Chapter 8: Problem 20
Describe the type of bonding that exists in the \(\mathrm{F}_{2}(g)\) molecule. How does this type of bonding differ from that found in the \(\mathrm{HF}(g)\) molecule? How is it similar?
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Chapter 8: Problem 20
Describe the type of bonding that exists in the \(\mathrm{F}_{2}(g)\) molecule. How does this type of bonding differ from that found in the \(\mathrm{HF}(g)\) molecule? How is it similar?
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Write electron configurations for the most stable ion formed by each of the elements Al, Ba, Se, and I (when in stable ionic compounds).
An ionic compound made from the metal \(M\) and the diatomic gas \(X_{2}\) has the formula \(M_{a} X_{b},\) in which \(a=1\) or 2 and \(b=1\) or \(2 .\) Use the data provided to determine the most likely values for \(a\) and \(b,\) along with the most likely charges for each of the ions in the ionic compound. Data (in units of \(\mathrm{kJ} / \mathrm{mol} )\) Successive ionization energies of \(\mathrm{M} : 480 ., 4750\) . Successive electron affinity values for \(\mathrm{X} :-175,920\) . Enthalpy of sublimation for \(\mathrm{M}(s) \rightarrow \mathrm{M}(g) : 110\) . Lattice energy for MX \(\left(\mathrm{M}^{+} \text { and } \mathrm{X}^{-}\right) :-1200\) . Lattice energy for \(\mathrm{MX}_{2}\left(\mathrm{M}^{2+} \text { and } \mathrm{X}^{-}\right) :-3500\) . Lattice energy for \(\mathrm{M}_{2} \mathrm{X}\left(\mathrm{M}^{+} \text { and } \mathrm{X}^{2-}\right) :-3600\) . Lattice energy for \(\mathrm{MX}\left(\mathrm{M}^{2+} \text { and } \mathrm{X}^{2-}\right) :-4800\) .
The compound \(\mathrm{NF}_{3}\) is quite stable, but \(\mathrm{NCl}_{3}\) is very unstable \(\mathrm{(NCl}_{3}\) was first synthesized in 1811 by \(\mathrm{P}\) . L. Dulong, who lost three fingers and an eye studying its properties). The compounds \(\mathrm{NBr}_{3}\) and \(\mathrm{NI}_{3}\) are unknown, although the explosive compound \(\mathrm{NI}_{3} \cdot \mathrm{NH}_{3}\) is known. Account for the instability of these halides of nitrogen.
The structure of \(\mathrm{TeF}_{5}-\) is Draw a complete Lewis structure for \(\mathrm{TeF}_{5}-\), and explain the distortion from the ideal square pyramidal structure. (See Exercise 116.)
Compare the electron affinity of fluorine to the ionization energy of sodium. Is the process of an electron being 鈥減ulled鈥 from the sodium atom to the fluorine atom exothermic or endothermic? Why is NaF a stable compound? Is the overall formation of NaF endothermic or exothermic? How can this be?
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