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The electrolysis of aqueous sodium chloride (brine) is an important industrial process for the production of chlorine and sodium hydroxide. In fact, this process is the second largest consumer of electricity in the United States, after the production of aluminum. Write a balanced equation for the electrolysis of aqueous sodium chloride (hydrogen gas is also produced).

Short Answer

Expert verified
The balanced equation for the electrolysis of aqueous sodium chloride is: 2 NaCl(aq) + 2 H鈧侽(l) 鈫 Cl鈧(g) + H鈧(g) + 2 NaOH(aq)

Step by step solution

01

Identify the half-reactions

The electrolysis of brine involves two simultaneous half-reactions, one occurring at the anode (positive electrode) and the other, at the cathode (negative electrode). At the anode, chloride ions (Cl鈦) are oxidized to chlorine gas (Cl鈧). The oxidation half-reaction is: 2 Cl鈦(aq) 鈫 Cl鈧(g) + 2 e鈦 At the cathode, water molecules (H鈧侽) are reduced to produce hydrogen gas (H鈧) and hydroxide ions (OH鈦). The reduction half-reaction is: 2 H鈧侽(l) + 2 e鈦 鈫 H鈧(g) + 2 OH鈦(aq)
02

Combine the half-reactions

Since both half-reactions involve 2 moles of electrons, they can be combined directly. Adding the two half-reactions together gives the overall balanced chemical equation for the electrolysis of aqueous sodium chloride: 2 Cl鈦(aq) + 2 H鈧侽(l) 鈫 Cl鈧(g) + H鈧(g) + 2 OH鈦(aq) However, since we started with sodium chloride (NaCl), we should include it in the equation. The sodium ions (Na鈦) present in brine combine with the hydroxide ions (OH鈦) produced at the cathode to form sodium hydroxide (NaOH). Now, the balanced equation becomes: 2 NaCl(aq) + 2 H鈧侽(l) 鈫 Cl鈧(g) + H鈧(g) + 2 NaOH(aq) This balanced equation describes the overall process of the electrolysis of aqueous sodium chloride, resulting in the production of chlorine gas, hydrogen gas, and sodium hydroxide.

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