Chapter 20: Problem 75
Although He is the second most abundant element in the universe, it is very rare on the earth. Why?
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Chapter 20: Problem 75
Although He is the second most abundant element in the universe, it is very rare on the earth. Why?
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Captain Kirk has set a trap for the Klingons who are threatening an innocent planet. He has sent small groups of fighter rockets to sites that are invisible to Klingon radar and put a decoy in the open. He calls this the 鈥渇ishhook鈥 strategy. Mr. Spock has sent a coded message to the chemists on the fighters to tell the ships what to do next. The outline of the message is Fill in the blanks of the message using the following clues. (1) Symbol of the halogen whose hydride has the second highest boiling point in the series of HX compounds that are hydrogen halides. (2) Symbol of the halogen that is the only hydrogen halide, HX, that is a weak acid in aqueous solution. (3) Symbol of the element whose existence on the sun was known before its existence on earth was discovered. (4) The Group 5A element in Table 20.13 that should have the most metallic character. (5) Symbol of the Group 6A element that, like selenium, is a semiconductor. (6) Symbol for the element known in rhombic and monoclinic forms. (7) Symbol for the element that exists as diatomic molecules in a yellow-green gas when not combined with another element. (8) Symbol for the most abundant element in and near the earth鈥檚 crust. (9) Symbol for the element that seems to give some protection against cancer when a diet rich in this element is consumed. (10) Symbol for the smallest noble gas that forms compounds with fluorine having the general formula \(\mathrm{AF}_{2}\) and \(\mathrm{AF}_{4}\) (reverse the symbol and split the letters as shown). (11) Symbol for the toxic element that, like phosphorus and antimony, forms tetrameric molecules when uncombined with other elements (split the letters of the symbol as shown). (12) Symbol for the element that occurs as an inert component of air but is a very prominent part of fertilizers and explosives.
The heaviest member of the alkaline earth metals is radium (Ra), a naturally radioactive element discovered by Pierre and Marie Curie in \(1898 .\) Radium was initially isolated from the uranium ore pitchblende, in which it is present as approximately 1.0 g per 7.0 metric tons of pitchblende. How many atoms of radium can be isolated from \(1.75 \times 10^{8} \mathrm{g}\) pitch- blende \((1 \text { metric ton }=1000 \mathrm{kg})\) ? One of the early uses of radium was as an additive to paint so that watch dials coated with this paint would glow in the dark. The longest-lived isotope of radium has a half-life of \(1.60 \times 10^{3}\) years. If an antique watch, manufactured in \(1925,\) contains 15.0 \(\mathrm{mg}\) radium, how many atoms of radium will remain in 2025\(?\)
What is the hybridization of the central atom in each of the following molecules? a. \(\mathrm{SF}_{6}\) b. \(\mathrm{ClF}_{3}\) c. \(\mathrm{GeCl}_{4}\) d. \(\mathrm{XeF}_{4}\)
The resistivity (a measure of electrical resistance) of graphite is \((0.4 \text { to } 5.0) \times 10^{-4}\) ohm \(\cdot \mathrm{cm}\) in the basal plane. (The basal plane is the plane of the six-membered rings of carbon atoms.) The resistivity is 0.2 to 1.0 ohm \(\cdot \mathrm{cm}\) along the axis perpendicular to the plane. The resistivity of diamond is \(10^{14}\) to \(10^{16} \mathrm{ohm} \cdot \mathrm{cm}\) and is independent of direction. How can you account for this behavior in terms of the structures of graphite and diamond?
Write the Lewis structure for \(\mathrm{O}_{2} \mathrm{F}_{2}\) . Predict the bond angles and hybridization of the two central oxygen atoms. Assign oxidation states and formal charges to the atoms in $\mathrm{O}_{2} \mathrm{F}_{2} .\( The compound \)\mathrm{O}_{2} \mathrm{F}_{2}$ is a vigorous and potent oxidizing and fluorinating agent. Are oxidation states or formal charges more useful in accounting for these properties of $\mathrm{O}_{2} \mathrm{F}_{2} ?$
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