/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 7 Which is more likely to dissolve... [FREE SOLUTION] | 91影视

91影视

Which is more likely to dissolve in an acidic solution, silver sulfide or silver chloride? Why?

Short Answer

Expert verified
Silver sulfide (Ag2S) is more likely to dissolve in an acidic solution because, in acidic environments, sulfide ions combine with H鈦 ions to form H2S gas, decreasing the concentration of S虏鈦 ions and allowing more Ag2S to dissolve, while silver chloride (AgCl) does not react with H鈦 ions and its dissolution remains unaffected.

Step by step solution

01

Write down the solubility equilibria for silver sulfide and silver chloride

First, let's write down the solubility equilibrium reactions for each compound. For silver sulfide (Ag2S): \[Ag2S(s) \rightleftharpoons 2Ag^+(aq) + S^{2-}(aq)\] For silver chloride (AgCl): \[AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)\]
02

Study the behavior of each compound in acidic environments

Now, let's study how each compound behaves in acidic environments by writing the reaction equation of the respective anions with H+ ions: For sulfide ion (S虏鈦): \[S^{2-}(aq) + H^+(aq) \rightleftharpoons HS^-(aq)\] \[HS^-(aq) + H^+(aq) \rightleftharpoons H2S(g)\] For chloride ion (Cl鈦): \[Cl^-(aq) + H^+(aq) \rightarrow \text{No reaction}\] In acidic solutions, sulfide ions combine with H鈦 ions to form H2S gas which escapes from the solution, effectively removing sulfide ions from the solution. This reduces the concentration of S虏鈦 ions, allowing more Ag2S to dissolve and establish equilibrium. On the other hand, chloride ions do not react with H鈦 ions in acidic environments, and thus their concentration is not affected.
03

Compare the solubility of silver sulfide and silver chloride in acidic environments

Based on the behavior of these compounds in acidic solutions, we can conclude the following: Silver sulfide (Ag2S) is more likely to dissolve in acidic solutions when compared to silver chloride (AgCl). This is because, in acidic environments, sulfide ions combine with H鈦 ions to form H2S gas, which escapes the solution, decreasing the concentration of S虏鈦 ions and allowing more Ag2S to dissolve to re-establish equilibrium. In contrast, silver chloride (AgCl) does not react with H鈦 ions, and its dissolution is not influenced by the acidity of the solution. So, the answer is: Silver sulfide (Ag2S) is more likely to dissolve in an acidic solution. The reason is that in acidic environments, sulfide ions combine with H鈦 ions to form H2S gas and decrease the concentration of S虏鈦 ions, allowing more Ag2S to dissolve.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

As sodium chloride solution is added to a solution of silver nitrate, a white precipitate forms. Ammonia is added to the mixture and the precipitate dissolves. When potassium bromide solution is then added, a pale yellow precipitate appears. When a solution of sodium thiosulfate is added, the yellow precipitate dissolves. Finally, potassium iodide is added to the solution and a yellow precipitate forms. Write equations for all the changes mentioned above. What conclusions can you draw concerning the sizes of the \(K_{\mathrm{sp}}\) values for \(\mathrm{AgCl}, \mathrm{AgBr},\) and \(\mathrm{AgI?}\)

Calculate the molar solubility of \(\mathrm{Co}(\mathrm{OH})_{3}, K_{\mathrm{sp}}=2.5 \times 10^{-43}.\)

The solubility of \(\mathrm{Pb}\left(\mathrm{IO}_{3}\right)_{2}(s)\) in a \(0.10-M \mathrm{KIO}_{3}\) solution is \(2.6 \times 10^{-11} \mathrm{mol} / \mathrm{L}\) . Calculate \(K_{\mathrm{sp}}\) for \(\mathrm{Pb}\left(\mathrm{IO}_{3}\right)_{2}.\)

Calculate the solubility of each of the following compounds in moles per liter. Ignore any acid鈥揵ase properties. a. \(A g_{3} P O_{4}, K_{s p}=1.8 \times 10^{-18}\) b. \(\mathrm{CaCO}_{3}, K_{\mathrm{sp}}=8.7 \times 10^{-9}\) c. \(\mathrm{Hg}_{2} \mathrm{Cl}_{2}, K_{\mathrm{sp}}=1.1 \times 10^{-18}\left(\mathrm{Hg}_{2}^{2+} \right.\) is the cation in is the cation in solution.\()\)

The \(K_{\mathrm{sp}}\) of \(\mathrm{Al}(\mathrm{OH})_{3}\) is \(2 \times 10^{-32} .\) At what pH will a \(0.2-M\) \(\mathrm{Al}^{3+}\) solution begin to show precipitation of \(\mathrm{Al}(\mathrm{OH})_{3} ?\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.