Chapter 20: Problem 27
Beryllium shows some covalent characteristics in some of its compounds, unlike the other alkaline earth compounds. Give a possible explanation for this phenomenon.
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Chapter 20: Problem 27
Beryllium shows some covalent characteristics in some of its compounds, unlike the other alkaline earth compounds. Give a possible explanation for this phenomenon.
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While selenic acid has the formula \(\mathrm{H}_{2} \mathrm{SeO}_{4}\) and thus is directly related to sulfuric acid, telluric acid is best visualized as \(\mathrm{H}_{6} \mathrm{TeO}_{6}\) or \(\mathrm{Te}(\mathrm{OH})_{6}\) a. What is the oxidation state of tellurium in Te(OH) \(_{6} ?\) b. Despite its structural differences with sulfuric and selenic acid, telluric acid is a diprotic acid with \(\mathrm{p} K_{\mathrm{a}_{1}}=7.68\) and \(\mathrm{p} K_{\mathrm{a}_{2}}=11.29 .\) Telluric acid can be prepared by hydrolysis of tellurium hexafluoride according to the equation $$ \mathrm{TeF}_{6}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Te}(\mathrm{OH})_{6}(a q)+6 \mathrm{HF}(a q) $$ Tellurium hexafluoride can be prepared by the reaction of elemental tellurium with fluorine gas: $$ \mathrm{Te}(s)+3 \mathrm{F}_{2}(g) \longrightarrow \mathrm{TeF}_{6}(g) $$ If a cubic block of tellurium (density \(=6.240 \mathrm{g} / \mathrm{cm}^{3} )\) measuring 0.545 \(\mathrm{cm}\) on edge is allowed to react with 2.34 \(\mathrm{L}\) fluorine gas at 1.06 \(\mathrm{atm}\) and \(25^{\circ} \mathrm{C},\) what is the pH of a solution of \(\mathrm{Te}(\mathrm{OH})_{6}\) formed by dissolving the isolated TeF \(_{6}(g)\) in 115 \(\mathrm{mL}\) solution? Assume 100\(\%\) yield in all reactions.
The United States Public Health Service (USPHS) recommends the fluoridation of water as a means for preventing tooth decay. The recommended concentration is 1 \(\mathrm{mg} \mathrm{F}^{-} / \mathrm{L}\) . The presence of calcium ions in hard water can precipitate the added fluoride. What is the maximum molarity of calcium ions in hard water if the fluoride concentration is at the USPHS recommended level? \(\left(K_{\mathrm{sp}} \text { for } \mathrm{CaF}_{2}=4.0 \times 10^{-11} .\right)\)
Photogray lenses contain small embedded crystals of solid silver chloride. Silver chloride is light-sensitive because of the reaction $$ \mathrm{AgCl}(s) \stackrel{\mathrm{hv}}{\longrightarrow} \mathrm{Ag}(s)+\mathrm{Cl} $$ Small particles of metallic silver cause the lenses to darken. In the lenses this process is reversible. When the light is removed, the reverse reaction occurs. However, when pure white silver chloride is exposed to sunlight it darkens; the reverse reaction does not occur in the dark. a. How do you explain this difference? b. Photogray lenses do become permanently dark in time. How do you account for this?
Give the Lewis structure, molecular structure, and hybridization of the oxygen atom for \(\mathrm{OF}_{2} .\) Would you expect \(\mathrm{OF}_{2}\) to be a strong oxidizing agent like \(\mathrm{O}_{2} \mathrm{F}_{2}\) discussed in Exercise 67\(?\)
The xenon halides and oxides are isoelectronic with many other compounds and ions containing halogens. Give a molecule or ion in which iodine is the central atom that is isoelectronic with each of the following. \(\begin{array}{ll}{\text { a. xenon tetroxide }} & {\text { d. xenon tetrafluoride }} \\ {\text { b. xenon trioxide }} & {\text { e. xenon hexafluoride }} \\ {\text {c. xenon difluoride}}\end{array}\)
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