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Consider a \(0.10-M \mathrm{H}_{2} \mathrm{CO}_{3}\) solution and a \(0.10-M \mathrm{H}_{2} \mathrm{SO}_{4}\) solution. Without doing any detailed calculations, choose one of the following statements that best describes the \(\left[\mathrm{H}^{+}\right]\) of each solution and explain your answer. a. The \(\left[\mathrm{H}^{+}\right]\) is less than 0.10\(M\) b. The \(\left[\mathrm{H}^{+}\right]\) is 0.10\(M .\) c. The \(\left[\mathrm{H}^{+}\right]\) is between 0.10\(M\) and 0.20 \(\mathrm{M}\) d. The \(\left[\mathrm{H}^{+}\right]\) is 0.20 \(\mathrm{M}\)

Short Answer

Expert verified
For the 0.10 M H鈧侰O鈧 solution, the [H鈦篯 is less than 0.10 M (option a) because it is a weak acid and only partially dissociates. For the 0.10 M H鈧係O鈧 solution, the [H鈦篯 is 0.20 M (option d) because it is a strong acid and completely dissociates, contributing 2 H鈦 ions per molecule.

Step by step solution

01

Acid Dissociation and Types of Acids

We are dealing with two acids, H鈧侰O鈧 (carbonic acid) and H鈧係O鈧 (sulfuric acid). To find the [H鈦篯 of each solution, we need to understand how each acid dissociates in water. Carbonic acid (H鈧侰O鈧) is a weak acid, which means it only partially dissociates in water: \(H_{2}CO_{3} \rightleftharpoons H^{+} + HCO_{3}^{-}\) Sulfuric acid (H鈧係O鈧) is a strong acid, which means it completely dissociates in water: \(H_{2}SO_{4} \rightarrow 2H^{+} + SO_{4}^{2-}\)
02

Comparison of [H鈦篯 Concentrations

For the 0.10 M H鈧侰O鈧 solution: Since H鈧侰O鈧 is a weak acid, it only partially dissociates, meaning that the [H鈦篯 will not reach 0.10 M. Thus, the [H鈦篯 is less than 0.10 M for the H鈧侰O鈧 solution, which corresponds to option a. For the 0.10 M H鈧係O鈧 solution: Since H鈧係O鈧 is a strong acid, each molecule of H鈧係O鈧 will contribute 2 H鈦 ions to the solution. Therefore, the [H鈦篯 would be double the initial concentration, which is 2*(0.10 M) = 0.20 M. This corresponds to option d. So the best answer for this exercise is a combination of option a for the H鈧侰O鈧 solution and option d for the H鈧係O鈧 solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Weak Acid
A weak acid is an acid that doesn't completely dissociate in water. When placed in an aqueous solution, it only partially releases its hydrogen ions (H鈦). This means that not all the acid molecules break apart, leading to a relatively low concentration of hydrogen ions in the solution compared to the initial acid concentration.

For example, carbonic acid (H鈧侰O鈧) is a classic case of a weak acid. Its dissociation in water can be represented by the equation: \(H_{2}CO_{3} \rightleftharpoons H^{+} + HCO_{3}^{-}\). This equation explains that H鈧侰O鈧 does not completely convert into hydrogen and bicarbonate ions; instead, it establishes an equilibrium where both the acid and its ions are present.

Because weak acids do not fully dissociate, the hydrogen ion concentration ([H鈦篯) is less than the concentration of the acid itself. So, a 0.10 M carbonic acid solution will have an [H鈦篯 that is less than 0.10 M, aligning with option a from the exercise. Understanding the nature of weak acids is crucial for predicting the behavior of many biological and chemical systems.
Strong Acid
Strong acids are known for their complete dissociation in water. When a strong acid is dissolved in an aqueous solution, it fully releases its hydrogen ions (H鈦), leaving no undissociated acid molecules behind. This total ionization results in a high concentration of hydrogen ions compared to the concentration of the acid.

Sulfuric acid (H鈧係O鈧) is an excellent example of a strong acid. Its dissociation, especially the first dissociation step, is complete: \(H_{2}SO_{4} \rightarrow 2H^{+} + SO_{4}^{2-}\). Notice here that each molecule of sulfuric acid releases two hydrogen ions. Due to this complete dissociation, the hydrogen ion concentration in a 0.10 M H鈧係O鈧 solution is 0.20 M, because each H鈧係O鈧 releases two H鈦 ions. This fact corresponds to option d in the exercise. Knowing about strong acids' characteristics helps in accurately determining solution behaviors, crucial for fields ranging from industrial chemistry to biochemistry.
Hydrogen Ion Concentration
Hydrogen ion concentration ([H鈦篯) is a key parameter that determines a solution's acidity level. It directly influences the pH of the solution, which is calculated as \(pH = -\log[H^{+}]\). The concentration of hydrogen ions is an indicator of how acidic or basic a solution is鈥攍ower [H鈦篯 values mean a more basic solution, while higher [H鈦篯 values indicate a more acidic environment.

It's important to recognize that the degree of dissociation of an acid in a solution determines the [H鈦篯. In the case of weak acids like carbonic acid, the partial dissociation results in lower [H鈦篯 compared to the initial acid concentration. Meanwhile, strong acids like sulfuric acid contribute more [H鈦篯 due to their complete dissociation.

In practical applications, monitoring the hydrogen ion concentration is crucial for processes like fermentation in food production and maintaining physiological pH in human bodies. Understanding these differences between weak and strong acids is fundamental in analyzing various chemical reactions and their resulting acidity.

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Most popular questions from this chapter

Making use of the assumptions we ordinarily make in calculating the \(\mathrm{pH}\) of an aqueous solution of a weak acid, calculate the pH of a \(1.0 \times 10^{-6}-\mathrm{M}\) solution of hypobromous acid \(\left(\mathrm{HBrO}, K_{\mathrm{a}}=2 \times 10^{-9}\right) .\) What is wrong with your answer? Why is it wrong? Without trying to solve the problem, explain what has to be included to solve the problem correctly.

Consider a \(0.67-M\) solution of \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\left(K_{\mathrm{b}}=5.6 \times 10^{-4}\right)\) a. Which of the following are major species in the solution? i. \(C_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\) ii. \(\mathrm{H}^{+}\) ii.. \(\mathrm{OH}^{-}\) iv. \(\mathrm{H}_{2} \mathrm{O}\) v. \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{3}+\) b. Calculate the \(\mathrm{pH}\) of this solution.

Place the species in each of the following groups in order of increasing acid strength. Explain the order you chose for each group. a. \(\mathrm{HIO}_{3}, \mathrm{HBrO}_{3}\) b. \(\mathrm{HNO}_{2}, \mathrm{HNO}_{3}\) c. HOCl, HOI d. \(\mathrm{H}_{3} \mathrm{PO}_{4}, \mathrm{H}_{3} \mathrm{PO}_{3}\)

Calculate the pH of a \(0.010-M\) solution of iodic acid (HIO \(_{3}, K_{\mathrm{a}}\) \(=0.17 )\)

What mass of \(\mathrm{NaOH}(s)\) must be added to 1.0 \(\mathrm{L}\) of 0.050 \(\mathrm{M}\) \(\mathrm{NH}_{3}\) to ensure that the percent ionization of \(\mathrm{NH}_{3}\) is no greater than 0.0010\(\% ?\) Assume no volume change on addition of \(\mathrm{NaOH} .\)

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