 10^{-4} \\ (4) & 0.40 & 0.050 & 0.20 & 3.1 \times 10^{-4} \\ (5) & 0.40 & 0.050 & 0.050 & 7.6 \times 10^{-5} \\ \hline \end{array} $$ (a) What is the rate law for the reaction? (b) Determine the rate constant. (c) The following mechanism has been proposed for the reaction: Show that the rate law deduced from the mechanism is consistent with that shown in (a).
The first-order rate constant for the decomposition of dimethyl ether $$ \left(\mathrm{CH}_{3}\right)_{2} \mathrm{O}(g) \longrightarrow \mathrm{CH}_{4}(g)+\mathrm{H}_{2}(g)+\mathrm{CO}(g) $$ is \(3.2 \times 10^{-4} \mathrm{~s}^{-1}\) at \(450^{\circ} \mathrm{C} .\) The reaction is carried out in a constant-volume flask. Initially only dimethyl ether is present and the pressure is 0.350 atm. What is the pressure of the system after 8.0 min? Assume ideal behavior.
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