Chapter 5: Problem 18
At the same conditions of pressure and temperature, ammonia gas is less dense than air. Why is this true?
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Chapter 5: Problem 18
At the same conditions of pressure and temperature, ammonia gas is less dense than air. Why is this true?
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A 2.50-L container is filled with 175 g argon. a. If the pressure is 10.0 atm, what is the temperature? b. If the temperature is 225 K, what is the pressure?
Xenon and fluorine will react to form binary compounds when a mixture of these two gases is heated to \(400^{\circ} \mathrm{C}\) in a nickel reaction vessel. A 100.0 -mL nickel container is filled with xenon and fluorine, giving partial pressures of 1.24 atm and 10.10 atm, respectively, at a temperature of \(25^{\circ} \mathrm{C}\) . The reaction vessel is heated to \(400^{\circ} \mathrm{C}\) to cause a reaction to occur and then cooled to a temperature at which \(\mathrm{F}_{2}\) is a gas and the xenon fluoride compound produced is a nonvolatile solid. The remaining \(\mathrm{F}_{2}\) gas is transferred to another \(100.0-\mathrm{mL}\) nickel container, where the pressure of \(\mathrm{F}_{2}\) at \(25^{\circ} \mathrm{C}\) is 7.62 \(\mathrm{atm}\) . Assuming all of the xenon has reacted, what is the formula of the product?
At elevated temperatures, sodium chlorate decomposes to produce sodium chloride and oxygen gas. A 0.8765-g sample of impure sodium chlorate was heated until the production of oxygen gas ceased. The oxygen gas collected over water occupied 57.2 \(\mathrm{mL}\) at a temperature of $22^{\circ} \mathrm{C}$ and a pressure of 734 torr. Calculate the mass percent of \(\mathrm{NaClO}_{3}\) in the original sample. (At \(22^{\circ} \mathrm{C}\) the vapor pressure of water is 19.8 torr.)
Silane, SiH, , is the silicon analogue of methane, \(\mathrm{CH}_{4}\) . It is prepared industrially according to the following equations: $$\begin{array}{c}{\mathrm{Si}(s)+3 \mathrm{HCl}(g) \longrightarrow \mathrm{HSiCl}_{3}(l)+\mathrm{H}_{2}(g)} \\ {4 \mathrm{HSiCl}_{3}(l) \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l)}\end{array}$$ a. If \(156 \mathrm{mL}\) \(\mathrm{HSiCl}_{3} (d=1.34 \mathrm{g} / \mathrm{mL})\) is isolated when 15.0 \(\mathrm{L}\) \(\mathrm{HCl}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3} ?\) b. When \(156 \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is 93.1\(\% ?\)
Freon- 12\(\left(\mathrm{CF}_{2} \mathrm{Cl}_{2}\right)\) is commonly used as the refrigerant in central home air conditioners. The system is initially charged to a pressure of 4.8 atm. Express this pressure in each of the fol lowing units \((1 \mathrm{atm}=14.7 \mathrm{psi}).\) a. mm Hg b. torr c. Pa d. psi
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