/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 117 Consider three identical flasks ... [FREE SOLUTION] | 91影视

91影视

Consider three identical flasks filled with different gases. Flask \(\mathrm{A} : \mathrm{CO}\) at 760 torr and \(0^{\circ} \mathrm{C}\) Flask \(\mathrm{B} : \mathrm{N}_{2}\) at 250 torr and \(0^{\circ} \mathrm{C}\) Flask \(\mathrm{C} : \mathrm{H}_{2}\) at 100 torr and \(0^{\circ} \mathrm{C}\) a. In which flask will the molecules have the greatest average kinetic energy? b. In which flask will the molecules have the greatest average velocity?

Short Answer

Expert verified
a. The molecules will have the greatest average kinetic energy in all the flasks since they are at the same temperature (\(0^{\circ}\mathrm{C}\)). b. The molecules will have the greatest average velocity in Flask C (hydrogen gas) with an average velocity of approximately \(1930.23 \,\text{m/s}\).

Step by step solution

01

a. Calculating average kinetic energy

According to the Kinetic Theory of Gases, the average kinetic energy of an ideal gas depends only on its temperature. All the flasks are at \(0^{\circ}\mathrm{C}\), which means they all have the same temperature. Therefore, the average kinetic energy of the gas molecules in all three flasks will be the same. So, the answer to question (a) is that the molecules will have the greatest average kinetic energy in all the flasks.
02

b. Calculating average velocity

The average velocity of the gas molecules can be determined using the following formula: \(v_{rms} = \sqrt{\frac{3RT}{M}}\) Where \(v_{rms}\) is the root mean square velocity of the gas molecules, \(R\) is the ideal gas constant (8.314 J鈥匥鈦宦光卪ol鈦宦), \(T\) is the temperature in Kelvin, and \(M\) is the molar mass of the gas in kg/mol. Since the temperature in all three flasks is \(0^{\circ}\mathrm{C}\) or 273.15 K, we can calculate the average velocity of the molecules in each flask by plugging in the values for each gas's molar mass (in kg/mol) and solving for \(v_{rms}\). For Flask A (carbon monoxide, CO): Molar mass of CO is 28.01 g/mol, which is 0.02801 kg/mol. \(v_{rms,CO} = \sqrt{\frac{3(8.314)(273.15)}{0.02801}}\) For Flask B (nitrogen, N鈧): Molar mass of N鈧 is 28.02 g/mol, which is 0.02802 kg/mol. \(v_{rms,N_2} = \sqrt{\frac{3(8.314)(273.15)}{0.02802}}\) For Flask C (hydrogen, H鈧): Molar mass of H鈧 is 2.02 g/mol, which is 0.00202 kg/mol. \(v_{rms,H_2} = \sqrt{\frac{3(8.314)(273.15)}{0.00202}}\) Solving the equations, we get: \(v_{rms,CO} 鈮 510.41 \,\text{m/s}\) \(v_{rms,N_2} 鈮 510.55 \,\text{m/s}\) \(v_{rms,H_2} 鈮 1930.23 \,\text{m/s}\) As we can see, the molecules in Flask C (hydrogen gas) have the greatest average velocity. So, the answer to question (b) is that the molecules will have the greatest average velocity in Flask C.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Average Kinetic Energy
The average kinetic energy of gas molecules is a key concept in understanding gas behavior, particularly under the framework of the Kinetic Theory of Gases. At the heart of this theory is the idea that the average kinetic energy of a gas depends only on its temperature, not the type of gas or the pressure it is under. This is because temperature is a measure of the average energetic movement of particles.

- **Dependence on Temperature**: Regardless of the type of gas, if the temperature remains constant, the average kinetic energy among gas molecules will also be constant. For instance, in the original exercise, all gases are at the same temperature of 0掳C or 273.15 K. Therefore, the gases in flasks A, B, and C have the same average kinetic energy.
- **Implications in Real World**: This concept is crucial for applications in chemistry and physics, especially in processes involving heat transfer. It implies that all gases at the same temperature have molecules moving with the same average energy, though they may differ in speed due to their mass.
Average Velocity
Understanding average velocity helps in analyzing how gas molecules move within a container. It reflects the speed at which gas molecules travel, which varies according to their mass and the temperature of the environment. The average velocity can be calculated using the root mean square velocity formula, which takes into account these factors.

- **Formula for Calculation**: The mathematical expression used is: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] Here, \(v_{rms}\) represents the root mean square velocity, \(R\) is the ideal gas constant, \(T\) is the temperature, and \(M\) is the molar mass of the gas. This formula helps determine the speed of molecules based on their mass.
- **Effect of Molar Mass**: Lighter molecules, such as hydrogen in flask C in the original exercise, move faster because they have lower mass. Despite having the same temperature as heavier gases like carbon monoxide (flask A) and nitrogen (flask B), hydrogen molecules exhibit a higher average velocity.
Root Mean Square Velocity
The root mean square velocity (RMS) is an important statistical measure used to determine the speed distribution of gas particles within a container. This measure provides insight into how fast molecules are moving on average in relation to their temperature and mass.

- **Computation Details**: The RMS velocity is derived from the average kinetic energy and involves the molar mass of the gas and the temperature. For example, in solving for RMS in the original solution: - Carbon monoxide \( (v_{rms,CO}) \) results in approximately 510.41 m/s, - Nitrogen \( (v_{rms,N_2}) \) gives about 510.55 m/s, - Hydrogen \( (v_{rms,H_2}) \) shoots up to 1930.23 m/s.
- **Importance in Gas Dynamics**: The RMS velocity is crucial in predicting how gases will behave under different conditions. It also helps in understanding diffusion and effusion rates, where lighter gases typically move faster than heavier gases.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

As weather balloons rise from the earth鈥檚 surface, the pressure of the atmosphere becomes less, tending to cause the volume of the balloons to expand. However, the temperature is much lower in the upper atmosphere than at sea level. Would this temperature effect tend to make such a balloon expand or contract? Weather balloons do, in fact, expand as they rise. What does this tell you?

A sealed balloon is filled with 1.00 \(\mathrm{L}\) helium at \(23^{\circ} \mathrm{C}\) and 1.00 atm . The balloon rises to a point in the atmosphere where the pressure is 220 . torr and the temperature is \(-31^{\circ} \mathrm{C}\) . What is the change in volume of the balloon as it ascends from 1.00 atm to a pressure of 220 . torr?

Sulfur trioxide, \(\mathrm{SO}_{3},\) is produced in enormous quantities each year for use in the synthesis of sulfuric acid. $$\mathrm{S}(s)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{SO}_{2}(g)$$ $$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g)$$ What volume of \(\mathrm{O}_{2}(g)\) at \(350 .^{\circ} \mathrm{C}\) and a pressure of 5.25 atm is needed to completely convert 5.00 \(\mathrm{g}\) sulfur to sulfur trioxide?

A gas sample containing 1.50 moles at \(25^{\circ} \mathrm{C}\) exerts a pressure of 400. torr. Some gas is added to the same container and the temperature is increased to 50\(\cdot^{\circ} \mathrm{C}\). If the pressure increases to 800. torr, how many moles of gas were added to the container? Assume a constant-volume container.

Consider the following samples of gases at the same temperature. Arrange each of these samples in order from lowest to highest: a. pressure b. average kinetic energy c. density d. root mean square velocity Note: Some samples of gases may have equal values for these attributes. Assume the larger containers have a volume twice the volume of the smaller containers, and assume the mass of an argon atom is twice the mass of a neon atom.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.