Chapter 22: Problem 95
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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Chapter 22: Problem 95
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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Explain why methyl alcohol is soluble in water in all proportions, while stearyl alcohol \(\left[\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{OH}\right]\) is a waxy solid that is not soluble in water.
Consider a sample of a hydrocarbon at 0.959 atm and 298 K. Upon combusting the entire sample in oxygen, you collect a mixture of gaseous carbon dioxide and water vapor at 1.51 atm and 375 K. This mixture has a density of 1.391 g/L and occupies a volume four times as large as that of the pure hydrocarbon. Determine the molecular formula of the hydrocarbon and name it.
Glucose can occur in three forms: two cyclic forms and one open-chain structure. In aqueous solution, only a tiny fraction of the glucose is in the open-chain form. Yet tests for the presence of glucose depend on reaction with the aldehyde group, which is found only in the open-chain form. Explain why these tests work.
Is octanoic acid more soluble in \(1 M \mathrm{HCl}, 1 M \mathrm{NaOH}\) , or pure water? Explain. Drugs such as morphine \(\left(\mathrm{C}_{17} \mathrm{H}_{19} \mathrm{NO}_{3}\right)\) are often treated with strong acids. The most commonly used form of morphine is morphine hydrochloride \(\left(\mathrm{C}_{17} \mathrm{H}_{20} \mathrm{ClNO}_{3}\right)\) Why is morphine treated in this way? (Hint: Morphine is an amine.)
Ethyl caprate is an ester used in the manufacture of wine bouquets. It is sometimes called "cognac essence." Combustion analysis of a sample of ethyl caprate shows it to be 71.89\(\% \mathrm{C}\) , 12.13\(\%\) hydrogen, and 15.98\(\%\) O by mass. Hydrolysis (reaction with water) of the ester produces ethanol and a carboxylic acid. The molar mass of the carboxylic acid is 172 \(\mathrm{g} / \mathrm{mol}\) , and the \(\mathrm{R}\) group attached to the COOH group of the acid is a straight chain alkane. What is the structure of ethyl caprate?
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