Chapter 8: Problem 119
Predict the molecular structure (including bond angles) for each of the following. a. \(\mathrm{SeO}_{3}\) b. \(\mathrm{SeO}_{2}\)
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Chapter 8: Problem 119
Predict the molecular structure (including bond angles) for each of the following. a. \(\mathrm{SeO}_{3}\) b. \(\mathrm{SeO}_{2}\)
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Rank the following bonds in order of increasing ionic character: \(\mathrm{N}-\mathrm{O}, \mathrm{Ca}-\mathrm{O}, \mathrm{C}-\mathrm{F}, \mathrm{Br}-\mathrm{Br}, \mathrm{K}-\mathrm{F}\) .
Which compound in each of the following pairs of ionic substances has the most exothermic lattice energy? Justify your answers. a. \(\mathrm{NaCl}, \mathrm{KCl} \quad\) d. Fe \((\mathrm{OH})_{2}, \mathrm{Fe}(\mathrm{OH})_{3}\) b. \(\mathrm{LiF}, \mathrm{LiCl} \quad\) e. \(\mathrm{NaCl}, \mathrm{Na}_{2} \mathrm{O}\) c. \(\mathrm{Mg}(\mathrm{OH})_{2}, \mathrm{MgO} \quad\) f. \(\mathrm{MgO}, \mathrm{BaS}\)
Use the formal charge arguments to rationalize why \(\mathrm{BF}_{3}\) would not follow the octet rule.
Write Lewis structures that obey the octet rule for each of the following molecules and ions. (In each case the first atom listed is the central atom.) a. \(\mathrm{POCl}_{3}, \mathrm{SO}_{4}^{2-}, \mathrm{XeO}_{4}, \mathrm{PO}_{4}^{3-}, \mathrm{ClO}_{4}^{-}\) b. \(\mathrm{NF}_{3}, \mathrm{SO}_{3}^{2-}, \mathrm{PO}_{3}^{3-}, \mathrm{ClO}_{3}^{-}\) c. \(\mathrm{ClO}_{2}-, \mathrm{SCl}_{2}, \mathrm{PCl}_{2}^{-}\) d. Considering your answers to parts a, b, and c, what conclusions can you draw concerning the structures of species containing the same number of atoms and the same number of valence electrons?
Identify the following elements based on their electron configurations and rank them in order of increasing electronegativity: \([\operatorname{Ar}] 4 s^{1} 3 d^{5} ;[\mathrm{Ne}] 3 s^{2} 3 p^{3} ;[\operatorname{Ar}] 4 s^{2} 3 d^{10} 4 p^{3} ;[\mathrm{Ne}] 3 s^{2} 3 p^{5}\)
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