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A mixture contains only NaCl and \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) . A \(0.456-\mathrm{g}\) sample of the mixture is dissolved in water, and an excess of NaOH is added, producing a precipitate of \(\mathrm{Fe}(\mathrm{OH})_{3}\) . The precipitate is filtered, dried, and weighed. Its mass is 0.107 \(\mathrm{g}\) . Calculate the following. a. the mass of iron in the sample b. the mass of Fe(NO \(_{3} )_{3}\) in the sample c. the mass percent of \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) in the sample

Short Answer

Expert verified
The mass of iron in the sample is 0.0560 g, the mass of Fe(NO₃)₃ in the sample is 0.2428 g, and the mass percent of Fe(NO₃)₃ in the sample is 53.25%.

Step by step solution

01

Write the balanced chemical equation

The reaction between iron(III) nitrate and sodium hydroxide forms a precipitate of iron(III) hydroxide and sodium nitrate. The balanced equation is: \(Fe(NO_3)_3 + 3NaOH \rightarrow Fe(OH)_3 + 3NaNO_3\)
02

Calculate the moles of \(\mathrm{Fe}\left(\mathrm{OH}\right)_{3}\) precipitate

We are given the mass of the precipitate, which is 0.107g. To calculate the moles, use the molar mass of Fe(OH)₃ (106.87 g/mol): Moles of \(Fe(OH)_3 = \frac{mass}{molar\,mass} = \frac{0.107\,g}{106.87\,g/mol} = 1.002\,×10^{-3}\,mol\)
03

Calculate the moles of \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\)

From the balanced equation, we can see that 1 mole of Fe(NO₃)₃ produces 1 mole of Fe(OH)₃. Therefore, moles of Fe(NO₃)₃ are the same as moles of Fe(OH)₃: Moles of \(Fe(NO_3)_3 = 1.002 × 10^{-3}\,mol\)
04

Calculate the mass of Fe in the sample

Now, we can calculate the mass of iron in the sample: Mass of Fe = (moles of \(Fe(NO_3)_3) * (molar\,mass\,of\,Fe)\) Mass of Fe = \(1.002 × 10^{-3} mol * 55.85\,g/mol = 0.0560\,g\)
05

Calculate the mass of \(Fe(NO_3)_3\) in the sample

Next, we can calculate the mass of Fe(NO₃)₃ in the sample: Mass of \(Fe(NO_3)_3\) = (moles of \(Fe(NO_3)_3) * (molar\,mass\,of\,Fe(NO_3)_3)\) Mass of \(Fe(NO_3)_3 = 1.002 × 10^{-3}\,mol * 241.86\,g/mol = 0.2428\,g\)
06

Calculate the mass percent of \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) in the sample

Finally, we can determine the mass percent of Fe(NO₃)₃ in the sample: Mass percent of \(Fe(NO_3)_3 = \frac{mass\,of\,Fe(NO_3)_3}{mass\,of\,sample} × 100\%\) Mass percent of \(Fe(NO_3)_3 = \frac{0.2428\,g}{0.456\,g} × 100\% = 53.25\%\) To sum up, the mass of iron in the sample is 0.0560 g, the mass of Fe(NO₃)₃ in the sample is 0.2428 g, and the mass percent of Fe(NO₃)₃ in the sample is 53.25%.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reactions
A chemical reaction is a process in which substances, known as reactants, are transformed into other substances, called products. In the given exercise, the reaction involves iron(III) nitrate \((\mathrm{Fe(NO}_3)_3)\) and sodium hydroxide \((\mathrm{NaOH})\) reacting to form iron(III) hydroxide \((\mathrm{Fe(OH)}_3)\) as a precipitate and sodium nitrate \((\mathrm{NaNO}_3)\). This transformation is described by a balanced chemical equation:\[ \mathrm{Fe(NO_3)_3 + 3NaOH \rightarrow Fe(OH)_3 + 3NaNO_3} \]Balancing chemical equations is crucial because it ensures that the same number of each type of atom is present on both sides of the equation. It reflects the Law of Conservation of Mass, stating that matter cannot be created or destroyed during a chemical reaction. This principle helps accurately determine the amounts of reactants and products involved, enabling further calculations in stoichiometry.
Molar Mass Calculation
Molar mass is an essential concept in stoichiometry that relates the mass of a substance to the number of moles. It allows us to convert between grams and moles, facilitating the calculation of reactants and products in a chemical reaction. For instance, the molar mass of iron(III) hydroxide \((\mathrm{Fe(OH)}_3)\) is 106.87 g/mol. To find it, sum up the atomic masses of each element in its chemical formula:- Fe = 55.85 g/mol- O = 16.00 g/mol (for 3 oxygen atoms, multiply by 3)- H = 1.01 g/mol (for 3 hydrogen atoms, multiply by 3)By adding these values, the molar mass of \(\mathrm{Fe(OH)}_3\) becomes:\[ \text{Molar Mass of } \mathrm{Fe(OH)}_3 = 55.85 + (3 \times 16.00) + (3 \times 1.01) = 106.87 \text{ g/mol} \]Molar mass aids in calculating the amount of substance, or moles, using the formula:\[ \text{Moles} = \frac{\text{Mass}}{\text{Molar Mass}} \]This calculation is crucial for interpreting chemical reactions quantitatively.
Precipitation Reaction
Precipitation reactions are a type of chemical reaction where an insoluble solid, called a precipitate, forms when two solutions are mixed. In the exercise example, iron(III) nitrate \((\mathrm{Fe(NO}_3)_3)\) reacts with sodium hydroxide \((\mathrm{NaOH})\), resulting in the formation of a precipitate, iron(III) hydroxide \((\mathrm{Fe(OH)}_3)\). The reaction can be represented by the following equation:\[ \mathrm{Fe(NO_3)_3 + 3NaOH \rightarrow Fe(OH)_3 + 3NaNO_3} \]Here, \(\mathrm{Fe(OH)}_3\) is the precipitate, which can be observed as a solid that separates from the solution. This type of reaction is used to isolate specific compounds from mixtures, as the precipitate can be filtered and weighed. It plays a vital role in various applications, including chemical analysis and environmental science, where unwanted contaminants are removed as solids.
Mass Percent Calculation
Mass percent is a measure of the concentration of a component in a mixture and is expressed as a percentage. It is calculated by dividing the mass of the component by the total mass of the sample and then multiplying by 100%.To find the mass percent of \(\mathrm{Fe(NO}_3)_3\) in the sample, follow these steps:1. Calculate the mass of \(\mathrm{Fe(NO}_3)_3\), which from the solution is 0.2428 g.2. Divide this value by the total mass of the sample, which is 0.456 g.3. Multiply the result by 100 to convert it to a percentage.Mathematically, this is shown as:\[ \text{Mass percent of } \mathrm{Fe(NO}_3)_3 = \left( \frac{0.2428 \text{ g}}{0.456 \text{ g}} \right) \times 100\% = 53.25\% \]Understanding mass percent is crucial for determining the composition of a mixture and is widely used in fields like chemistry, pharmacy, and metallurgy. This calculation helps in analyzing the purity of substances and the formulation of chemical solutions.

