Chapter 10: Problem 155
For a simple cubic array, solve for the volume of an interior sphere (cubic hole) in terms of the radius of a sphere in the array.
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Chapter 10: Problem 155
For a simple cubic array, solve for the volume of an interior sphere (cubic hole) in terms of the radius of a sphere in the array.
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You and a friend each synthesize a compound with the formula \(\mathrm{XeCl}_{2} \mathrm{F}_{2} .\) Your compound is a liquid and your friend's compound is a gas (at the same conditions of temperature and pressure). Explain how the two compounds with the same formulas can exist in different phases at the same conditions of pressure and temperature.
The radius of tungsten is 137 \(\mathrm{pm}\) and the density is 19.3 \(\mathrm{g} / \mathrm{cm}^{3}\) . Does elemental tungsten have a face-centered cubic structure or a body- centered cubic structure?
What fraction of the total volume of a cubic closest packed structure is occupied by atoms? (Hint: \(V_{\text { sphere }}=\frac{4}{3} \pi r^{3} .\) ) What fraction of the total volume of a simple cubic structure is occupied by atoms? Compare the answers.
Iron has a density of 7.86 \(\mathrm{g} / \mathrm{cm}^{3}\) and crystallizes in a body-centered cubic lattice. Show that only 68\(\%\) of a body-centered lattice is actually occupied by atoms, and determine the atomic radius of iron.
Consider the following formulas for n-pentane and neopentane: Both compounds have the same overall formula \(\left(\mathrm{C}_{5} \mathrm{H}_{12}, \text { molar }\right.\) mass \(=72.15 \mathrm{g} / \mathrm{mol} ),\) yet \(n\) -pentane boils at \(36.2^{\circ} \mathrm{C}\) whereas neopentane boils at \(9.5^{\circ} \mathrm{C} .\) Rationalize the differences in the boiling points between these two nonpolar compounds.
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