/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 18 At the same conditions of pressu... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

At the same conditions of pressure and temperature, ammonia gas is less dense than air. Why is this true?

Short Answer

Expert verified
Under the same pressure and temperature conditions, ammonia gas is less dense than air because it has a lower molecular mass (17 atomic mass units) compared to the average molecular mass of air (approximately 21.8 atomic mass units). Consequently, for a given volume, ammonia gas has more, lighter molecules, resulting in a lower overall mass and density.

Step by step solution

01

Understand the concept of density

Density is defined as the mass per unit volume of a substance, represented mathematically as: \(Density = \frac{Mass}{Volume}\) Density depends on factors such as temperature, pressure, and molecular mass.
02

Determine the molecular mass of ammonia and air

Ammonia gas (NH3) is composed of one nitrogen atom and three hydrogen atoms. To find the molecular mass of ammonia, we need to sum the atomic masses of its constituent atoms: Molecular mass of ammonia (NH3) = (1 Nitrogen atom x 14 atomic mass units) + (3 Hydrogen atoms x 1 atomic mass unit) = 14 + 3 = 17 atomic mass units Air is a mixture of gases primarily composed of nitrogen (N2, approximately 78%) and oxygen (O2, approximately 21%), with trace amounts of other gases. To find the average molecular mass of air, we can use a weighted average based on the percentages of nitrogen and oxygen. Molecular mass of nitrogen gas (N2) = 2 Nitrogen atoms x 14 atomic mass units = 28 atomic mass units Molecular mass of oxygen gas (O2) = 2 Oxygen atoms x 16 atomic mass units = 32 atomic mass units Average molecular mass of air ≈ (0.78 x 28) + (0.21 x 32) ≈ 21.8 atomic mass units
03

Compare the densities of ammonia and air

Under the same pressure and temperature conditions, if a gas has a lower molecular mass, it tends to have a lower density. Since the molecular mass of ammonia (17 atomic mass units) is less than that of air (approximately 21.8 atomic mass units), ammonia gas will be less dense than air under the same conditions of pressure and temperature. This is because for a given volume, there will be more, lighter molecules in the ammonia gas, leading to a lower overall mass of the substance. Due to its lower molecular mass, the ammonia molecules occupy more space, thus leading to a lower density compared to air.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

A 2.50-L container is filled with 175 g argon. a. If the pressure is 10.0 atm, what is the temperature? b. If the temperature is 225 K, what is the pressure?

Xenon and fluorine will react to form binary compounds when a mixture of these two gases is heated to \(400^{\circ} \mathrm{C}\) in a nickel reaction vessel. A 100.0 -mL nickel container is filled with xenon and fluorine, giving partial pressures of 1.24 atm and 10.10 atm, respectively, at a temperature of \(25^{\circ} \mathrm{C}\) . The reaction vessel is heated to \(400^{\circ} \mathrm{C}\) to cause a reaction to occur and then cooled to a temperature at which \(\mathrm{F}_{2}\) is a gas and the xenon fluoride compound produced is a nonvolatile solid. The remaining \(\mathrm{F}_{2}\) gas is transferred to another \(100.0-\mathrm{mL}\) nickel container, where the pressure of \(\mathrm{F}_{2}\) at \(25^{\circ} \mathrm{C}\) is 7.62 \(\mathrm{atm}\) . Assuming all of the xenon has reacted, what is the formula of the product?

At elevated temperatures, sodium chlorate decomposes to produce sodium chloride and oxygen gas. A 0.8765-g sample of impure sodium chlorate was heated until the production of oxygen gas ceased. The oxygen gas collected over water occupied 57.2 \(\mathrm{mL}\) at a temperature of $22^{\circ} \mathrm{C}$ and a pressure of 734 torr. Calculate the mass percent of \(\mathrm{NaClO}_{3}\) in the original sample. (At \(22^{\circ} \mathrm{C}\) the vapor pressure of water is 19.8 torr.)

Silane, SiH, , is the silicon analogue of methane, \(\mathrm{CH}_{4}\) . It is prepared industrially according to the following equations: $$\begin{array}{c}{\mathrm{Si}(s)+3 \mathrm{HCl}(g) \longrightarrow \mathrm{HSiCl}_{3}(l)+\mathrm{H}_{2}(g)} \\ {4 \mathrm{HSiCl}_{3}(l) \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l)}\end{array}$$ a. If \(156 \mathrm{mL}\) \(\mathrm{HSiCl}_{3} (d=1.34 \mathrm{g} / \mathrm{mL})\) is isolated when 15.0 \(\mathrm{L}\) \(\mathrm{HCl}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3} ?\) b. When \(156 \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is 93.1\(\% ?\)

Freon- 12\(\left(\mathrm{CF}_{2} \mathrm{Cl}_{2}\right)\) is commonly used as the refrigerant in central home air conditioners. The system is initially charged to a pressure of 4.8 atm. Express this pressure in each of the fol lowing units \((1 \mathrm{atm}=14.7 \mathrm{psi}).\) a. mm Hg b. torr c. Pa d. psi

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.