Chapter 20: Problem 34
Elemental boron is produced by reduction of boron oxide with magnesium to give boron and magnesium oxide. Write a balanced equation for this reaction.
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Chapter 20: Problem 34
Elemental boron is produced by reduction of boron oxide with magnesium to give boron and magnesium oxide. Write a balanced equation for this reaction.
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Many lithium salts are hygroscopic (absorb water), but the corresponding salts of the other alkali metals are not. Why are lithium salts different from the others?
Molten \(\mathrm{CaCl}_{2}\) is electrolyzed for 8.00 \(\mathrm{h}\) to produce \(\mathrm{Ca}(s)\) and \(\mathrm{Cl}_{2}(g) .\) a. What current is needed to produce 5.52 \(\mathrm{kg}\) of calcium metal? b. If 5.52 \(\mathrm{kg}\) calcium metal is produced, what mass (in kg) of \(\mathrm{Cl}_{2}\) is produced?
While selenic acid has the formula \(\mathrm{H}_{2} \mathrm{SeO}_{4}\) and thus is directly related to sulfuric acid, telluric acid is best visualized as \(\mathrm{H}_{6} \mathrm{TeO}_{6}\) or \(\mathrm{Te}(\mathrm{OH})_{6}\) a. What is the oxidation state of tellurium in Te(OH) \(_{6} ?\) b. Despite its structural differences with sulfuric and selenic acid, telluric acid is a diprotic acid with \(\mathrm{p} K_{\mathrm{a}_{1}}=7.68\) and \(\mathrm{p} K_{\mathrm{a}_{2}}=11.29 .\) Telluric acid can be prepared by hydrolysis of tellurium hexafluoride according to the equation $$ \mathrm{TeF}_{6}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Te}(\mathrm{OH})_{6}(a q)+6 \mathrm{HF}(a q) $$ Tellurium hexafluoride can be prepared by the reaction of elemental tellurium with fluorine gas: $$ \mathrm{Te}(s)+3 \mathrm{F}_{2}(g) \longrightarrow \mathrm{TeF}_{6}(g) $$ If a cubic block of tellurium (density \(=6.240 \mathrm{g} / \mathrm{cm}^{3} )\) measuring 0.545 \(\mathrm{cm}\) on edge is allowed to react with 2.34 \(\mathrm{L}\) fluorine gas at 1.06 \(\mathrm{atm}\) and \(25^{\circ} \mathrm{C},\) what is the pH of a solution of \(\mathrm{Te}(\mathrm{OH})_{6}\) formed by dissolving the isolated TeF \(_{6}(g)\) in 115 \(\mathrm{mL}\) solution? Assume 100\(\%\) yield in all reactions.
Draw Lewis structures for the AsCl \(_{4}^{+}\) and \(\mathrm{AsCl}_{6}-\) ions. What type of reaction (acid-base, oxidation-reduction, or the like) is the following? $$ 2 \mathrm{AsCl}_{5}(g) \longrightarrow \mathrm{AsCl}_{4} \mathrm{As} \mathrm{Cl}_{6}(s) $$
Argon gas is inert, so it poses no serious health risks. However, if significant amounts of radon are inhaled into the lungs, lung cancer is a possible result. Explain the health risk differences between argon gas and radon gas.
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