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Which of the following incorrectly shows the bond polarity? Show the correct bond polarity for those that are incorrect. a. \(^{\delta+} \mathrm{H}-\mathrm{F}^{\delta-} \quad\) d. \(\delta^{+} \mathrm{Br}-\mathrm{Br}^{\delta-}\) b. \(^{\delta+} \mathrm{Cl}-\mathrm{I}^{\delta-} \qquad\) e. \(\quad\) e. \(\quad ^{\delta+}\mathrm{O}-\mathrm{P}^{\delta-}\) c. \(\quad \delta+\mathrm{Si}-\mathrm{S}^{\delta-}\)

Short Answer

Expert verified
The incorrect bond polarities are: - d. \(\delta^{+} \mathrm{Br}-\mathrm{Br}^{\delta-}\), which should be \(\mathrm{Br}-\mathrm{Br}\) - e. \(^{\delta+}\mathrm{O}-\mathrm{P}^{\delta-}\), which should be \(\delta^- \mathrm{O}-\mathrm{P} \delta^+\)

Step by step solution

01

Locate electronegativity values for the involved elements

Use a periodic table with electronegativity values or memorize some common electronegativities. The electronegativity values we need are: - H: 2.2 - F: 3.98 - Cl: 3.16 - I: 2.66 - Si: 1.9 - S: 2.58 - Br: 2.96 - O: 3.44 - P: 2.19 Note that these values are from the Pauling scale and can vary slightly depending on the reference used.
02

Determine the partial charge distribution for each bond

For each molecule, compare the electronegativity values of the atoms involved in the bond: a. H-F: 2.2 - 3.98 --> F is more electronegative, so the bond polarity is correct: \(\delta^+ \mathrm{H}-\mathrm{F} \delta^-\) b. Cl-I: 3.16 - 2.66 --> Cl is more electronegative, so the bond polarity is correct: \(\delta^+ \mathrm{Cl}-\mathrm{I} \delta^-\) c. Si-S: 1.9 - 2.58 --> S is more electronegative, so the bond polarity is correct: \(\delta^+ \mathrm{Si}-\mathrm{S} \delta^-\) d. Br-Br: 2.96 - 2.96 --> Same atoms, so no polarity: \(\mathrm{Br}-\mathrm{Br}\) e. O-P: 3.44 - 2.19 --> O is more electronegative, so the bond polarity is incorrect. The correct bond polarity is: \(\delta^- \mathrm{O}-\mathrm{P} \delta^+\)
03

Identify the incorrect bond polarities and state the correct ones

The incorrect bond polarities are: - d. \(\delta^{+} \mathrm{Br}-\mathrm{Br}^{\delta-}\), which should be \(\mathrm{Br}-\mathrm{Br}\) - e. \(^{\delta+}\mathrm{O}-\mathrm{P}^{\delta-}\), which should be \(\delta^- \mathrm{O}-\mathrm{P} \delta^+\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electronegativity
Electronegativity is a key concept in understanding chemical bonds. It describes an atom's ability to attract and hold on to electrons within a bond. Each element has an electronegativity value. These values help predict how electrons are shared in bonds. Atoms with high electronegativity, like fluorine, tend to pull electrons closer. This leads to the formation of a partial negative charge around them. Conversely, atoms with lower electronegativity, like hydrogen, end up with a partial positive charge. This difference is crucial for understanding bond polarity. Electronegativity values are instrumental in determining bond characteristics, such as whether a bond is more ionic or covalent. Bonds between atoms with significantly different electronegativities often show stronger dipoles, while differences of less than 0.5 generally indicate nonpolar bonds.
Pauling Scale
The Pauling scale is a commonly used method to quantify electronegativity. Developed by Linus Pauling, it assigns values to elements based on their electron-attracting power. These values typically range from about 0.7 for the least electronegative element鈥攍ike cesium鈥攖o 3.98 for fluorine, the most electronegative. Pauling's work allows chemists to compare elements effectively when predicting bond properties. Understanding the Pauling scale helps reveal why certain molecules behave differently in chemical reactions. The scale provides insight into the distribution of electrons in a compound, guiding predictions about molecule shape, reactivity, and interactions. While other scales also exist, Pauling's remains the most widely used due to its comprehensive nature.
Partial Charge Distribution
Partial charge distribution occurs in molecules when atoms have different electronegativities. Electrons tend to gravitate towards the more electronegative atom, creating a dipole鈥攁 separation of partial charges. In a simple diatomic molecule, the atom with higher electronegativity becomes partially negative (未鈦), while the less electronegative atom turns partially positive (未鈦). This concept is essential in understanding the behavior of polar molecules, as it affects how they interact with other compounds, including solvents and reagents in reactions. It鈥檚 important to note that the distinction between the 未鈦 and 未鈦 is subtle yet critical in chemistry. This charge imbalance can influence boiling points, solubility, and biological activity of molecules. Identifying the correct partial charge distribution enables students to predict and explain a molecule's properties accurately.

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Most popular questions from this chapter

Use the following data to estimate \(\Delta H_{\mathrm{f}}^{\circ}\) for barium bromide. $$\mathrm{Ba}(s)+\mathrm{Br}_{2}(g) \longrightarrow \mathrm{BaBr}_{2}(s)$$ \(\begin{array}{ll}{\text { Lattice energy }} & {-1985 \mathrm{kJ} / \mathrm{mol}} \\ {\text { First ionization energy of Ba }} & \quad {503 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Second ionization energy of } \mathrm{Ba}} & \quad {965 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Electron affinity of } \mathrm{Br}} & {-325 \mathrm{kJ} / \mathrm{mol}}\\\\{\text { Bond energy of } \mathrm{Br}_{2}} & \quad {193 \mathrm{kJ} / \mathrm{mol}} \\\ {\text { Enthalpy of sublimation of } \mathrm{Ba}} & \quad {178 \mathrm{kJ} / \mathrm{mol}}\end{array}\)

In general, the higher the charge on the ions in an ionic compound, the more favorable the lattice energy. Why do some stable ionic compounds have \(+1\) charged ions even though \(+4,+5,\) and \(+6\) charged ions would have a more favorable lattice energy?

Which of the following statements is(are) true? Correct the false statements. a. It is impossible to satisfy the octet rule for all atoms in \(\mathrm{XeF}_{2}\) . b. Because \(\mathrm{SF}_{4}\) exists, OF_ should also exist because oxygen is in the same family as sulfur. c. The bond in NO + should be stronger than the bond in \(\mathrm{NO}^{-}\). d. As predicted from the two Lewis structures for ozone, one oxygen-oxygen bond is stronger than the other oxygen-oxygen bond.

Consider the following reaction: $$A_{2}+B_{2} \longrightarrow 2 A B \quad \Delta H=-285 \mathrm{kJ}$$ The bond energy for \(\mathrm{A}_{2}\) is one-half the amount of the AB bond energy. The bond energy of \(\mathrm{B}_{2}=432 \mathrm{kJ} / \mathrm{mol}\) . What is the bond energy of \(\mathrm{A}_{2}\) ?

Which of the following molecules have net dipole moments? For the molecules that are polar, indicate the polarity of each bond and the direction of the net dipole moment of the molecule. a. \(\mathrm{CH}_{2} \mathrm{Cl}_{2}, \mathrm{CHCl}_{3}, \mathrm{CCl}_{4}\) b. \(\mathrm{CO}_{2}, \mathrm{N}_{2} \mathrm{O}\) c. \(\mathrm{PH}_{3}, \mathrm{NH}_{3}\)

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