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Most popular questions from this chapter

Using the general solubility rules given in Table 4.1, name three reagents that would form precipitates with each of the following ions in aqueous solution. Write the net ionic equation for each of your suggestions. a. chloride ion \(\quad\) d. sulfate ion b. calcium ion \(\quad\) e. mercury \((1)\) ion, \(\mathrm{Hg}_{2}^{2+}\) c. iron(M) ion \(\quad\) f. silver ion

Consider reacting copper(II) sulfate with iron. Two possible reactions can occur, as represented by the following equations. $$\operatorname{copper}(\mathrm{II}) \text { sulfate }(a q)+\mathrm{iron}(s) \longrightarrow (s)+\operatorname{iron}(\mathrm{II}) \text { sulfate }(a q)$$ $$\operatorname{copper}(\mathrm{II}) \text { sulfate }(a q)+\mathrm{iron}(s) \longrightarrow (s)+\text { iron (III) sulfate }(a q) $$ You place 87.7 mL of a 0.500-M solution of copper(II) sulfate in a beaker. You then add 2.00 g of iron filings to the copper(II) sulfate solution. After one of the above reactions occurs, you isolate 2.27 g of copper. Which equation above describes the reaction that occurred? Support your answer

It took \(25.06 \pm 0.05 \mathrm{mL}\) of a sodium hydroxide solution to titrate a 0.4016-g sample of KHP (see Exercise 83). Calculate the concentration and uncertainty in the concentration of the sodium hydroxide solution. (See Appendix 1.5.) Neglect any uncertainty in the mass

A 10.00-g sample consisting of a mixture of sodium chloride and potassium sulfate is dissolved in water. This aqueous mixture then reacts with excess aqueous lead(II) nitrate to form 21.75 g of solid. Determine the mass percent of sodium chloride in the original mixture.

Triiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: $$\mathrm{IO}_{3}^{-}(a q)+\mathrm{I}^{-}(a q) \longrightarrow \mathrm{I}_{3}^{-}(a q)$$ Triodide ion concentration is determined by titration with a sodium thiosulfate \(\left(\mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3}\right)\) solution. The products are iodide ion and tetrathionate ion \(\left(\mathrm{S}_{4} \mathrm{O}_{6}^{2-}\right)\) a. Balance the equation for the reaction of \(\mathrm{IO}_{3}^{-}\) with \(\mathrm{I}^{-}\) ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HCl required to convert all of the 1 \(\mathrm{O}_{3}^{-}\) ions to \(\mathrm{I}_{3}^{-}\) ions? c. Write and balance the equation for the reaction of \(\mathrm{S}_{2} \mathrm{O}_{3}^{2-}\) with \(\mathrm{I}_{3}-\) in acidic solution. d. A 25.00 -mL sample of a 0.0100\(M\) solution of \(\mathrm{KIO}_{3}\) is reacted with an excess of \(\mathrm{KL}\) . It requires 32.04 \(\mathrm{mL}\) of \(\mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3}\) solution to titrate the \(\mathrm{I}_{3}^{-}\) ions present. What is the molarity of the \(\mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3}\) solution? e. How would you prepare 500.0 \(\mathrm{mL}\) of the KIO\(_{3}\)solution in part d using solid \(\mathrm{KIO}_{3} ?\)

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