Chapter 5: Problem 11
If you release a helium balloon, it soars upward and eventually pops. Explain this behavior
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Chapter 5: Problem 11
If you release a helium balloon, it soars upward and eventually pops. Explain this behavior
These are the key concepts you need to understand to accurately answer the question.
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In 1897 the Swedish explorer Andreé tried to reach the North Pole in a balloon. The balloon was filled with hydrogen gas. The hydrogen gas was prepared from iron splints and diluted sulfuric acid. The reaction is $$\mathrm{Fe}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{FeSO}_{4}(a q)+\mathrm{H}_{2}(g)$$ The volume of the balloon was 4800 \(\mathrm{m}^{3}\) and the loss of hydrogen gas during filling was estimated at \(20 . \%\) . What mass of iron splints and 98\(\%\) (by mass) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) were needed to ensure the complete filling of the balloon? Assume a temperature of \(0^{\circ} \mathrm{C},\) a pressure of 1.0 atm during filling, and 100\(\%\) yield.
An organic compound contains \(\mathrm{C}, \mathrm{H}, \mathrm{N},\) and \(\mathrm{O}\) . Combustion of 0.1023 \(\mathrm{g}\) of the compound in excess oxygen yielded 0.2766 \(\mathrm{g} \mathrm{CO}_{2}\) and 0.0991 \(\mathrm{g} \mathrm{H}_{2} \mathrm{O} .\) A sample of 0.4831 \(\mathrm{g}\) of the compound was analyzed for nitrogen by the Dumas method (see Exercise 137\() .\) At STP, 27.6 \(\mathrm{mL}\) of dry \(\mathrm{N}_{2}\) was obtained. In a third experiment, the density of the compound as a gas was found to be 4.02 \(\mathrm{g} / \mathrm{L}\) at \(127^{\circ} \mathrm{C}\) and 256 torr. What are the empirical and molecular formulas of the compound?
A compressed gas cylinder contains \(1.00 \times 10^{3} \mathrm{g}\) argon gas. The pressure inside the cylinder is \(2050 .\) psi (pounds per square inch) at a temperature of \(18^{\circ} \mathrm{C}\) . How much gas remains in the cylinder if the pressure is decreased to 650 . psi at a temperature of \(26^{\circ} \mathrm{C} ?\)
A compound containing only \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{N}\) yields the following data: i. Complete combustion of 35.0 \(\mathrm{mg}\) of the compound produced 33.5 \(\mathrm{mg}\) of \(\mathrm{CO}_{2}\) and 41.1 \(\mathrm{mg}\) of \(\mathrm{H}_{2} \mathrm{O} .\) ii. A 65.2 -mg sample of the compound was analyzed for nitrogen by the Dumas method (see Exercise \(137 ),\) giving 35.6 \(\mathrm{mL}\) of dry \(\mathrm{N}_{2}\) at \(740 .\) torr and \(25^{\circ} \mathrm{C}\) . iii. The effusion rate of the compound as a gas was measured and found to be \(24.6 \mathrm{mL} / \mathrm{min}\). The effusion rate of argon gas, under identical conditions, is \(24.6 \mathrm{mL} / \mathrm{min}\). What is the molecular formula of the compound?
A mixture of cyclopropane and oxygen is sometimes used as a general anesthetic. Consider a balloon with an anesthetic mixture of cyclopropane and oxygen at 170. torr and 570. torr, respectively. Calculate the mole fraction of cyclopropane in the mixture.
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