Chapter 11: Problem 30
Outdoor water pipes have to be drained or insulated in winter in a cold climate. Why?
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 11: Problem 30
Outdoor water pipes have to be drained or insulated in winter in a cold climate. Why?
These are the key concepts you need to understand to accurately answer the question.
All the tools & learning materials you need for study success - in one app.
Get started for free
Which has a greater density, crystalline \(\mathrm{SiO}_{2}\) or amorphous \(\mathrm{SiO}_{2}\) ? Why?
What is the origin of dark spots on the inner glass walls of an old tungsten lightbulb? What is the purpose of filling these lightbulbs with argon gas?
The fluorides of the second-period elements and their melting points are: \(\mathrm{LiF}, 845^{\circ} \mathrm{C} ; \mathrm{BeF}_{2}\), \(800^{\circ} \mathrm{C} ; \mathrm{BF}_{3},-126.7^{\circ} \mathrm{C} ; \mathrm{CF}_{4},-184^{\circ} \mathrm{C} ; \mathrm{NF}_{3}\) \(-206.6^{\circ} \mathrm{C} ; \quad \mathrm{OF}_{2},-223.8^{\circ} \mathrm{C} ; \quad \mathrm{F}_{2},-219.6^{\circ} \mathrm{C}\) Classify the type(s) of intermolecular forces present in each compound.
Heat of hydration, that is, the heat change that occurs when ions become hydrated in solution, is largely due to ion-dipole interactions. The heats of hydration for the alkali metal ions are \(\mathrm{Li}^{+},-520 \mathrm{~kJ} /\) mol; \(\mathrm{Na}^{+},-405 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{K}^{+},-321 \mathrm{~kJ} / \mathrm{mol} .\) Account for the trend in these values.
Silicon used in computer chips must have an impurity level below \(10^{-9}\) (that is, fewer than one impurity atom for every \(10^{9} \mathrm{Si}\) atoms \() .\) Silicon is prepared by the reduction of quartz \(\left(\mathrm{SiO}_{2}\right)\) with coke (a form of carbon made by the destructive distillation of coal) at about \(2000^{\circ} \mathrm{C}\) : $$\mathrm{SiO}_{2}(s)+2 \mathrm{C}(s) \longrightarrow \mathrm{Si}(I)+2 \mathrm{CO}(g)$$ Next, solid silicon is separated from other solid impurities by treatment with hydrogen chloride at \(350^{\circ} \mathrm{C}\) to form gaseous trichlorosilane \(\left(\mathrm{SiCl}_{3} \mathrm{H}\right)\) $$ \mathrm{Si}(s)+3 \mathrm{HCl}(g) \longrightarrow \mathrm{SiCl}_{3} \mathrm{H}(g)+\mathrm{H}_{2}(g) $$ Finally, ultrapure \(\mathrm{Si}\) can be obtained by reversing the above reaction at \(1000^{\circ} \mathrm{C}\) : $$ \mathrm{SiCl}_{3} \mathrm{H}(g)+\mathrm{H}_{2}(g) \longrightarrow \mathrm{Si}(s)+3 \mathrm{HCl}(g) $$ (a) Trichlorosilane has a vapor pressure of 0.258 atm at \(-2^{\circ} \mathrm{C} .\) What is its normal boiling point? Is trichlorosilane's boiling point consistent with the type of intermolecular forces that exist among its molecules? (The molar heat of vaporization of trichlorosilane is \(28.8 \mathrm{~kJ} / \mathrm{mol} .\) ) (b) What types of crystals do Si and \(\mathrm{SiO}_{2}\) form? (c) Silicon has a diamond crystal structure (see Figure 11.28 ). Each cubic unit cell (edge length \(a=543 \mathrm{pm}\) ) contains eight Si atoms. If there are \(1.0 \times 10^{13}\) boron atoms per cubic centimeter in a sample of pure silicon, how many Si atoms are there for every \(\mathrm{B}\) atom in the sample? Does this sample satisfy the \(10^{-9}\) purity requirement for the electronic grade silicon?
What do you think about this solution?
We value your feedback to improve our textbook solutions.