Chapter 16: Problem 14
When \(\mathrm{Na}_{3} \mathrm{PO}_{4}(a q)\) is added to a solution containing a metal ion and a precipitate forms, the precipitate generally could be one of two possibilities. What are the two possibilities?
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Chapter 16: Problem 14
When \(\mathrm{Na}_{3} \mathrm{PO}_{4}(a q)\) is added to a solution containing a metal ion and a precipitate forms, the precipitate generally could be one of two possibilities. What are the two possibilities?
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Calculate the solubility of each of the following compounds in moles per liter. Ignore any acid–base properties. a. \(P b I_{2}, K_{s p}=1.4 \times 10^{-8}\) b. \(\operatorname{CdCO}_{3}, K_{s p}=5.2 \times 10^{-12}\) c. \(\operatorname{Sr}_{3}\left(\mathrm{PO}_{4}\right)_{2}, K_{s p}=1 \times 10^{-31}\)
Calculate the molar solubility of \(\mathrm{Cd}(\mathrm{OH})_{2}, K_{\mathrm{sp}}=5.9 \times 10^{-15}.\)
Describe how you could separate the ions in each of the following groups by selective precipitation. a. \(\mathrm{Ag}^{+}, \mathrm{Mg}^{2+}, \mathrm{Cu}^{2+}\) b. \(\mathrm{Pb}^{2+}, \mathrm{Ca}^{2+}, \mathrm{Fe}^{2+}\) c. \(\mathrm{Pb}^{2+}, \mathrm{Bi}^{3+}\)
The \(K_{\mathrm{sp}}\) of \(\mathrm{Al}(\mathrm{OH})_{3}\) is \(2 \times 10^{-32} .\) At what pH will a \(0.2-M\) \(\mathrm{Al}^{3+}\) solution begin to show precipitation of \(\mathrm{Al}(\mathrm{OH})_{3} ?\)
Calculate the solubility of \(\mathrm{AgCN}(s)\left(K_{\mathrm{sp}}=2.2 \times 10^{-12}\right)\) in a solution containing \(1.0 M\) \(\mathrm{H}^{+} .\left(K_{\mathrm{a}} \text { for } \mathrm{HCN} \text { is } 6.2 \times 10^{-10} .\right)\)
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